| 光谱学与光谱分析 |
|
|
|
|
|
| VUV Excited Luminescence of LnZr(BO3)2∶Eu3+(Ln=Ba, Sr) |
| SHEN Fang1, HE Da-wei1*, LIU Hong-li1, XU Jian-hua2 |
1. Laboratory of Material for Information Storage and Display, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China
2. Laboratory of Beijing Synchrotron Radiation, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039, China |
|
|
|
|
Abstract Powder samples of Ba(1-x)SrxZr(BO3)2∶Eu3+(0≤x≤1) were prepared by the conventional solid state reaction method. The excitation spectrum shows a strong absorption in the VUV region with the broad absorption band edge at 130-170 nm due to the host and the f→d transition of Eu3+, and another absorption band of charge-transfer state (CTS) of Eu3+ in the region of 230 nm. The absorption of the charge-transfer band of Eu3+ can be increased by incorporating Al3+ ion into Zr4+ ion lattice. The luminescence of Ba(1-x)SrxZr(BO3)2∶Eu3+ is also increased by incorporating Al3+ into the lattices. In Ba(1-x)SrxZr(BO3)2∶Eu3+, the intensity of the absorption band (130-170 nm) decreases, and the band shifts about 30 nm toward lower energy with x increasing. The emission spectra revealed an intense and sharp (616 nm) red color emission from Eu 3+(5D0→7F2) transition under 147 nm VUV excitation.
|
|
Received: 2005-04-26
Accepted: 2005-08-16
|
|
|
|
Corresponding Authors:
HE Da-wei
|
|
| Cite this article: |
|
SHEN Fang,HE Da-wei,LIU Hong-li, et al. VUV Excited Luminescence of LnZr(BO3)2∶Eu3+(Ln=Ba, Sr) [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(07): 1195-1198.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2006/V26/I07/1195 |
[1] Rao P R, Devine D J. Int. Conference on Luminescence and Optical Spectroscopy of Condensed Matter. Osaka, Japan, 1999, 152.
[2] Hornebecq V, Gravereau P, Chaminade J P, et al. Mater. Res. Bull., 2002, 37: 2165.
[3] Cheng C, Wu Y, Jiang A, et al. J. Opt. Soc. Am., 1989, B6(4): 616.
[4] Koike J, Kojima T, Toyonaga Ryuya, et al. J. Electrochem. Soc., 1979, 126: 1008.
[5] Dorenbos P. J. Lumin., 2000, 91: 91.
[6] HE Hong, LIANG Hong-bin, YU Ying-ning, et al(赫 泓，梁宏斌，于英宁，等). Journal of the Chinese Rare Earth Society(中国稀土学报)，2002，20(6): 556.
[7] ZHANG Shi-ying, WEI Kun(张世英, 魏 坤). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004，24(4): 407.
[8] Belsky A N, Krupa J C. Displays, 1999, 19: 185.
[9] Blasse G, Grabmaier B C. Luminescence Materials. New York: Springer Verlag, 1994, 22.
[10] Shionoya S, et al. Phosphor Handbook. Boca Raton: CRC Press, 1999. 190.
[11] WANG Xi-gui, WU Hong-ying, XIE Da-tao, et al(王喜贵, 吴红英, 谢大弢， 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2002，22(2): 270.
