| 光谱学与光谱分析 |
|
|
|
|
|
| Determination of Trace Manganese by Catalytic Kinetic Spectrophotometry Method with CTMAB as the Sensitizer |
| SONG Gui-lan, REN Hao, LI Guo-bao, YANG Lin |
| School of Chemistry and Chemical Engineering, Jinan University, Ji’nan 250022, China |
|
|
|
|
Abstract A new catalytic spectrophotometric method for the determination of trace amount of Mn(Ⅱ) was developed. The method is based on the oxidation of 7-(2-nitryl-4-methyl phenylazo)-8-hydroxy-qinolin-5-slfonic acid by potassium periodate in the presence of nitrilo triacec acid as an activator and CTMAB as a sensitizer. The wavelengths for the determination was 509 nm.The linear range of determination is 0-3.2×10-9 g·mL-1 for Mn(Ⅱ). The determination limit is 3.8×10-11 g·mL-1. The interference of foreign ions was studied. The method can be used for the determination of Mn(Ⅱ) in mung bean, rice, cereal and soil samples.
|
|
Received: 2005-04-21
Accepted: 2005-08-06
|
|
|
|
Corresponding Authors:
SONG Gui-lan
|
|
| Cite this article: |
|
SONG Gui-lan,REN Hao,LI Guo-bao, et al. Determination of Trace Manganese by Catalytic Kinetic Spectrophotometry Method with CTMAB as the Sensitizer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(08): 1536-1539.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2006/V26/I08/1536 |
[1] Crouch S R, Cullen T F, Scheeline A, et al. Anal. Chem., 1998, 70: 53.
[2] Wei Qin, Du Bin. Talanta, 1998, 45(5): 957.
[3] JIA Xin-xin, QIN Yong-hui(贾欣欣, 秦永惠). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1999, 19(3): 499.
[4] LI Jian-guo, ZHANG Min, ZHAO Kang(李建国, 张 敏, 赵 康). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(7): 870.
[5] WU He-zhou，ZHENG Zhao-sheng, DING Chun-sheng, et al(吴和舟, 郑肇生, 丁春生, 等). Chinese J. Anal. Chem.(分析化学)，1996，24(9): 1085.
[6] XIE Zeng-hong, ZHENG Zhao-sheng, WANG Dan, et al(谢增鸿, 郑肇生, 王 丹, 等). Chinese J. Anal. Chem.(分析化学)，1999, 27(3): 350.
[7] LIN Zhi-fen, ZHENG Zhao-sheng(林志芬, 郑肇生). Chinese J. Anal. Chem.(分析化学)，2000, 28(1): 72.
[8] XIE Zeng-hong, FU Yan-bin, CHEN Guo-nan(谢增鸿, 傅彦斌, 陈国南). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2002, 22(4): 623.
[9] GAO Feng, ZHANG De-xing, GE Zhi-qing, et al(高 峰, 张德兴, 葛治清, 等). Chinese J. Anal. Chem.(分析化学), 2003, 31(10): 1217.
|
| [1] |
LIU Bing-zhi1, LUO Zhi-yong2*, ZHENG Huai-li1, JIANG Lei2 . Study on the Catalytic Kinetic Spectrophotometric Determination of Trace Amounts of Iron(Ⅲ) and Its Reaction Mechanism [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(04): 1139-1144. |
| [2] |
LUO Zhi-yong1, ZHENG Huai-li2 . Determination of Trace Amounts of Nitrite and Its Chemical Reaction Kinetics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(06): 1619-1623. |
| [3] |
LING Xiao,BORJIHAN Ge-rel-tu*,ZHOU Hai-jun,NA Ri-su. Fluorescence Characteristics and Analytical Application of Mn(Ⅱ)-Piperine-Cetyltrimethylammonium Bromide Ternary System[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(01): 188-191. |
| [4] |
LI Hua1, 2,ZHANG Xin-shen3*,ZOU Yu-quan3,XIE Yong-hong3. Study on a New Method for Determining Trace Amounts of Manganese(Ⅱ) in Water by Flow-Injection Catalytic Kinetic Spectrophotometry [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(04): 785-788. |
| [5] |
ZI Yan-qin, LU Hao-miao. Study on Determination of Trace Nitrite and Reaction Mechanism by Two-Wavelength Negative Absorption-Catalytic Spectrophotometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(01): 137-139. |
| [6] |
GUO Liang-qia, LIN Xu-cong, XIE Zeng-hong*, FU Yan-bin. Study on β-Cyclodexdrin Sensitizing Catalytic Kinetic Spectrophotometric Determination of Mn(Ⅱ) [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(10): 1662-1666. |
| [7] |
YU Ping, GAO Jun-jie, SONG En-jun. Kinetic Spectrophotometric Determination of Trace Chromium(Ⅵ) with Sensitized Function of Microemulsion [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(10): 1674-1676. |
| [8] |
SUN Deng-ming,FANG Hua-cai. Determination of Trace Manganese by Non-Organic Solvents Extraction Catalytic Spectrophotometry in Mn(Ⅱ)-H2O2-EBT-PEG-2000 System [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(08): 1315-1317. |
| [9] |
FAN Jing, Lü Hui-xiong, YE Cun-ling,CUI Feng-ling. Speciation Analysis of Selenium by Flow-Injection Catalytic Spectrophotometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(02): 263-265. |
| [10] |
SUN Deng-ming，YOU Yong-li. Extraction Catalytic Spectrophotometric Determination of Trace Chromium by Synergetic Catalytic Effect[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(12): 1643-1645. |
| [11] |
SHA Ren, BAO Di, WU Di, Erdengsang. A Catalytic Kinetic Spectrophotometric Method for Determination of Trace Zinc(Ⅱ) in Mongolian Medicine and Hair Sample [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(12): 1646-1648. |
| [12] |
LI Jian-guo, ZHANG Min, ZHAO Kang . Kinetic-Spectrophotometric Determination of Trace Manganese by IO-4-Tetrabase New System and the Mechanism [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(07): 870-872. |
|
|
|
|
