光谱学与光谱分析 |
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Study on the Identification of Radix Scutellariae and Extract Using Fourier Transsform Infrared Spectroscopy and Two-Dimensional IR Correlation Spectroscopy |
ZHANG Chun-hui1, ZHANG Gui-jun1*, SUN Su-qin2, TU Ya2 |
1. College of Pharmaceutics, Beijing University of Chinese Medicine, Beijing 100102, China 2. Department of Chemistry, Tsinghua University, Beijing 100084, China |
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Abstract 2D-IR correlation spectroscopy was used to do the research on crude and prepared drug of radix scutellariae and the extracts of them.The results show that the holistic shape of peaks among them are similar in the FTIR spectra. In second derivative spectra, the two absorption peaks: 1 745 and 1 411 cm-1 of processed products move to the bigger wavenumber direction, while 1 357 cm-1 of processed products moves to the smaller wavenumber direction; There are conspicuous differences in Two-dimensional infrared correlation spectroscopy among them: Four characteristic peaks are shown between 1 300 and 1 800 cm-1. The intensity of peak at 1 575 cm-1 is the strongest. There are three main districts about the autopeaks of sliced scutellariae. Wine-fried scutellariae has two auto-peak districts, in which all the auto-peaks are positively correlated. The FTIR spectra of total glycoside extract of different samples present characteristic peaks at 1 615, 1 585, 1 450 cm-1(vibration of phenyl framework) and 1 658 cm-1(CO)respectively, therefore, the authors speculated that their mutual component is the compound of phenolic glycoside. The two-dimensional infrared correlation spectra present five automatic peaks (vibration of phenyl framework) in 800-1 800 cm-1(1 366,1 420,1 508,1 585,1 669 cm-1). So the authors can conclude that a lot of information can be provided by macro-fingerprint technology of infrared spectroscopy which can evaluate overall quality of radix scutellariae accurately and be used to study the characteristics of relevance of crude and prepared scutellariae.
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Received: 2009-09-26
Accepted: 2009-12-28
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Corresponding Authors:
ZHANG Gui-jun
E-mail: guijunzhang@163.com
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[1] Pharmacopoeia Committe of Ministry of Health, the People’s Republic of China(中华人民共和国卫生部药典委员会编). Pharmacopoeia of the People’s Republic of China(中华人民共和国药典). Beijing: Chemical Industry Press(北京:化学工业出版社), 2005. 221. [2] WU Tian-jin, LI Wei-de(吴天津, 李维德). Journal of Chinese Clinical Medicine(中华临床医药), 2004, 5(18):109. [3] LIANG Bi-yan, LI Shu-yuan, SUN Su-qin(梁碧燕, 李书渊, 孙素琴). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2009, 29(2): 313. [4] ZHANG Hong-mei, GUO Xi-hua(张红梅, 郭西华). Chinese Journal of Spectroscopy Laboratory(光谱实验室), 2008, 25(4): 609. [5] XU Rong, SUN Su-qin, LIU You-gang(徐 荣, 孙素琴, 刘友刚). Chinese Journal of Analytical Chemistry(分析化学), 2009, 37(2): 221. [6] WANG Yan-chun, ZHANG Zhong-yan, JIANG Xiao-zhuo(王艳春, 张忠艳, 姜小卓). China Foreign Medicinal Treatment(中外医疗), 2009, 28(13): 158. [7] ZHOU Dian-feng(周殿凤). Chinese Journal of Light Scattering(光散射学报), 2009, 21(1): 69. [8] ZHOU Yun, ZANG Hong-chang(周 云, 臧红昌). Food and Durg(食品与药品), 2009, 11(1): 72. [9] ZHAO Jun, SONG Zhi-rong, WANG Yu-xia(赵 珺, 宋治荣, 王玉霞). Chinese Journal of Medicinal Guide(中国医药导刊), 2009, 11(4): 620. [10] ZHAO Bao-wen(赵保文). Capital Medicine(首都医药),2000,7(4):33. [11] WANG Yong-gao,ZHU Yuan-long,ZHU Ren-hong(王永高,朱元龙,朱任宏). Acta Pharmaceutica Sinica(药学学报),1980,15(9):526. [12] CAI Bao-chang(蔡宝昌). China Journal of Traditional Chinese Medicine and Pharmacy(中国医药学报),1990,5(3):31. [13] SUN Su-qin,LIU Jun,ZHOU Qun(孙素琴,刘 军,周 群). Chinese Journal of Analytical Chemistry(分析化学),2002,30(2):140. [14] SUN Su-qin,HUANG H,XU Y Q. Anal. Sci., 2001,I3(Suppl 1):a451. [15] SUN Su-qin,DU D G,ZHOU Qun,et al. Anal. Sci., 2001,13(Suppl 1):a455.
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