|
| [1] |
YU Hao-zhang, WANG Fei-fan, ZHAO Jian-xun, WANG Sui-kai, HE Shou-jie*, LI Qing. Optical Characteristics of Trichel Pulse Discharge With Needle Plate
Electrode[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3041-3046. |
| [2] |
LIU Hong-wei1, FU Liang2*, CHEN Lin3. Analysis of Heavy Metal Elements in Palm Oil Using MP-AES Based on Extraction Induced by Emulsion Breaking[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3111-3116. |
| [3] |
LIU Pan1, 2, 3, DU Mi-fang1*, LI Bin1, LI Jing-bin1, ZENG Lei1, LIU Guo-yuan1, ZHANG Xin-yao1, 4, ZHA Xiao-qin1, 4. Determination of Trace Tellurium Content in Aluminium Alloy by
Inductively Coupled Plasma-Atomic Emission Spectrometry Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3125-3131. |
| [4] |
TIAN Fu-chao1, CHEN Lei2*, PEI Huan2, BAI Jie-qi1, ZENG Wen2. Diagnosis of Emission Spectroscopy of Helium, Methane and Air Plasma Jets at Atmospheric Pressure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2694-2698. |
| [5] |
ZHANG Zhi-fen1, LIU Zi-min1, QIN Rui1, LI Geng1, WEN Guang-rui1, HE Wei-feng2. Real-Time Detection of Protective Coating Damage During Laser Shock Peening Based on ReliefF Feature Weight Fusion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2437-2445. |
| [6] |
LI Zhi-xiong1, 2, LU Qian-shu1, ZHANG Lian-kai1, 2*, ZHANG Song1, YANG Wan-tao1, LI Can-feng1, FENG Jun1, LIU Zhen-chao1. Study on the Determination of Silver, Boron, Molybdenum, Tin in Geochemical Samples by the Method of Solid Sampling Carrier Distillation Atomic Emission Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2132-2138. |
| [7] |
SI Yu1, LIU Ji1*, WU Jin-hui2, ZHAO Lei1, YAN Xiao-yan2. Optical Observation Window Analysis of Penetration Process Based on Flash Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 718-723. |
| [8] |
YU Cheng-hao, YE Ji-fei*, ZHOU Wei-jing, CHANG Hao*, GUO Wei. Characteristics of the Plasma Plume and Micro-Impulse Generated by
Irradiating the Aluminum Target With a Nanosecond Laser Pulse at
Oblique Incidence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 933-939. |
| [9] |
WANG Wei, WANG Yong-gang*, WU Zhong-hang, RAO Jun-feng, JIANG Song, LI Zi. Study on Spectral Characteristics of Pulsed Argon Vacuum Dielectric
Barrier Discharge[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 455-459. |
| [10] |
LI Ru, YANG Xin, XING Qian-yun, ZHANG Yu. Emission Spectroscopy Study of Remote Ar Plasma[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 394-400. |
| [11] |
HAO Jun1, WANG Yu2, LIU Cong2, WU Zan2, SHAO Peng2, ZU Wen-chuan2*. Application of Solution Cathode Glow Discharge-Atomic Emission Spectrometry for the Rapid Determination of Calcium in Milk[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3797-3801. |
| [12] |
YANG Kun, CHEN Lei*, CHENG Fan-chong, PEI Huan, LIU Gui-ming, WANG Bao-huai, ZENG Wen. Emission Spectroscopy Diagnosis of Air Gliding Arc Plasma Under
Atmospheric Pressure Condition[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3006-3011. |
| [13] |
HU Xuan1, CHENG Zi-hui1*, ZHANG Shu-chao2, SHI Lei2. Matrix Separation-Determination of Rare Earth Oxides in Bauxite by
Inductively Coupled Plasma-Atomic Emission Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3130-3134. |
| [14] |
LIU Pan1, 2, LI Jing-bin1, ZHANG Jian-hao1, ZHANG Yi1, CHANG Guo-liang1, HE Peng-fei1, ZHANG Bin-bin1, ZHANG Xin-yao1, 3. Determination of Phosphorus in Welding Flux by Inductively Coupled Plasma Atomic Emission Spectrometry With Ultrasonic Assisted
Hydrochloric Acid Extraction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2824-2829. |
| [15] |
LI Yan-fei1, 2，HAN Dong1, 2*，QIU Zong-jia1，LI Kang1，ZHAO Yi-kun1, 2，WAN Liu-jie1, 2，ZHANG Guo-qiang1, 2. Characteristic Emission Spectrum Analysis and Discharge Identification on the Development Process of Air Corona Discharge[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2956-2962. |
|
|
|
|
