|
|
|
|
|
|
| Properties and Mechanism of Shield Powder/Rubber Compatibilizer
Composites Based on Spectroscopic Analysis |
| YU Xian-kun1, 2, 4, XU Wei-cheng1, ZHANG Hao1, 2, 3*, WU Yu-xi1, LI Hai-li3, LONG Hong-ming1, 2, CHENG Zheng-ming5, LIU Zi-min6, RONG Bei-guo7, ZHANG Gui-wen8 |
1. Key Laboratory of Metallurgical Emission Reduction and Comprehensive Utilization of Resources, Ministry of Education (Anhui University of Technology), Ma'anshan 243002, China
2. School of Metallurgical Engineering, Anhui University of Technology, Ma'anshan 243032, China
3. School of Civil Engineering and Architecture, Anhui University of Technology, Ma'anshan 243032, China
4. Sinosteel Maanshan Institute of Mining Research Co., Ltd., Ma'anshan 243000, China
5. Shougang Jingtang United Iron & Steel Co., Ltd., Tangshan 063200, China
6. Ma'anshan Iron & Steel Co., Ltd., Ma'anshan 243003, China
7. Guilin Hongcheng Mining Equipment Manufacture Co., Ltd., Guilin 541002, China
8. Jiangsu Hua'an Rubber Technology Co., Ltd., Suqian 223600, China
|
|
|
|
|
Abstract Calcium carbonate is an important inorganic filler in rubber production, with capacity building and reinforcement functions.With the growing demand for rubber in China, calcium carbonate usage is expanding, and its production costs and energy consumption are becoming increasingly problematic.Steel slag is a byproduct of the steelmaking process and has problems such as low utilization and large accumulation.The main components of steel slag are CaO, SiO2, FexOy, Al2O3, etc. The physical and chemical properties of steel slag are similar to those of traditional fillers, and the wear resistance and porosity of steel slag are excellent, so the use of steel slag to replace some calcium carbonate as a rubber filling material not only has important research significance but also can alleviate the problems of energy consumption and environmental pollution. Based on this, this study used the combined treatment of steel slag with homemade functional compound and ultra-fine vertical mill to obtain a sample shield powder with a particle size of 800 and prepared shield powder/rubber bulking composites with different dosage ratios of active calcium carbonate to shield powder.The prepared shield powder/rubber bulking composites were tested for their properties using an intelligent volcano meter, an electronic tensiometer, a rubber hardness tester and a microcalorimeter (MCC), and the shield powder/rubber bulking composites were characterized and analyzed by thermogravimetric analysis-Fourier transform infrared spectrometer (TG-FTIR) and Raman spectrometer (Ram).The results show that replacing part of active calcium carbonate by shield powder has a certain promotion effect on the vulcanization performance of the rubber system and can improve the vulcanization speed of shield powder/rubber capacitated composites.The addition of shield powder can improve the compound rubber system's mechanical and flame retardant properties. Analysis of the shield powder/rubber bulking composites by microcalorimetry and Raman spectroscopy revealed that the heat release capacity and total heat release of the rubber system after the replacement of part of active calcium carbonate by shield powder decreased, and the graphitization of carbon residue increased, further indicating that the replacement of part of active calcium carbonate by shield powder also has certain flame retardant properties while ensuring the physical properties of the shield powder/rubber bulking composites. Thermogravimetric-infrared analysis shows that the gas produced during the cracking of the shield powder/rubber capacitated composite is mainly hydrocarbons. Adding a home-made functional compound can alleviate the incompatibility of the steel slag interface with the rubber interface and optimise the rubber composite.The above study provides data and theoretical support for preparing shield powder/rubber bulking composites with better performance.
|
|
Received: 2022-08-29
Accepted: 2022-11-16
|
|
|
|
Corresponding Authors:
ZHANG Hao
E-mail: fengxu19821018@163.com
|
|
[1] Gu J, Zhou Y, Jia D, et al. Synthtrc Rubber Industry, 2004, 27(2): 106.
[2] Phuhiangpa N, Phongphanphanee S, Smitthipong W. IOP Conference Series: Materials Science and Engineering, 2020, 773: 012013.
[3] YANG Jin-tao, FAN Hong, BU Zhi-yang, et al(杨晋涛, 范 宏, 卜志扬，等). Acta Materiae Compositae Sinica（复合材料学报），2005, 22(2): 38.
[4] Abdelaziz M, Abdelrazek E M. Journal of Materials Science: Materials in Electronics, 2014, 25(12): 5481.
[5] Liu M D, Jia K, Liu X B. Journal of Polymer Research, 2014, 21(11): 570.
[6] Kang L, Du H L, Zhang H, et al. Complexity, 2018, 10: 8.
[7] Xiang L, Xiang Y, Wang Z G, et al. Powder Technology, 2002, 126: 129.
[8] Zhang H. Ceramics International, 2020, 46(7): 9972.
[9] Zhang H, Li Z H. Open Medicine, 2019, 14: 673.
[10] Zhang Y J, Kang L, Liu L C, et al. Applied Surface Science, 2015, 331: 399.
[11] Zhang H, Fang Y. Journal of Alloys and Compounds, 2019, 781: 201.
