光谱学与光谱分析 |
|
|
|
|
|
Simultaneous Determination of Aspirin and Salicyclic Acid by Synchronous Fluorescence Spectrometry |
WEI Yong-feng, LI Xiao-hua,MA Dong-mei |
Department of Chemistry, Northwest University, Xi'an 710069, China |
|
|
Abstract A simple, rapid and inexpensive fluorimetric method for simultaneously determining ASA and SA in a single scan of the co-existing specimen had been established. When the wavelength interval(Δλ) is 80 nm for scaning, the amounts of ASA and AS could be quantitatively determined respectively. The fluorescence intensity was linearly related to the aspirin concentration in the range of 4.0×10-6-1.0×10-4 mol·L-1 with correlation coefficient 0.994 9; the fluorescence intensity was linearly related to the salicyclic acid concentration in the range of 8.0×10-7-1.0×10-4 mol·L-1 with correlation coefficient 0.997 5, the determination limit was 4.0×10-7 mol·L-1. The method is simple, rapid and inexpensive, it can be used for medicament analysis.
|
Received: 2003-09-02
Accepted: 2003-12-26
|
|
Corresponding Authors:
WEI Yong-feng
|
|
Cite this article: |
WEI Yong-feng,LI Xiao-hua,MA Dong-mei. Simultaneous Determination of Aspirin and Salicyclic Acid by Synchronous Fluorescence Spectrometry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(04): 588-590.
|
|
|
|
URL: |
https://www.gpxygpfx.com/EN/Y2005/V25/I04/588 |
[1] USP 23, The United States Pharmacopceial Convention Inc., Rockville, M D, 1994. 136. [2] British Pharmacopoeia, London:Her Majesty's Stationery Office, 1998. 901. [3] WU Zhou-an,WU Sheng-qing(吴周安, 吴盛清). Chin. J. Anal. Chem.(分析化学),1997,25(8):991. [4] Gillian P M, Shane J Q, Desmond J F et al. J. Chromatogr. B, 1998,707(1~2): 322. [5] Pirola R, Bareggi S R, Benedittis G D. J. Chromatogr. B, 1998, 705(13): 309. [6] Zenon K, Kinga B. J. Pharm. Biomed. Anal., 1998, 18: 871. [7] China Pharmacopoeia(中国药典, 二部). 2000. Vol Ⅱ:328. [8] Miles C I, Schenk G H. Anal. Chem., 1970, 42(6): 656. [9] Shane N A, Stillman R. J. Pharm. Sci., 1971, 60(1): 114 (Eng). [10] HE Wen-qi, YAO Wei-xi, XIE Xue-peng(何文琪,姚渭溪,谢学鹏). Spectroscopy and Spectral Analysis(光谱学与光谱分析),1996,16(4):100.
|
[1] |
ZHANG Tian-yao1,2, ZHANG Zhao-hui1*, ZHAO Xiao-yan1, WEI Qing-yang1, CAO Can1, YU Yang1, LI Ying1, LI Xing-yue1. Polarizability Measurements for Salicylic Acid Embedded in Polymer Matrix Using Terahertz Time-Domain Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1688-1694. |
[2] |
CHEN Jian1, HUANG Jun-shi1, 2, LIU Mu-hua1, 2, YUAN Hai-chao1, 2, HUANG Shuang-gen1, 2, ZHAO Jin-hui1, 2*, XU Ning1, WANG Ting1, HU Wei1. Study on Rapid Detection Method of Danofloxacin Mesylate and Ofloxacin Residues in a Chicken Based on Synchronous Fluorescence Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1367-1372. |
[3] |
WU Yu-hang1, HAN Zhong-bao1, MA Jia-ze1, HE Yan1, LIU Li-yan1, XIN Shi-gang2, YU Zhan1* . Intermolecular Interactions between Cytisine and Bovine Serum Albumin: A Synchronous Fluorescence Spectroscopic Analysis and Molecular Docking Research[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(03): 765-769. |
[4] |
LIU Wen-han, YUAN Rong-hui, TENG Yuan-jie, QIN Yan-ping, PAN Zai-fa, MA Chun-an . Chemical Adsorption of Thiosalicylic Acid on Silver Surface Investigated by Surface-Enhanced Raman Scattering [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(09): 2433-2437. |
[5] |
KANG Qian-qian, ZHOU Guang-ming*. Study of Aspirin and Its Interaction with DNA by Raman and UV Spectroscopies [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(03): 699-702. |
[6] |
GUO Xiao-xia1, HAO Yu-ying1*, LEI Jun-feng1, FAN Wen-hao1, WANG Hua2, XU Bing-she2 . New Highly Phosphorescent Heteroleptic Tris-Cyclometalated Iridium (Ⅲ) Complexes: Synthesis and Photophysical Characterization [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(01): 170-173. |
[7] |
CHEN Zhi-qiang1, 2, CHEN Wen-li1, 2*, YANG Cheng-wei1 . Effects of Exogenous Salicylic Acid on Photosynthesis in Arabidopsis Leaves Based on Fluorescence Spectra and Delayed Fluorescence Technique [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(08): 2208-2212. |
[8] |
CUI Feng-ling,QIN Li-xia,HAO Er-jun,WANG Jun-li,WANG Li,ZHANG Qiang-zhai. Studied on the Determination of Protein by Probe of Zinc 5-Aminosalicylate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(07): 1596-1599. |
[9] |
LIU Hao1,XIANG Bing-ren2*,QU Ling-bo3,XU Jian-ping2 . Structure Analysis of Benzoic Medicines by Near Infrared and Two Dimensional Correlation Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(02): 265-269. |
[10] |
LIN Pei-he1,WANG Si-hong2,CHANG Shu-lan1. Synthesis and Characterization of Doping Terbium-Dichlorosalicylic Acid-N-Phenyl-β-Naphthylamine Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(01): 123-125. |
[11] |
ZHANG Guo-wen1, PAN Jun-hui2, NI Yong-nian3* . Resolution of Synchronous Fluorimetric Spectrum for Carbaryl and Coumaphos and Its Application Study[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(06): 1092-1095. |
[12] |
ZHANG Guo-wen1, NI Yong-nian2*. Synchronous Fluorimetric Determination of the Residues of Three Quinolones in Eel by Partial Least Squares[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(01): 113-116. |
[13] |
DAI Gang, AODENG Gao-wa*. Determination of Enoxacin in Urine by Synchronous Fluorimetry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(10): 1634-1636. |
[14] |
LIN Peng, LIANG Chun-jun, DENG Zhen-bo, BAI Feng , ZHANG Zhi-feng, XIONG De-ping, ZHANG Xi-qing . Luminescence Properties of Rare Earth Complexes Tb(BSA)4[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(06): 828-831. |
[15] |
BAI Feng1, DENG Zhen-bo1*, XU Zheng1, GAO Xin1,LI Yong2, XU Yi-zhuang2, WU Jin-guang2 . The Luminescence Characteristic of a New Novel Coprecipitate Rare Earths Complexes [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(10): 1168-1171. |
|
|
|
|