| 光谱学与光谱分析 |
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| Synthesis and Infrared Spectroscopic Study of 1-D Magnetic Chain Compound Based on [BrBzPy][Ni(dmit)2] |
| CHEN You-cun, SHU Qing-hai |
| Department of Chemistry, Anqing Normal College, Anqing 246011, China |
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Abstract The synthesis and functional study of one-dimensional free radical-metal chain compound has been a hotspot task in molecule material, especially in composing high TC molecule ferromagnet. A new compound [BrBzPy][Ni(dmit)2] has been prepared and characterized. The crystal structure at room temperature was determined. The crystal is triclinic with space group P21/c，a=0.627 5(1) nm，b=1.743 8(3) nm，c=2.283 9(3) nm，α=90°，β=91.87(1)°，γ=90°，V=2.497(7) nm3，Z=4，Mr=700.57，and Dc=1.863 g·cm-3. The planar [Ni(dmit)2]- is nearly perfect, which shows that it has good conjugate characteristic and is a 1-D magnetic chain compound.
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Received: 2004-11-09
Accepted: 2005-02-15
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Corresponding Authors:
CHEN You-cun
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| Cite this article: |
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CHEN You-cun,SHU Qing-hai. Synthesis and Infrared Spectroscopic Study of 1-D Magnetic Chain Compound Based on [BrBzPy][Ni(dmit)2] [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(01): 54-56.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2006/V26/I01/54 |
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