| 光谱学与光谱分析 |
|
|
|
|
|
| Preparation and Spectrum Properties of Cellulose Nanoparticles |
| TANG Li-rong, HUANG Biao*, DAI Da-song, OU Wen, LIN Yan-ping, CHEN Xue-rong |
| College of Material Engineering，Fujian Agriculture and Forestry University，Fuzhou 350002，China |
|
|
|
|
Abstract Manipulating cellulose molecules in nanosize range to create excellent nano materials is the frontier of cellulose science. Cellulose nanoparticles, a kind of renewable biomaterial, have become the research focus home and aboard. It is of great importance to develop a simple, green, low energy-consuming, rapid and efficient method to prepare cellulose nanoparticles. In the present paper, cellulose nanoparticles (CNP) which enjoy good dispersity and nanosize were prepared by alkaline hydrolysis in a simple and feasible way, with microcrystalline cellulose (MCC) as the raw material. Moreover, the size and morphology, crystal structure and spectrum properties of the cellulose nanoparticles were analyzed by means of transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and Fourier transform infrared spectrometry (FTIR). TEM images demonstrate that the prepared samples are in quasi-sphere shapes with good dispersity and with size about 20-40 nm. The SEM images of the samples show that the purified cellulose nanoparticles can be obtained after dialysis treatment to remove salt particles. The XRD results show that the microcrystalline cellulose and cellulose nanoparticles almost have the same diffraction peaks in cellulose I crystal form. Because of the damage of amorphous region of MCC by alkaline hydrolysis, the crystallinity of produced samples increases by up to 79.71%. The grain size was calculated with Scherrer’s formula, and the average size is about 3-6 nm. Furthermore, the FTIR spectra suggest that the characteristic peaks on the graphs of cellulose nanoparticles have no significant change compared to natural cellulose, which indicates that the sample remains as the basic chemical groups of cellulose. The results show that preparing cellulose nanoparticles (CNP) by alkaline hydrolysis enjoys the ease to operate and can produce high yield, and therefore the study offers a new approach to obtaining cellulose nanoparticles with nanosize and good dispersion.
|
|
Received: 2009-08-08
Accepted: 2009-11-12
|
|
|
|
Corresponding Authors:
HUANG Biao
E-mail: fjhuangbiao@hotmail.com
|
|
[1] Hubbe M A, Rojas O J, Lucia L A, et al. Bioresources, 2008, 3(3): 929.
[2] Cheng Q, Wang S, Rials T G. Composites: Part A, 2009, 40(2): 218.
[3] George J, Sreekala M S, Thomas S. Polymer Engineering and Science, 2001, 41(9): 1471.
[4] Nogi M, Iwamoto S, Nakagaito A N, et al. Advanced Materials, 2009, 20: 1.
[5] Favier V, Canova G R, Cavaille J Y, et al. Polymers Advan. Technol., 1995, 6(5): 351.
[6] Lee S Y, Mohan D J, Kang I A, et al. Fibers and Polymers, 2009, 10(1): 77.
[7] Ahola S, Salmi J, Johansson L S, et al. Biomacromolecules, 2008, 9(4): 1273.
[8] Panthapulakkal S, Zereshkian A, Sain M. Bioresource Technology, 2006, 97(2): 265.
[9] Cranston E D, Gray D G. Biomacromolecules, 2006, 7(9): 2522.
[10] ZHEN Wen-juan, SHAN Zhi-hua(甄文娟，单志华). Modern Chemical Industry(现代化工), 2008, 28(6): 85.
[11] Abe K, Iwamoto S, Yano H. Biomacromolecules, 2007, 8(10): 3276.
[12] Siqueira G, Bras J, Dufresne A. Biomacromolecules, 2009, 10(2): 425.
[13] Alemdar A, Sain M. Composites Science and Technology, 2008, 68(2): 557.
[14] Cheng Q, Wang S, Harper D P. Composites Part A: Applied Science and Manufacturing, 2009, 40(5): 583.
[15] Jean B, Dubreuil F, Heux L, et al. Langmuir, 2008, 24(7): 3452.
[16] CHEN Guan-fu-shou, LIU Hai-qing (陈观福寿，刘海清). Chemical Journal of Chinese Universities(高等学校化学学报), 2009, 30(2): 417.
[17] Wegner T H, Jones P E. Cellulose, 2006, 13(2): 115.
[18] Goetz L, Mathew A, Oksman K, et al. Carbohydrate Polymers, 2009, 75(1): 85.
[19] Klemm D, Heublein B, Fink H P, et al. Angewandte Chemie International Edition, 2005, 44(22): 3358.
[20] LI Jian(李 坚). Wood Spectroscopy(木材波谱学). Beijing: Science Press(北京: 科学出版社), 2003.
