| 光谱学与光谱分析 |
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| Spectroscopy Studies on the Interaction of Bis(p-Nitrophenyl) Esters and β-Cyclodextrin |
| LI Hong, HU Dao-dao, FANG Yu*, LIU Ya-ling |
| School of Chemistry and Materials Science, Shanxi Normal University, Xi'an 710062, China |
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Abstract The bis(p-nitrophenyl) esters of succinic acid, adipic acid and sebacic acid have been synthesized, respectively, by employing 1,3-dicyclohexylcarbodiimide (DCC) as a dehydration agent. The composition and structure of the esters have been characterized by elemental analysis, FTIR, 1H NMR and DSC. Furthermore, the host-guest interactions of the esters with β-cyclodextrin (β-CD) have been studied systematically by using fluorescence quenching, fluorescence spectroscopy and UV-Vis spectroscopy measurements. It was demonstrated that the chain of the esters was longer, the interactions was weaker between the esters and the β-CD. Both p-nitrophenyl groups in bisp-nitrophenyl) esters of succinic acid can enter the inner cavity of β-CD. In contrast, only one of the groups in bis(p-nitrophenyl) esters of adipic acid can enter the cavity. For bis (p-nitrophenyl) esters of sebacic acid, however, both groups can not enter the cavity of the β-CD. The difference in the host-guest interactions of the three esters with β-CD has been attributed to the difference in the conformations adopted by the esters. Based upon these observations, it is proposed that the esters with short linker may be more suitable for construction of new networks, which are based upon, in concept, host-guest interactions.
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Received: 2003-09-26
Accepted: 2004-02-16
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Corresponding Authors:
FANG Yu
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| Cite this article: |
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LI Hong,HU Dao-dao,FANG Yu, et al. Spectroscopy Studies on the Interaction of Bis(p-Nitrophenyl) Esters and β-Cyclodextrin [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(02): 226-231.
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https://www.gpxygpfx.com/EN/Y2005/V25/I02/226 |
[1] Atwood Ｊ Ｌ, Davies Ｊ Ｅ Ｄ, MacNicol Ｄ Ｄ. Chemistry, 1999, 64, 1503.
[2] LIU Yu, YOU Chang-cheng, ZHANG Heng-yi(刘 育, 尤长城, 张衡益). Supramolecular Chemistry-Molecular Recognition and Assembly of Synthetic Receptors(超分子化学—合成受体的分子识别与组装). Tianjin: Nankai University Press(天津: 南开大学出版社), 2001. 12.
[3] WANG Nan-ping, YU Xiao-dong, CHEN Hong-yuan(王南平, 余晓冬, 陈洪渊). Chinese Journal of Chemical Research and Application(化学研究与应用), 2001, 13(1): 27.
[4] Bertrand Ｇ Ｌ, Faulkner Ｊ Ｒ, Man Ｓ Ｍ, Amstrong Ｄ Ｗ. J. Phys. Chem., 1989, 93：6863.
[5] Eftink Ｍ Ｒ, Harrison Ｊ Ｃ. Bioorg. Chem., 1981, 10：388.
[6] LI Pei-zhi, MAO Min-yuan, ZHU Ting-ting(李培之, 毛敏媛, 朱婷婷). Chinese Journal of Analytical Chemistry(分析化学), 1994, 22: 58.
[7] Katsarava Ｒ Ｄ, Kharadze Ｄ Ｐ, Avalishvili Ｌ Ｍ, Kartvelishvili Ｔ Ｍ, Zaalishvili Ｍ Ｍ. Izv. Akad. Nauk Jruzssr, Ser. Khim., 1980, 6：215 (Russ.).
[8] Tadami Ｎ, Kazumi Ｔ. J. Appl. Polym. Sci., 1987, 33：2821.
[9] Field Ｍ Ｊ, May Ｂ Ｌ, Clements Ｐ, Tsanaksidis Ｊ, Easton Ｃ Ｊ, Lincoln Ｓ Ｔ. J. Chem. Soc. Perkin Trans I, 2000, 1251.
[10] May Ｂ Ｌ, Clements Ｐ, Tsanaktsidis Ｊ, Easton Ｃ Ｊ, Lincoln Ｓ Ｔ. J. Chem. Soc. Perkin Trans I, 2000, 463.
[11] ZＨＵ Yu-ping, LI Long-di, TONG Ai-jun(朱渝萍, 李隆弟, 童爱军). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 199８, 18(５)：617.
[12] XU Hao, CHEN Liang(续 浩, 陈 亮). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2002, 22(2)：292.
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