光谱学与光谱分析 |
|
|
|
|
|
Study on Visible Chemiluminescence from Reaction of Microwave Discharge of CF4/Ar with Carbon Disulfide |
ZHANG Xian-yi1,2, LUO Xiao-lin1, KONG Xiang-lei1, ZHANG Wei1,LI Hai-yang1* |
1. Laboratory of Environmental Spectroscopy, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China 2. College of Physics and Electronic Information, Anhui Normal University, Wuhu 241000, China |
|
|
Abstract Using crossed molecular beam-chemiluminescence apparatus,visible chemiluminescence in the region of 300-900 nm was measured from the gas-phase reaction of microwave discharge of CF4 diluted in Ar with carbon disulfide at various pressures. The geometries and frequencies of possible reaction products were respectively investigated at the B3LYP/6-311++G(3df,2pd) and MP2/6-311+G(d,p) levels. Chemiluminescence spectrum was assigned to emission spectrum of the electronically excited states of F2S2. From the analyse of spectrum and reaction mechanism, it is proposed that carbon disulfur was dissociated by metastable Ar generated from microwave discharge. The electronically excited state of F2S2 was obtained from multistage reactions of the dissociative products with atoms F generated from microwave discharge.
|
Received: 2003-05-06
Accepted: 2003-10-26
|
|
Corresponding Authors:
LI Hai-yang
|
|
Cite this article: |
ZHANG Xian-yi,LUO Xiao-lin,KONG Xiang-lei, et al. Study on Visible Chemiluminescence from Reaction of Microwave Discharge of CF4/Ar with Carbon Disulfide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(12): 1502-1505.
|
|
|
|
URL: |
https://www.gpxygpfx.com/EN/Y2004/V24/I12/1502 |
[1] Zabrnick S,Fleming J W, Lin M C. Int. J. Chem. Kinet., 1989, 21: 765. [2] Slagle I R, Gilbert J R, Gutman D. J. Chem. Phys., 1974, 61: 704. [3] William F C, John F H. J. Phys. Chem., 1992, 96: 5405. [4] CHEN Cong-xiang, ZHU Meng-xia, WANG Li, ZOU Jian-hong(陈从香,朱梦霞,王 利,邹建宏). Acta Physico-Chimica Sinica(物理化学学报),1992, 8: 226. [5] Cheng Yuying, Han Jiande, Chen Xirong, Ishikawa Y, Weiner B R. J. Phys. Chem. A, 2001, 105: 3693. [6] Glinski R J. Chem. Phys. Lett., 1986, 129: 342. [7] Glinski R J, Taylor C D, Kutzler F W. J. Phys. Chem., 1990, 94: 6196. [8] Zhou Q, Karolczak J, Clouthier D J. J. Chem. Phys., 1994, 100: 6113. [9] Glinski R J, Mishalanie E A, Birks J W. J. Photochem., 1987, 37: 217. [10] Glinski R J, Getty J N, Birks J W. Chem. Phys. Lett., 1985, 117: 359. [11] Frisch M J, Trucks G W, Schlegel H B et al. GAUSSIAN 98, Gaussian Inc., Pittsburgh PA, 1998. [12] Murray K K, Leopold D G, Miller T M, Lineberger W C. J. Chem. Phys., 1988, 89: 5442. [13] Shimanouchi T. J. Phys. Chem. Ref. Data, 1972, 6(3): 993. [14] Okabe H. Photochemistry of Small Molecules. New York:John Wiley & Sons Inc.,1978. [15] http://webbook.nist.gov/chemistry/form-ser.html. [16] Xu Dadong, Li Xuechu, Shen Guanlin, Wang Liming, Chen Hong, Lou Nanquan. Chem. Phys. Lett., 1993, 210: 315. [17] Tang J, Saito S. J. Chem. Phys., 1996, 104: 7437. |
[1] |
ZHOU Ying1, BAI Yong-hui1, SONG Xu-dong1*, YAO Min3, WANG Jiao-fei1, SU Wei-guang1, YU Guang-suo1,2*. Application of Chemiluminescence in Spectral Diagnosis: A Review[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3358-3364. |
[2] |
