| 光谱学与光谱分析 |
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| Resonance-Scattering Spectral Determination of H2O2 Using Rhodamine 6G Association Particles |
| LI Zhen-zhong1，JIANG Zhi-liang1*，YANG Guang1，LU Dan1，LIU Shao-pu2 |
1.Department of Resource and Environmental Science, Guangxi Normal University, Guilin 541004, China
2.Institute of Environmental Chemistry, Southwest China Normal University, Chongqing 400715, China |
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Abstract Under the conditions of 0.02 mol·L-1 HCl-4.0×10-4 mol·L-1 KI-1.6×10-5 mol·L-1 Mo(Ⅵ), there is a fluorescence peak at 540 nm and a synchronous fluorescence peak at 540 nm for Rhodamine 6G (RhG).When there exists H2O2, it reacts with I- to form I-3.RhG and I-3 combine to form an ion association particle.The particles exhibit three resonance scattering peaks at 320 nm, 400 and 595 nm respectively.And there is fluorescence quenching at 540 nm.H2O2 concentration in the range of 0.068-34 μg·mL-1 is proportional to the resonance scattering peak at 400 nm.And a new resonance scattering spectral method has been described for the determination of H2O2 in water samples.The spectral results have verified that the formation of (RhG-I3)n association particles and the interface are the main factor that causes the fluorescence quenching and resonance scattering effects.
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Received: 2005-05-20
Accepted: 2004-08-28
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Corresponding Authors:
JIANG Zhi-liang
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| Cite this article: |
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LI Zhen-zhong,JIANG Zhi-liang,YANG Guang, et al. Resonance-Scattering Spectral Determination of H2O2 Using Rhodamine 6G Association Particles [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(08): 1286-1288.
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https://www.gpxygpfx.com/EN/Y2005/V25/I08/1286 |
[1] Hellpointner E, Gab S.Nature, 1989, 337: 631.
[2] Lazrus A LK, Kok G L, Getlin S N，et al.Anal.Chem., 1985, 57(4): 917.
[3] Liu S P，Luo H Q, Liu Z F，et al.Anal.Chem., 2001, 73(16): 3907.
[4] Huang C Z, Li K A, Tong S Y.Anal.Chem., 1996, 68: 2259.
[5] JIANG Zhi-liang, LIU Shao-pu, ZHAO Bao-gang, CHEN Sa, LI Jian(蒋治良，刘绍璞，赵保刚，陈 飒，李 健).Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2002, 22(4): 615.
[6] JIANG Zhi-liang, JIANG Hong-liu, LIU Feng-zhi(蒋治良，江洪流，刘凤志).Chin.J.Appl.Chem.(应用化学)，2003，20(4)： 351.
[7] LIU Bao-sheng, ZHANG Hong-yi, ZHANG Hong-lei, et al(刘保生，张红医，张红蕾，等).Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(2): 229.
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