[21] QU Hua, CAO Li-xin, SU Ge, et al(曲 华，曹立新，苏 革，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2009, 29(2): 305.
[22] Alemdar A, Sain M. Bioresource Technology, 2008, 99(6): 1664.
[23] Oh S Y, Yoo D I, Shin Y, et al. Carbohydrate Research, 2005, 340(15): 2376.
|
| [1] |
LIU Jia1, 2, GUO Fei-fei2, YU Lei2, CUI Fei-peng2, ZHAO Ying2, HAN Bing2, SHEN Xue-jing1, 2, WANG Hai-zhou1, 2*. Quantitative Characterization of Components in Neodymium Iron Boron Permanent Magnets by Laser Induced Breakdown Spectroscopy （LIBS）[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 141-147. |
| [2] |
ZHANG Peng1, 3, YANG Yi-fan1, WANG Hui1, TU Zong-cai1, 2, SHA Xiao-mei2, HU Yue-ming1*. A Review of Structural Characterization and Detection Methods of Glycated Proteins in Food Systems[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2667-2673. |
| [3] |
SUN Da-wei1, 2, 3, DENG Jun1, 2*, JI Bing-bing4. Study on the Preparation Mechanism of Steel Slag-Based Biomass Activated Carbon by Special Steel Slag-Discard Walnut Shells Based on ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2308-2312. |
| [4] |
LI Zhi1, WANG Xia1*, XU Can1*, LI Peng2, HUO Yu-rong1, FU Jing-yu1, WANG Pei1, FENG Fei3. Review of Spectral Characterization and Identification of Unresolved Space Objects[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1329-1339. |
| [5] |
WANG Zhi-hao, YIN Yong*, YU Hui-chun, YUAN Yun-xia, XUE Shu-ning. Early Warning Method of Apple Spoilage Based on 2D Hyperspectral
Information Representation With Pixel Mean and Variance[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2290-2296. |
| [6] |
XU Heng-shan2, GONG Guan-qun1, 2*, ZHANG Ying-jie1, 2, YUAN Fei2, ZHANG Yong-xia2. The Spectroscopic Characteristics of Fulvic Acid Complexed With Copper Ion and the Construction of the Mechanism of Action[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1010-1016. |
| [7] |
KONG Hui-hua1, 2, LIAN Xiang-yuan1, CHEN Ping2, PAN Jin-xiao1, 2. Research on Color Characterization of Material Components Based on Spectral CT[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3612-3617. |
| [8] |
SUN Feng1, 2, YAN Qing-qing1, WANG Lu1, SUN Zhen-fei1. Study on the Conditions of Hydrothermal Synthesis of Chinese Purple BaCuSi2O6 and the Analysis of Its Products[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2284-2287. |
| [9] |
YAO Jing-jing1, 2, YAN Yue-er3, ZHANG Ruo-hong1, LUO Chan1, LIU Jun1, BI Ning1*, TANG Yi2*. Spectroscopic Detection and Analysis for Micro Structure of Aged Traditional Handmade Paper[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1559-1565. |
| [10] |
ZENG Jian-hua, MENG Yan, LIU Lin-lin, YANG Yang, LI Mei-ying, WANG Zi-yue, ZHU Xiu-qing*, SHI Yan-guo*. Characterization and Effects of pH on the Conformation of Hemp Protein Isolate Based on Multi-Spectroscopic Technique[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3748-3754. |
| [11] |
ZHANG Hao1,2, ZHANG Lei1, LIU Xiu-yu1. Study on Preparation Stage and Mechanism of Modified Desulfurization Ash-Based Eco Rubber by X-Ray Diffraction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(02): 616-621. |
| [12] |
SONG Si-yue, LIU Xu-wei, LIN Hong-xiao, WANG Xue-jin*，HE Zhi-wei. Spectral Characterization of Electrodeposited Cu2ZnSnS4 Thin Films on Fluorine-Doped Tin Oxide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(09): 2940-2945. |
| [13] |
HE Jiang-long, HUANG Ming-li, LI Ling-yu, NIE Zhao-guang, GENG Cun-zhen, YAN Dong-yun*. Stability and Structural Characterization of Chelated Fertilizers[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(09): 2966-2973. |
| [14] |
YE Ping, WU Miao-miao, WEI Ming, YANG Zhen, HAN Qiao-feng*. Preparation, Characterization and Properties of BiOCl1-xIx and BiOBr1-xIx Solid Solution[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(08): 2443-2449. |
| [15] |
GONG Tian-cheng1,2, ZHU Yong1*, WANG Xin-yu1,3, WANG Ning1, ZHANG Jie1. Research on Preparation Process Optimization and Surface Enhanced Raman Spectroscopy (SERS) of Graphene-Silver Nanoparticle Composites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3321-3327. |
|
|
|
|
