| 光谱学与光谱分析 |
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| TLC-SERS Study on Evodiamine in Evodia Rutaecarpa |
| ZHANG Jin-zhi1,WANG Yuan2,CHEN Hui2,SHAO Hui-bo2 |
1. North University of Technology, Beijing 100041, China
2. Department of Chemistry, Capital Normal University, Beijing 100037, China |
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Abstract A new method for analyzing the ingredients of evodiamine(EV), rutaecarpine(RU), hydroxyevodiamine(HYD), evodiamide(ED), dihydrorutaecarpine(DRU) and 14-formyldihydrorutaecarpine(FDRU)in evodia rutaecarpa using high performance thin layer chromatography (TLC) and surface enhanced Raman spectroscopy (SERS) technique is reported. The character of this method is that standard samples are not needed . The results show that the characteristic spectral bands of EV, RU, HYD, and ED can be obtained from the TLC spot with microgramme of sample. The spectral band at 1 562 cm-1 was obtained with great enhancement. Molecule absorbed in surface silver sol by π electrons in ring. The spectral bands of EV, RU, HYD and ED are obviously different due to their differences in structure. The TLC and SERS techniques standard samples are a convenient and speedy method to analyze chemical ingredients with high sensitivity for the study of the Chinese traditional medicine.
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Received: 2006-05-06
Accepted: 2006-09-08
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Corresponding Authors:
ZHANG Jin-zhi
E-mail: zhangjzh@ncut.edu.cn
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