| 光谱学与光谱分析 |
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| Study on the Characterization of β-Cyclodextrin-Diferrocenylenone Inclusion Complex and Micro-Environmental Effects |
| CHEN Xiao-yan, LIU Wan-yi*, ZHANG Jing |
| Key Laboratory of Energy Sources and Engineering, Ningxia University, College of Chemistry and Chemical Engineering, Yinchuan 750021, China |
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Abstract The structure of the inclusion complex of diferrocenylenone and β-cyclodextrin prepared by a novel method of solid-grinding was studied by UV, FTIR and powder X-ray diffractometry. Continuous variation plot proved that 2∶3(DFE∶β-CD) inclusion complex has been formed. The binding constant of the inclusion compound was found to be 1.48×1015 (L4·mol-4) with the data of UV spectroscopy. Furthermore, the influence of different solvents and pH on the UV spectrum of DFE and β-CD-DFE was discussed respectively. The results show that different micro-environment has apparently different effects on the electric spectra of guest and inclusion complex.
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Received: 2005-04-28
Accepted: 2005-08-08
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Corresponding Authors:
LIU Wan-yi
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| Cite this article: |
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CHEN Xiao-yan,LIU Wan-yi,ZHANG Jing. Study on the Characterization of β-Cyclodextrin-Diferrocenylenone Inclusion Complex and Micro-Environmental Effects[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(07): 1285-1289.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2006/V26/I07/1285 |
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