光谱学与光谱分析 |
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Synthesis, Characterization and Fluorescent Property of Ternary Complexes of Rare-Earth, Cinnamic Acid and 2,2’-Bipyridine |
YANG Yong-li, DENG Yu-heng*,NIE Feng-mei,WANG Shao-ting, ZONG Rui-fa |
Department of Chemistry,Capital Normal University,Beijing 100037,China |
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Abstract The ternary rare-earth complexes were synthesized using cinnamic acid (L), 2,2’-bipyridine (bipy) and rare-earth (RE= Tb, Eu, Gd, Nd) in ethanol solution. Their compositions were confirmed to be REL3·bipy by the element analysis, infrared and ultraviolet absorption spectra, and DTA-TGA, respectively. The spectral properties of complexes and the fluorescent property of EuL3·bipy were discussed. The fluorescence intensity of EuL3 is 4.5 times stronger than that of EuL3·bipy·H2O.
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Received: 2005-09-22
Accepted: 2005-12-28
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Corresponding Authors:
DENG Yu-heng
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Cite this article: |
YANG Yong-li,DENG Yu-heng,NIE Feng-mei, et al. Synthesis, Characterization and Fluorescent Property of Ternary Complexes of Rare-Earth, Cinnamic Acid and 2,2’-Bipyridine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(04): 663-665.
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URL: |
https://www.gpxygpfx.com/EN/Y2006/V26/I04/663 |
[1] YANG Lu-dong, WU Jin-guang(杨鲁栋,吴谨光). Acta Chimica Sinica(化学学报), 1996, 54: 374. [2] YANG Hong, WANG Ze-min, YU Xi-bin, et al(杨 红, 王则民, 余锡宾, 等). Journal of Shanghai Teachers University(Natural Sciences) (上海师范大学学报·自然科学版), 2002, 31(1): 51. [3] ZHAO You-liang, ZHAO Feng-ying. Journal of Rare Earths, 2000, 18(4): 318. [4] XIE Xiao-mei, ZENG Zheng-zhi(谢晓梅,曾正志). Journal of Lanzhou University(Natural Sciences)(兰州大学学报·自然科学版), 2003, 39(2): 64. [5] Geary W J. Coordination Chemistry Review, 1971, 7: 81. [6] Nakamoto K(中本一雄), Translated by HUANG De-ru, WANG Ren-qing(黄德如, 王仁庆译). Infrared and Raman Spectra of Inorganic Coordination Compounds(无机和配位化合物的红外和拉曼光谱·第2版). Beijing: Chemical Industry Press(北京:化学工业出版社), 1986. 231,237. [7] YANG Lu-qin, YANG Ru-dong(杨鲁勤,杨汝栋). Acta Chemia Sinica(化学学报), 1989, 47: 911.
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