| 光谱学与光谱分析 |
|
|
|
|
|
| Determination of Norfloxacin by Flow-Injection Chemiluminescence |
| LIAO Su-lan1, 2, XIE Zeng-hong1* |
1. Department of Chemistry, Fuzhou University, Fuzhou 350002，China
2. Nanping Teachers College, Nanping 353000，China |
|
|
|
|
Abstract Sodium dodecylsulfate(SDS) can greatly enhance the emission intensity of the weak chemiluminescence reaction of Ce(Ⅳ) with norfloxacin(NFLX) in acid medium. Based on this phenomenon, a simple and rapid new method for the continuous determination of norfloxacin was developed. The calibration graph is linear for 7.78×10-8-5.82×10-6 g·mL-1, the detection limit(3σ) is 1.57×10-8 g·mL-1, and the relative standard deviation (n=10, c=1.94×10-6 g·mL-1) is 1.7%. The method was successfully applied to the determination of norfloxacin in capsules. Additionally, the system’s mechanism was discussed.
|
|
Received: 2004-09-02
Accepted: 2004-12-16
|
|
|
|
Corresponding Authors:
XIE Zeng-hong
|
|
[1] Ito A, Hirai K, Inoue M, et al. Antimicrob. Agents Chemother., 1980, 17(2): 103.
[2] Sultan S M, Suliman F E O. Analyst, 1993, 118: 573.
[3] Vílchez J L, Ballesteros O, Taoufiki J, et al. Anal. Chim. Acta, 2001, 444: 279.
[4] LI Jian-qing, FENG Xiao-hua, DONG Chuan(李建晴, 冯小花, 董 川). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(2): 311.
[5] Rahman N, Ahmad Y, Hejaz Azmi SN. Eur. J. Pharm. Biopharm., 2004, 57(2): 359.
[6] Mascher H J, Kikuta C. J. Chromatogr. A, 1998, 812: 381.
[7] Wallis S C, Charles B G, Gahan L R. J. Chromatogr. B, 1995, 674: 306.
[8] Rao Y, Tong Y, Zhang X R, et al. Anal. Lett., 2000, 33: 1117.
[9] Aly F A, Al-Tamimi S A, Alwarthan A A. Talanta, 2001, 53: 885.
[10] LIAN Ning, SUN Chun-yan, ZHAO Hui-chun(连 宁, 孙春燕, 赵慧春). Journal of Analytical Science(分析科学学报), 2002, 18(2): 111.
[11] CHEN Guo-nan, ZHANG Fan(陈国南, 张 帆). Chemiluminscence and Bioluminescence-Theory and Application(化学发光与生物发光——理论及应用). Fuzhou: Fujian Science and Technology Press(福州: 福建科技出版社), 1998. 265.
[12] Wolkoff A W, Larose R H. Anal. Chem., 1975, 47: 1005. |
| [1] |
BAI Jun-peng1, 2, LI Bin1*, ZHANG Shu-juan2, CHEN Yi-mei1. Study on Norfloxacin Concentration Detection Based on Terahertz Time Domain Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2710-2716. |
| [2] |
ZHENG Pei-chao, ZHONG Chao, WANG Jin-mei*, LUO Yuan-jiang, LAI Chun-hong, WANG Xiao-fa, MAO Xue-feng. Evaluation of Flow Injection-Solution Cathode Glow Discharge With an Interference Filter Wheel for Spectral Discrimination[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 842-847. |
| [3] |
ZHOU Ying1, BAI Yong-hui1, SONG Xu-dong1*, YAO Min3, WANG Jiao-fei1, SU Wei-guang1, YU Guang-suo1,2*. Application of Chemiluminescence in Spectral Diagnosis: A Review[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3358-3364. |
| [4] |
ZHANG Jing1, GAO Xuan1, 2, JIN Liang1, WANG Hong-hui1, ZHOU Xi-ping1. Comparisons and Applications of Functional Equations for the Calculation of the Protein-Ligand Binding Constant Based on Fluorescence Spectral Data[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3494-3498. |
| [5] |
WU Sheng-yang1,2, HU Ren-zhi1,2*, XIE Pin-hua1,2, LI Zhi-yan1,2, LIU Xiao-yan3, LIN Chuan1,4, CHEN Hao1,2, WANG Feng-yang1,2, WANG Yi-hui1,5, JIN Hua-wei1,2. Real-Time Measurement of NOy （Total Reactive Nitrogen Oxide） by Cavity Ring Down Spectrometer (CRDS)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1661-1667. |
| [6] |
LIU Yao, TAN Jian-guo*, GAO Zheng-wang. College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1018-1022. |
| [7] |
WANG Zhong-yuan1, ZHANG Hong-kang2*, NI Zhi-xin1, LIU Jing-qin1, CHEN Xin1, LI Sheng-yong1, YANG Qi-jin2, ZHANG Can1. FI-KR-FAAS Twice Gas Isolation Elution Method for the Determination of Trace Lead in Marine Biological Samples[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3578-3582. |
| [8] |
CAO Xuan1,2, CHU Dong-zhi1,2, LIU Yan1,2*, MA Ran1,2, ZHANG Shu-wei1,2, WU Ning1,2, SHI Qian1,2, MA Hai-kuan1,2. An On-Line Microfluidic Analysis System for Seawater Chemical Oxygen Demand Using Ozone Chemiluminescence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3698-3702. |
| [9] |
AN Xue-jing, LUO Yun-jing*, ZHANG Chen-yang. Research on the Reaction Dynamics between Peroxynitrite and Tyrosine Catalyzed with Mimic Enzyme through Flow Injection Analyzer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(12): 4052-4057. |
| [10] |
ZHENG Zhi-yuan1, 2, 3, DU Yu-zhi1, 2, ZHANG Ming1, 2, 3, YU Ming-jie1, 2, 3, LI Cen1, 2, 3, YANG Hong-xia1, 2, ZHAO Jing1, 2, 3, XIA Zheng-hua1, 2, 3, WEI Li-xin1, 2*. Study on Content Determination of Lead and Arsenic in Four Traditional Tibetan Medicine Prescription Preparations by Wet Digestion Flow Injection-Hydride Generation-Atomic Absorption Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(04): 1037-1042. |
| [11] |
CAO Jun-tao1, WANG Hui1, CHEN Yong-hong2, LIU Yan-ming1* . Sensitive Determination of Hemoglobin in Human Blood and Serum by Flow Injection Coupled with Chemiluminescence Detection [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(01): 241-245. |
| [12] |
CUI Jian1, 2, ZHAO Xue-hong1*, WANG Yan1, XIAO Ya-bing3, JIANG Xue-hui1, DAI Li1 . Research on Optimization of Mathematical Model of Flow Injection-Hydride Generation-Atomic Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(01): 246-251. |
| [13] |
DU Jun-jun1, WANG Hui1, REN Shu-wei2, ZHOU Min1, LIU Ying-ying1, LIU Yan-ming1* . Sensitive Determination of Bovine Serum Albumin by Flow-Injection Chemiluminescence [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(06): 1693-1696. |
| [14] |
WANG Zhong-yuan1, ZHANG Hong-kang2*, FANG Hong-da1, SU Yao-dong3, Gauri S Mittal4 . FI-KR Non-Separated Method Coupled with FAAS for the Determination of Fe(Ⅱ) and Fe(Ⅲ) in Water [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(03): 817-820. |
| [15] |
FENG Ting, HU Yu-fei*, LI Gong-ke*. A Novel Flow Injection Chemiluminescence Method with Ferricyanide and Luminol for the Determination of Ractopamine in Biological Samples [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(01): 74-77. |
|
|
|
|
