| 光谱学与光谱分析 |
|
|
|
|
|
| Synthesis and Catalytic-Isomerization Performance of Al-MCM-41 Mesoporous Sieves |
| GUO Jian-wei1,LI Long-huan1,LIU Sa2,CUI Yi-hua1,DENG Zhi-cheng1,YU Lin1 |
1. Department of Chemical Engineering,Guangdong University of Technology，Guangzhou 510006,China
2. College of Material Science and Engineering,South China University of Technology,Guangzhou 510640,China |
|
|
|
|
Abstract Al-MCM-41 mesoporous sieves were synthesized at the ambient temperature by using TEOS as silica source,Al(NO)3·9H2O as Al source,and cetyl trimethylammonium bromide as templating agent. The framework and surface structures of the synthesized samples were characterized by XRD,N2-adsorption/ desorption isotherms,FTIR and SEM etc. The results showed that the samples were the typical Al-MCM-41 mesoporous sieves with the higher ordered-degree and specific surface area (up to 816 m2·g-1) and the narrower pore diameter distribution. Controlling the highest value of Al/Si with the range of 0.06-0.13,and taking temperature programmed calcination would be beneficial to the formation of the highly ordered Al-MCM-41 mesoporous sieves. The evaluating results showed that the synthesized Al-MCM-41 molecular sieves have a higher catalytic activity for isomerization of endo-tetrahydrodicyclo-pentadiene (endo-TCD) into exo-tetrahydrodicyclo- pentadiene (exo-TCD) and adamantane.
|
|
Received: 2006-05-08
Accepted: 2006-08-18
|
|
|
|
Corresponding Authors:
GUO Jian-wei
E-mail: doctorgjw@163.com
|
|
| Cite this article: |
|
GUO Jian-wei,LI Long-huan,LIU Sa, et al. Synthesis and Catalytic-Isomerization Performance of Al-MCM-41 Mesoporous Sieves[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(07): 1368-1371.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2007/V27/I07/1368 |
[1] Beck J S,Varrwli J E,et al. J. Am. Chem. Soc.,1992，114: 10834.
[2] Twigg M V. Catalyst Handbook，2nd. ED,Wolfe Publishing Ltd.,1990. 284.
[3] Chen Changlin，Li Tao，Cheng Soofin，et al. Microporous and Mesoporous Materials，2001,50： 201.
[4] Karakassides M A，Fournaris K G，Atravlos D Petridis. Adv. Mater.,1998，10： 483.
[5] Tuel A. Microporous and Mesoporous Materials，1999,27: 151.
[6] HUO Yong-qian，LI Jun，WANG Wei，et al(霍涌前，李 珺，王 伟，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2004,24(3): 281.
[7] Selvaraj M,Sinha P K,Pandurangan A. Microporous and Mesoporous Materials，2004,70: 1.
[8] Selvaraj M,Pandurangan A,Seshadri K S,et al. Journal of Molecular Catalysis A: Chemical,2003,192: 153.
[9] GUO Jian-wei,CUI Ying-de,MI Zhen-tao,et al(郭建维，崔英德，米镇涛，等). Chinese J. of Catalysis(催化学报)，2001,22(3)： 271. |
| [1] |
HU Shuang1, LIU Cui-mei2*, JIA Wei2, HUA Zhen-dong2. Rapid Qualitative Analysis of Synthetic Cannabinoids by Raman
Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 145-150. |
| [2] |
LIU Yu-ying1, 2, WANG Xi-yuan1, 2*, MEI Ao-xue1, 2. Green Preparation of Biomass Carbon Quantum Dots for Detection of Cu2+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 248-253. |
| [3] |
WANG Chong1, WANG Jing-hua1, 2, LI Dong-dong1, SHE Jiang-bo2. Preparation of Gd3+-Doped LiYF4∶Yb3+/Ho3+ Micro-Crystal and the Application Research in Anti-Counterfeiting[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3581-3587. |
| [4] |
WANG Yan-ru, TANG Hai-jun*, ZHANG Yao. Study on Infrared Spectral Detection of Fuel Contamination in Mobil Jet Oil II Lubricating Oil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1541-1546. |
| [5] |
YANG Yan-ling1, Andy Hsitien Shen1, FAN Yu-rong2, HUANG Wei-zhi1, PEI Jing-cheng1*. UV-Vis-NIR Spectroscopic Characteristics of Vanadium-Rich
Hydrothermal Synthetic Emeralds From Russia[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1199-1203. |
| [6] |
ZHANG Jia-lin, ZHANG Qian, PEI Jing-cheng*, HUANG Wei-zhi. Gemological and Spectroscopy Characteristics of Synthetic Blue-Green Beryl by Hydrothermal Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2258-2262. |
| [7] |
WANG Chong1, MO Jian-ye1，2, LI Dong-dong1, SHE Jiang-bo2, LIU Zhen2. Application and Research of NaYF4∶Yb3+/Eu3+ Upconverting Luminescent Micro-Nano Particles in Anti-Counterfeiting Identification[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1525-1529. |
| [8] |
WANG Shi-xia, HU Tian-yi, YANG Meng. Study on Preparation of Ag-Doped ZnO Nanomaterials and Phase Transition at High Pressure Using Diamond Anvil Cell and Raman Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 484-488. |
| [9] |
WANG Zhi-wei1, 2, 3, YUE Guang-yang1*, WU Xiao-dong1, ZHANG Wen2, WANG Pu-chang2, SONG Xue-lian2, WU Jia-hai2. A Study on Ground Deformations Monitoring in Tianshan Mountain of Xinjiang on Active Microwave Spectral Imagines[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(08): 2366-2372. |
| [10] |
XIONG Yang1,2, XU Jun1,2, QIU Su-yan1,2, WEI Yi-hua1,2, ZHANG Jin-yan1,2*. Study on Interaction Between Phenylethanolamine A and CdTe Nanomaterials by Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(05): 1402-1406. |
| [11] |
WANG Meng-xin 1，2, LUO A-li1，2. Spectral Analysis of Host Galaxy from Possible Dual AGNs[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 290-293. |
| [12] |
TAN Guan-ni1, GAO Hong1,2*, SONG Jie3, SHANG Shi-bin1,2, SONG Zhan-qian1,2. Synthesis, Spatial Configuration and Spectral Properties of Donor-Acceptor Molecules with Dehydroabietic Acid Triarylamine as Donors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(07): 2083-2090. |
| [13] |
LIANG Rong1, LAN Yan1, 2, ZHANG Tian-yang2, LU Tai-jin3, CHEN Mu-yu1, WANG Xiao-qing1, ZHANG Xiao-hu1. Multi-Spectroscopy Studies on Large Grained HPHT Synthetic Diamonds from Shandong, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(06): 1840-1845. |
| [14] |
DONG Xue1, QI Li-jian2, ZHOU Zheng-yu2, SUN Dui-xiong1*. Spectral Characteristics and Application of Synthetic Hydrothermal Red Beryl[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(02): 517-521. |
| [15] |
SUN Yan-wen1, CHANG Yu2, JIN Yu-fen1, XIE Wen-bing2, CHANG Jing1, YU Ting1*, PAN Li-hua2. Study of Synthesis and Spectral Property of Europium Cryptate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2189-2193. |
|
|
|
|