WU Sheng-yang1,2, HU Ren-zhi1,2*, XIE Pin-hua1,2, LI Zhi-yan1,2, LIU Xiao-yan3, LIN Chuan1,4, CHEN Hao1,2, WANG Feng-yang1,2, WANG Yi-hui1,5, JIN Hua-wei1,2. Real-Time Measurement of NOy (Total Reactive Nitrogen Oxide) by Cavity Ring Down Spectrometer (CRDS)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1661-1667. |
[3] |
LIU Yao, TAN Jian-guo*, GAO Zheng-wang. College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1018-1022. |
[4] |
CAO Xuan1,2, CHU Dong-zhi1,2, LIU Yan1,2*, MA Ran1,2, ZHANG Shu-wei1,2, WU Ning1,2, SHI Qian1,2, MA Hai-kuan1,2. An On-Line Microfluidic Analysis System for Seawater Chemical Oxygen Demand Using Ozone Chemiluminescence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3698-3702. |
[5] |
CAO Jun-tao1, WANG Hui1, CHEN Yong-hong2, LIU Yan-ming1* . Sensitive Determination of Hemoglobin in Human Blood and Serum by Flow Injection Coupled with Chemiluminescence Detection [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(01): 241-245. |
[6] |
DU Jun-jun1, WANG Hui1, REN Shu-wei2, ZHOU Min1, LIU Ying-ying1, LIU Yan-ming1* . Sensitive Determination of Bovine Serum Albumin by Flow-Injection Chemiluminescence [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(06): 1693-1696. |
[7] |
FENG Ting, HU Yu-fei*, LI Gong-ke*. A Novel Flow Injection Chemiluminescence Method with Ferricyanide and Luminol for the Determination of Ractopamine in Biological Samples [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(01): 74-77. |
[8] |
LI Hui-zhi, PEI Mei-shan, ZHANG Jin, WEI Qin . Flow-Injection Chemiluminescence Determination of Trace Copper On-Line Separation and Enrichment by Ion Imprinted Polymer [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(06): 1472-1475. |
[9] |
LIU Hai-feng1, YAO Ming-fa1*, JIN Chao2, ZHANG Peng1, LI Zhe-ming1, ZHENG Zun-qing1 . Chemiluminescence Spectroscopic Analysis of Homogeneous Charge Compression Ignition Combustion Processes [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(10): 2611-2615. |
[10] |
ZHAO Yan-fang, ZHANG Nuo, WEI Qin*, HAN Yan-yan, MAO Ke-xia, CAI Yan-yan, LI Ru . Studies and Application of Flow Injection Chemiluminescence in Analytical Chemistry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(09): 2512-2517. |
[11] |
TANG Jun1, WANG Tao1,2, LIU Er-bao1,2* . Study on the Mechanism of Sodium Formate Enhancing Luminol Chemiluminescence and Its Application in Micellar Medium [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(11): 2901-2903. |
[12] |
ZHOU Yan-mei1, ZHANG Cheng-li1, LEI Jian-du2, MA Tong-sen1, MA Guang-hui2, SU Zhi-guo2, CHAO Yang1. Molecular Imprinting-Flow Injection Chemiluminescence Method for Determination of Doxycycline Hydrochloride[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(07): 1745-1749. |
[13] |
LI Jian-jun1,ZHANG Zu-ling1,QU Ling-bo1, 2,YANG Ran2. Determination of Pazufloxacin Mesylas by Terbium Sensitized Chemiluminescence Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(01): 73-77. |
[14] |
ZHANG Ling, GUO Wen-ying, CHU Hai-hong, TU Yi-feng*. Studies on Sensitization for Electrochemiluminescence of Luminol with Platinum-Gold Bimetallic Nanoparticles Modified Electrode[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(12): 2785-2788. |
[15] |
WANG Tao1, XUE Bing-chun1, LIU Er-bao1,2*. Chemiluminescence Determination of 6-Mercaptopurine in the Luminol-Potassium Ferricyanide System[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(05): 1026-1029. |
|
|
|
|