| 光谱学与光谱分析 |
|
|
|
|
|
| Determination of U, Th and Tl in Fourteen Chinese Traditional Medicines by Microwave Digestion-ICP-MS |
| SUN Wei-min1,XUE Da-fang2,LI Hong1,LIU Hui1,TENG Wen-feng1* |
1. The Laboratory Medical College, Dalian Medical University, Dalian 116044, China
2. Technical Center, Liaoning Administration for Entry Exit Inspection and Quarantine, Dalian 116000, China |
|
|
|
|
Abstract Fourteen Chinese traditional medicines were digested by microwave digestion, which are generally applied to treat tumor in clinic, and the contents of U, Th and Tl in the fourteen Chinese traditional medicines were determined by inductively coupled plasma mass spectrometry (ICP-MS), and the results show that the change ranges of the elements contents were: 0.005 153-0.153 4 μg·g-1 for U;0.035 01-0.462 8 μg·g-1 for Th;0.001 43-1.600 μg·g-1 for Tl. The contents of U, Th and Tl in the fourteen Chinese traditional medicines were low, and not with one accord. The determination results of the fourteen Chinese traditional medicines were analyzed by SPSS 11.5, and the results show that there were not significant deviations(p＞0.05) of the contents of U, Th and Tl between the medicine of treating the toxifying disease with poisonous agents and the medicines of heat-clearing. The study indicates that inductively coupled plasma mass spectrometry (ICP-MS) is a quick, accurate, sensitive method to determine the contents of U, Th and Tl in Chinese traditional medicine, and the results of this study provide reference data for using Chinese traditional medicine safely in clinic and developing Chinese traditional medicine.
|
|
Received: 2007-09-28
Accepted: 2007-12-29
|
|
|
|
Corresponding Authors:
TENG Wen-feng
E-mail: tengwenfeng1234@163.com
|
|
[1] WU Zhong, SU Wei-wei, LIN Jing-ming(吴 忠，苏薇薇，林敬明). Journal of Chinese Medicinal Materials(中药材), 2001, 24(1)：57.
[2] Marcela Sivillaverde, Sandra V Verstraeten. Archives of Biochemistry and Biophysics, 2003, 417(2): 235.
[3] Hsieh C Y, Tsai M H, Ryan D K, et al. The Science of the Total Environment, 2004, 320: 37.
[4] WANG Jing-yu, ZHU Hong-da, OUYANG Li(王京宇，诸洪达，欧阳荔). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(9): 1117.
[5] Prabhavathi P A, Fatima S K, Rao M S, et al. Mutation Research, 2000, 466: 37.
[6] Miller A C, Brooks K, Stewart M, et al. Journal of Environmental Radioactivity, 2003, 64: 247.
[7] Hayata I, Wang C, Zhang W, et al. Genome Res, 2004, 104(124): 237.
[8] WANG Yong, FAN Fei-yue, YANG She-hua(王 勇, 樊飞跃, 杨陟华, 等). Chinese Journal of Stereology and Image Analysis(中国体视学与图像分析), 2006, 11(2): 152.
[9] Dublineau I, Grison S, Linard C, et al. J. Toxicol Environ Health A, 2006, 69(17): 1613.
[10] HE Feng-sheng, WANG Shi-jun, REN Yin-jin, et al(何凤生, 王世俊, 任引津, 等). China Occupational Medicine(中华职业医学). Beijing: People’s Medical Publishing House(北京: 人民卫生出版社), 2002. 321.
[11] Lü Hui-min, JIA Ke-jun, ZHENG Hui(吕慧敏， 贾柯君， 郑 辉, 等). Chinese Journal of Radiological Medicine and Protection(中华放射医学与防护杂志), 2007, 27(3): 260.
[12] ZENG Shao-hua, ZENG Xue-ping(曾昭华，曾雪萍). Hunan Geology(湖南地质), 1999, 18(4): 245.
[13] KOU Xing-ming, XU Min，GU Yong-zuo(寇兴明, 徐 敏, 顾永祚). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(6): 1197.
[14] SHI Li-fei, XUE Da-fang, XU Heng-gui, et al(施丽飞，薛大方，徐恒瑰, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(5): 1036.
[15] RUI Yu-kui, GUO Jing, HUANG Kun-lun, et al(芮玉奎, 郭 晶, 黄昆仑, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(4): 796.
[16] HU Qing-yuan, LI Li, SHI Jie, et al(胡清源, 李 力, 石 杰, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(6): 1210.
[17] WANG Yan-ze, WANG Ying-feng, SHI Yan-zhi, et al(王艳泽, 王英锋, 施燕支, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(12): 2327.
[18] LIU Ya-qiong, WANG Xiao-yan, WANG Jing-yu(刘雅琼，王小燕, 王京宇). Journal of Chinese Mass Spectrometry Society(质谱学报), 2003, 24(4): 491.
