光谱学与光谱分析 |
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Syntheses and Spectral Study of Novel Metal Zinc Organic Phosphonate |
SUN Rui-qing, HU Jin, ZHANG Han-hui*, CAO Yan-ning, YE Zhi-bin, WANG Ye-qin, CHEN Yi-ping |
Department of Chemistry, Fuzhou University, Fuzhou 350108, China |
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Abstract Two novel Zn2+ organic phosphonate Zn(4,4′-bipy)(HBCP) 1 and [Zn2(phen)2(BCP)(H2BCP)]·H2O 2 were hydrothermally synthesized. The compound 1 is with two-dimensional layer framework whereas the compound 2 is zero- dimensional structure. The Zn2+ion is four-coordinated in compound 1 while five or six-coordinated in compound 2. The relationship between their properties and structures was studied by using FTIR, two-dimensional (2D) correlation infrared spectroscopy under thermal perturbation, fluorescence and UV-Vis DRS spectrum etc. Upon light excitation at 350 nm, the compound 1 exhibits luminescence with a strong wide emission at 412 nm and a weak emission at 520 nm, while the compound 2 exhibits luminescence with a wide emission only at 398 nm under light excitation at 336 nm.
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Received: 2009-08-16
Accepted: 2009-11-18
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Corresponding Authors:
ZHANG Han-hui
E-mail: zhanghh1840@sina.com
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