| 光谱学与光谱分析 |
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| Preparation and Characterization of 2(8-Hydroxyquinoline)-2(Phenol)Zirconium Thin Film |
| HAO Yu-ying1, HAO Hai-tao2, WANG Hua2, ZHOU He-feng2, LIU Xu-guang2, XU Bing-she2 |
1. The College of Science of Taiyuan University of Technology，Taiyuan 030024, China
2. The College of Material Science and Engineering of Taiyuan University of Technology，Taiyuan 030024, China |
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Abstract In this paper, the new emitting material zirconium complex with 8-hydroxyquinoline and phenol (Zr(OPh)2q2), which can form high quality nano-scale amorphous thin films at glass substrates cleaned by vacuum evaporation, was synthesized. Its crystallization，thermal stability，the structure of energy band and PL mechanism were investigated respectively by FTIR spectra, DTA-TG analysis , SEM, XRD spectra, UV-Vis absorption spectra and fluorescence spectra. Results show that the Zr(OPh)2q2 is a thermally stable material, whose melting point is 381.2 ℃, decomposition temperature is 467.1 ℃, whose film can emits intense yellow-green fluorescence with peak wavelength at 525 nm and a full width at half-maximum of 107.6 nm under UV excitation(390 nm), powder has intense yellow fluorescence, therefore it may be a excellent electroluminescent material.
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Received: 2003-10-18
Accepted: 2004-01-08
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Corresponding Authors:
HAO Yu-ying
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| Cite this article: |
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HAO Yu-ying,HAO Hai-tao,WANG Hua, et al. Preparation and Characterization of 2(8-Hydroxyquinoline)-2(Phenol)Zirconium Thin Film[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(12): 1524-1527.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2004/V24/I12/1524 |
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