| 光谱学与光谱分析 |
|
|
|
|
|
| Raman and PL Spectra Studies of Natural and HPHT Synthetic Diamonds |
| YANG Zhi-jun, LI Hong-zhong, ZHOU Yong-zhang, WANG Xiao-yue, LUO Feng |
| Department of Geoscience, Sun Yat-sen University, Guangzhou 510275, China |
|
|
|
|
Abstract Investigations of crystal habit, quality and defects analysis of natural diamond and HPHT synthetic diamonds from Fe-C(H) and Ni-C system by Raman and PL spectra indicate that most of the diamonds from Fe-C(H) system have an octahedral habit which is the main habit in natural diamond, while most of the diamonds from Ni-C system have a hexakisoctahedral habit. Because there are more photoluminescence centers in synthetic diamond from Ni-C system than that from Fe-C(H) system, and in synthetic diamond than in natural diamond, the quality of natural diamond is best though it forms in more polygenic environment, which suggested that during the process of diamond formation clearing “impurity” must occur. Therefore, the authors believe that not only the substance system variance but also time and space conditions for diamond formation should be considered when the authors try to probe into the relations of formation process between natural and HPHT synthetic diamonds.
|
|
Received: 2008-11-16
Accepted: 2009-02-18
|
|
|
|
Corresponding Authors:
YANG Zhi-jun
E-mail: yangzhj@mail.sysu.edu.cn
|
|
[1] Barnard A S, DipDT F G A A. The Diamond Formula: Diamond Synthesis-a Gemological Perspective. Oxford: Reed Educational and Professional Publishing Ltd., 2000. 3.
[2] Field J E. The Properties of Natural and Synthetic Diamond. London: Academic Press, 1992. 345.
[3] YANG Zhi-jun, PENG Ming-sheng, MENG Yu-fei, et al(杨志军，彭明生，蒙宇飞，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2007，27(6): 1066.
[4] YANG Zhi-jun, LI Hong-zhong, PENG Ming-sheng, et al(杨志军, 李红中, 彭明生, 等). Chinese Science Bulletin(科学通报), 2008, 53(1): 137.
[5] YANG Zhi-jun, LIN Feng, LI Hong-zhong, et al(杨志军，林 峰，李红中，等). Superhard Material Engineering(超硬材料工程)，2007，19(1): 1.
[6] Dementjev A P, Petukhov M N. Diamond and Related Materials, 1997, 6: 486.
[7] Kindlein W Jr., Livi R P, Balzaretti N M, et al. Diamond and Related Materials, 2000, 9: 22.
[8] Herch H, Cappelli M A. Physical Review B, 1994, 49(5), 3213.
[9] Zaitsev A M. Optical Properties of Diamond-A Data Handbook. Berlin Heidelberg: Springer-Verlag, 2001. 141.
[10] Yelisseyev A, Babich Yu, Nadolinny V, et al. Diamond and Related Materials, 2002, 11: 22.
[11] Collins A T. Diamond and Related Materials, 2000, 9: 417.
[12] Iakoubovskii K, Adriaenssens G J. Journal of Physics: Condensed Matter, 2002, 14: L95.
[13] Davies G, Lawson S C, Collins A T, et al. Physical Review B, 1992, 46(20): 13157.