[12] Hou X J, Wang Y, Yang Y L, et al. Energy, 2019, 188: 116081.
[13] ZHANG Hao, LI Hai-li, LONG Hong-ming, et al（张 浩, 李海丽, 龙红明, 等）. Spectroscopy and Spectral Analysis（光谱学与光谱分析）, 2021, 41(4): 1138.
[14] Meng Y, Yan T, Muhammad Y, et al. Journal of Cleaner Production, 2022, 338: 130563.
[15] Huang Q X, Liu T Y, Zhang J S, et al. Construction and Building Materials, 2020, 253: 118870.
|
| [1] |
XU Xiu-ping1, 3, XU Wei-cheng2, YU Xian-kun1, 3, CHEN Yu4, YANG Gang5, ZHANG Hao1, 2, 6*. The Kinetic Mechanism of Nickel and Lead Adsorption by Converter Steel Slag Powder Was Studied Based on ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(02): 594-600. |
| [2] |
HU Wen-feng1, 2, TANG Wei-hao1, LI Chuang1, WU Jing-jin1, MA Qing-fen1, LUO Xiao-chuan1, WANG Chao2, TANG Rong-nian1*. Estimating Nitrogen Concentration of Rubber Leaves Based on a Hybrid Learning Framework and Near-Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2050-2058. |
| [3] |
SUN Da-wei1, 2, 3, DENG Jun1, 2*, JI Bing-bing4. Study on the Preparation Mechanism of Steel Slag-Based Biomass Activated Carbon by Special Steel Slag-Discard Walnut Shells Based on ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2308-2312. |
| [4] |
ZHANG Hao1, 2, HAN Wei-sheng1, CHENG Zheng-ming3, FAN Wei-wei1, LONG Hong-ming2, LIU Zi-min4, ZHANG Gui-wen5. Thermal Oxidative Aging Mechanism of Modified Steel Slag/Rubber Composites Based on SEM and FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3906-3912. |
| [5] |
XUE Xin-xin, WANG Wen-bin, LUO Xue-hua, ZHANG Yong-fa, ZHAO Chun-mei. FTIR Spectroscopic Characterization of Material Composition in Leaf of Hevea Brasiliensis Seedlings Under Potassium and Magnesium Deficiency[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 74-79. |
| [6] |
ZHANG Hao1, 2, 4, LI Hai-li1, LONG Hong-ming2, 4, LIU Zi-min3, ZHANG Yao-hui3, ZHENG Wei-cheng4. Spectroscopic Analysis of Reinforcing-Flame Retardant Mechanism of Modified Steel Slag-Mineral Powder Composite Rubber Filler[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(04): 1138-1143. |
| [7] |
LI Jing-jing1, 2, WU Hao-rong1, ZHANG Xiao-dong1, YU Lan1*. Study on X-Ray Photoelectron Spectroscopy of High-Temperature Vulcanized Silicone Rubber Accelerated Aging by Ultraviolet Radiation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 720-726. |
| [8] |
YIN Xian-hua1, 2, LIU Yu1, 2, FENG Mu-lin1, 2, LI An3, MO Wei1*. Separation of Tire Rubber Overlapping Terahertz Spectra Using Non-Negative Matrix Factorization of Spectral Feature Constraints[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3736-3742. |
| [9] |
LI Jing-jing1,2, ZHANG Hui-hui1, LI Guo-fang1, ZHANG Shan-gang3, LIU Yan1, DONG Kun1, ZU En-dong1, YU Lan1*. Aging Mechanism Analysis of High Temperature Vulcanization Silicone Rubber Irradiated by Ultraviolet Radiation Based on Infrared Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1063-1070. |
| [10] |
ZHANG Hao1,2, FAN Wei-wei1. Spectroscopic Analysis of Activated Carbon Mixed with Steel Slag Composite Material in Sintering Flue Gas of Desulfurization and Denitration[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1195-1200. |
| [11] |
ZHANG Hao1, 2, 3, ZHANG Lei3, LONG Hong-ming1, 2*. Spectroscopic Analysis of Preparation of Ecological Activated Carbon Based on Electric Furnace Slag Ultrafine Powder Modified Biomass Waste Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(03): 861-866. |
| [12] |
ZHANG Hao1,2, ZHANG Lei1, LIU Xiu-yu1. Study on Preparation Stage and Mechanism of Modified Desulfurization Ash-Based Eco Rubber by X-Ray Diffraction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(02): 616-621. |
| [13] |
YIN Xian-hua1, 2, GUO Chao1, 2, LI An3, MO Wei1*. Application of Zernike Moment in Terahertz Spectrum Quantitative Analysis of Rubber Additives[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(09): 2725-2731. |
| [14] |
ZHANG Hao1,2, LIU Ying1. Study on Reinforcement Mechanism of Composite Rubber Using Modified Desulfurization Ash Replacing Partial Carbon Black by FTIR and XRD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(07): 2067-2072. |
| [15] |
CHEN Ping1, WANG Xi-lin1, HONG Xiao2, WANG Han3, ZHAO Chen-long1, JIA Zhi-dong1, ZOU Lin2, LI Yan-min4, FAN Jian-hua4. Influence of Sample Surface Roughness on Signal of Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(06): 1929-1934. |
|
|
|
|