[19] TANG Xian-ping, GAO Feng-ling, WANG Zhen-qing(唐先平，高凤玲，王振卿). Tumor Clinic Common Chinese Traditional Medicine Manual(肿瘤临床常用中药指南). Beijing: Scientific and Technical Documents Publishing House(北京: 科学技术文献出版社), 2005. 25
[20] MA Li(马 丽). Modern Journal of Integrated Traditional Chinese and Western(现代中西医结合杂志), 2001，10(23): 2324. |
| [1] |
XU Rong1, AO Dong-mei2*, LI Man-tian1, 2, LIU Sai1, GUO Kun1, HU Ying2, YANG Chun-mei2, XU Chang-qing1. Study on Traditional Chinese Medicine of Lonicera L. Based on Infrared Spectroscopy and Cluster Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3518-3523. |
| [2] |
SUN Cheng-yu1, JIAO Long1*, YAN Na-ying1, YAN Chun-hua1, QU Le2, ZHANG Sheng-rui3, MA Ling1. Identification of Salvia Miltiorrhiza From Different Origins by Laser
Induced Breakdown Spectroscopy Combined with Artificial Neural
Network[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3098-3104. |
| [3] |
MA Qian1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, CHENG Hui-zhu1, 2, ZHAO Yan-chun1, 2. Research on Classification of Heavy Metal Pb in Honeysuckle Based on XRF and Transfer Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2729-2733. |
| [4] |
JIN Cheng-liang1, WANG Yong-jun2*, HUANG He2, LIU Jun-min3. Application of High-Dimensional Infrared Spectral Data Preprocessing in the Origin Identification of Traditional Chinese Medicinal Materials[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2238-2245. |
| [5] |
ZHANG Zhi-wei1, 2, QIU Rong1, 2*, YAO Yin-xu1, 2, WAN Qing3, PAN Gao-wei1, SHI Jin-fang1. Measurement and Analysis of Uranium Using Laser-Induced
Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 57-61. |
| [6] |
LIN Hai-lan1, HUANG Zhong-ting1*, CHEN Yang2, YU Tao1, YANG Yun-bo2, BI Jun-ping1, LIU Pei1. Application of LEFC-2006 in Thallium Monitoring of Water Quality[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3642-3646. |
| [7] |
ZHANG Fei1, 5，HUA Xia2*，YUAN Jia-ying3，YOU Fan1，YE Ren-cai4，DING Li4, ZHAO Jian-mei4. Determination of Thallium in Blood of Occupational Exposed Population by Inductively Coupled Plasma Mass Spectrometry With High Matrix Introduction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2870-2874. |
| [8] |
LI Meng1, 2, ZHANG Xiao-bo2, LIU Shao-bo3, CHEN Xing-feng4*, HUANG Lu-qi5*, SHI Ting-ting2, YANG Rui6, LIU Shu7, ZHENG Feng-jie8. Partly Interpretable Machine Learning Method of Ginseng Geographical Origins Recognition and Analysis by Hyperspectral Measurements[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1217-1221. |
| [9] |
WANG Wei-hong1, 2*, LUO Xue-gang1, 3, WU Feng-qiang1, 2, LIN Ling1, 2, LI Jun-jie1, 2. Spectral Angles of Plant Leaves as Indicators of Uranium Pollution in Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1313-1317. |
| [10] |
ZHANG Fei1，HUA Xia2，YOU Fan1，WANG Bin3，MAO Li3*. Determination of Thallium and Its Compounds in Workplace Air by Ultrasonic Extraction-Inductively Coupled Plasma Mass Spectrometry Using No Gas Mode[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2279-2283. |
| [11] |
ZHANG Wei1, 2, DONG Fa-qin3*, HE Xiao-chun3, SONG Huai-qing4, QIN Yi-lin5, XIONG Xin5, TANG Zi-han5. Release of Phosphorus to Promote Biomineralization of Uranium by Saccharomyces Cerevisiae Based on Spectroscopy Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 25-31. |
| [12] |
FAN Feng-jie1, XUAN Feng-lai1, BAI Yang1, JI Hui-fang2. Pattern Recognition of Traditional Chinese Medicine Property Based on Three-Dimensional Fluorescence Spectrum Characteristics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1763-1768. |
| [13] |
ZHANG En-hua1, QIU Xuan-bing1,2 *, WEI Yong-bo1, LI Ning1, LI Jie1, HE Xiao-hu1, GUO Gu-qing1, LI Chuan-liang1*, WEI Ji-lin1, ZANG Zhen-zhong2, YANG Ming2. Near-Infrared LED Moisture Content Sensor for Traditional Chinese Medicine Based on Square Wave Excitation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(05): 1656-1660. |
| [14] |
ZHENG Pei-chao1, ZHENG Shuang1, WANG Jin-mei1*, LIAO Xiang-yu1, LI Xiao-juan1, PENG Rui2. Study on Grade Identification of Dendrobium by LIBS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(03): 941-944. |
| [15] |
ZHOU Lin1, 2, DONG Fa-qin2*, ZHANG Wei3, 4, TANG Zi-han5, XIONG Xin5, ZHOU Lei2, LI Dong-kun2, HUO Ting-ting2, CHEN Xiao-ming5，LIU Jin-feng1, 2, FENG Chen-xun2, LI Ruo-fei5. Removal Behavior and Mechanism of Uranium by Bacillus Siamensis Based on Spectroscopic Analysis: the Role of Biological Phosphorus[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 22-28. |
|
|
|
|