[14] Yelisseyev A P, Steeds J W, Babich Y N, et al. Diamonds & Related Materials, 2006, 15: 1886. |
| [1] |
FENG Xiang-yu, JIANG Na, WANG Wei, LI Meng-qian, ZHAO Su-ling*, XU Zheng. One-Step Synthesis of Sulfur Quantum Dots and Electroluminescent Properties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1569-1574. |
| [2] |
WANG Jin-mei, HE Shi, ZHANG Hang-xi, YANG Chen, YIN Yi-tong, ZHANG Li, ZHENG Pei-chao*. Study on the Detection Method of Nitrate Nitrogen in Water Based on
Ultraviolet Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1037-1042. |
| [3] |
LI Guo-hua1, ZHANG Zhen-rong1, YE Jing-feng1, WANG Sheng1, FANG Bo-lang1, SHAO Jun1, HU Zhi-yun1, 2. Measurement of OH Distribution in Kerosene Combustion Based on
Fluorescence Spectrum Discrimination[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 401-404. |
| [4] |
LI Ai-min1, FAN Meng2*, QIN Guang-duo2, WANG Hai-long2, XU You-cheng2. Water Quality Parameter COD Retrieved From Remote Sensing Based on Convolutional Neural Network Model[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 651-656. |
| [5] |
GAO Xi-ya1, 2, 3, ZHANG Zhu-shan-ying1, 2, 3*, LU Cui-cui1, 2, 3, MENG Yong-ji1, 2, 3, CAO Hui-min1, 2, 3, ZHENG Dong-yun1, 2, 3, ZHANG Li1, 2, 3, XIE Qin-lan1, 2, 3. Quantitative Analysis of Hemoglobin Based on SiPLS-SPA
Wavelength Optimization[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 50-56. |
| [6] |
OUYANG Ai-guo, YU Bin, HU Jun, LIN Tong-zheng, LIU Yan-de. Grade Evaluation of Grain Size in High-Speed Railway Wheel Steel Based on Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3428-3434. |
| [7] |
FU Hong-bo1, WU Bian1, WANG Hua-dong1, ZHANG Meng-yang1, 2, ZHANG Zhi-rong1, 2*. Quantitative Analysis of Li in Lithium Ores Based on Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3489-3493. |
| [8] |
WANG Zi-min1, MAO Xiao-tian1, YIN Zuo-wei1*, CHEN Chang2, CHENG Tian-jia1. Study on the Spectral Characteristics and the Color-Change Effect of Spinel[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3541-3545. |
| [9] |
JUMAHONG Yilizhati1, 2, TAN Xi-juan1, 2*, LIANG Ting1, 2, ZHOU Yi1, 2. Determination of Heavy Metals and Rare Earth Elements in Bottom Ash of Waste Incineration by ICP-MS With High-Pressure Closed
Digestion Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3168-3173. |
| [10] |
WANG Xi1, CHEN Gui-fen1,2*, CAO Li-ying1, MA Li1. Study on Maize Leaf Nitrogen Inversion Model Based on Equivalent Water Thickness Gradient[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2913-2918. |
| [11] |
ZHU Xiang1, 2*, YUAN Chao-sheng1, CHENG Xue-rui1, LI Tao1, ZHOU Song1, ZHANG Xin1, DONG Xing-bang1, LIANG Yong-fu2, WANG Zheng2. Study on Performances of Transmitting Pressure and Measuring Pressure of [C4mim][BF4] by Using Spectroscopic Techniques[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1674-1678. |
| [12] |
ZHANG Jun-yi1, 2, GAO De-hua1, SONG Di1, QIAO Lang1, SUN Hong1, LI Min-zan1*, LI Li1. Wavelengths Optimization and Chlorophyll Content Detection Based on PROSPECT Model[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1514-1521. |
| [13] |
JIANG Xiao-yu1, 2, LI Fu-sheng2*, WANG Qing-ya1, 2, LUO Jie3, HAO Jun1, 2, XU Mu-qiang1, 2. Determination of Lead and Arsenic in Soil Samples by X Fluorescence Spectrum Combined With CARS Variables Screening Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1535-1540. |
| [14] |
YE Shuang1, CHEN Mei-hua1*, WU Gai2, HE Shuang1. Spectroscopic Characteristics and Identification Methods of Color-Treated Purplish Red Diamonds[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 191-196. |
| [15] |
YANG Zhi-jun1,2, MAO Meng-ai1, HUANG Yi-cong1, ZHANG Jia-wei1. Study on the Surface Morphology and Its Vibrational Spectra of Diamond From the Western Yangtze Craton[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 236-242. |
|
|
|
|
