| 光谱学与光谱分析 |
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| Preparation and Photoluminescence Investigation of Erbium-Doped Zinc Oxide Nanocrystalline |
| SONG Guo-li, SUN Kai-xia |
| Department of Physics, Harbin University, Harbin 150086, China |
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Abstract Er3+-doped zinc oxide nanocrystalline powders were successfully prepared by chemical precipitation method. Photoluminescence spectrum (PL), photoluminescence spectrum excitation(PLE) and X-ray diffraction pattern(XRD) of the nanocrystalline ZnO∶Er3+ with excitation wavelength 365 nm were measured at room temperature. XRD pattern indicates that nanocrystalline ZnO∶Er3+ has a hexagonal wurtzite structure and polycrystallining. The mean grain size of nanocrystalline ZnO∶Er3+ was calculated with Debye-Scherrer formula. The luminescence process of Er3+-doped zinc oxide nanocrystalline was investigated by using PL and PLE. Emissions of S3/2(550 nm)，2H11/2(521 nm) and 4F5/2(456 nm)of Er3+ ions were observed in wide visible band of ZnO. By analyzing the spectrum the effect of Er3+-doping on the luminescence of ZnO was studied. An energy transfer from excited states of ZnO hosts to doping Er3+ ions centers was disclosed by the fact that photoluminescence intensity maximum of nanocrystalline ZnO∶Er3+changed with the doping concentration of Er3+.
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Received: 2005-12-28
Accepted: 2006-06-13
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Corresponding Authors:
SONG Guo-li
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| Cite this article: |
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SONG Guo-li,SUN Kai-xia. Preparation and Photoluminescence Investigation of Erbium-Doped Zinc Oxide Nanocrystalline[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(10): 1806-1809.
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https://www.gpxygpfx.com/EN/Y2006/V26/I10/1806 |
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