光谱学与光谱分析 |
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Kinetic Study on the In Situ Synthesis of Nickle Phthalocyanine in Silica Gel Glass Matrix by UV/Vis Absorption Spectra |
HUANG Juan, ZHENG Chan, FENG Miao, ZHAN Hong-bing* |
College of Materials Science and Engineering, Fuzhou University, Fuzhou 350002, China |
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Abstract In decades, metallo-phthalocyanines (MPcs) have undergone a renaissance because of their singular and unconventional physical properties. However, for the successful application of MPcs in practical devices, it is important to disperse MPc molecules into solid state matrix to fabricate MPc doped composite with desired properties. Inorganic glass is an ideal matrix because of its transparency and high environmental stability. One attractive approach to fabricating MPc/inorganic composite is sol-gel technique. In the present paper, silica gel glass matrix was prepared by hydrolysis and poly-condensation of tetraethyloxysilane. 1,2-dicyanobenzene and analytically pure soluble nickle salt were used as the nickle phthalocyanine (NiPc) reactants and chemical synthesis technique was used to prepare NiPc doped sol-gel materials at several temperatures. During the heat treatment, four 1,2-dicyanobenzene molecules and one nickle ion collide to form a NiPc molecule. In-situ synthesizing process of NiPc in the pores of silica gel glass matrix was traced by UV/Vis absorption spectra. Owing to the remarkable absorption band of NiPc in visible region, quantity of in-situ synthesized NiPc was calculated by the absorbance at certain wavelength of 670 nm, using composites with physically doped NiPc as a reference. The in-situ synthesized kinetics was studied in detail and found to be consistent with Avrami-Erofeev equation. The reaction grades were deduced to be 4.5, 4.5, 3.7, 3.2 and 1.9 respectively at temperatures of 180 ℃, 185 ℃, 190 ℃, 195 ℃ and 200 ℃, respectively.
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Received: 2007-08-28
Accepted: 2007-12-06
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Corresponding Authors:
ZHAN Hong-bing
E-mail: hbzhan@fzu.edu.cn
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[1] Leznoff C C, Lever A B P. Phthalocyanines Properties and Applications. New York: VCH Publishers, 1989. 55. [2] Thomas L A. Phthalocyanine Research and Application. Florida: CRC Press, 1990. 181. [3] Nagao K. Current Opinion in Solid State & Materials Science, 1999, 4(4): 345. [4] O’Flaherty S M, Hold S V, Hanack M, et al. Advanced Materials, 2003, 15: 19. [5] LI Lin, HUANG Yan-ping, LI Shan-shan, et al(李 琳, 黄燕萍, 李姗姗, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(2): 149. [6] Qian G D, Wang M Q. Journal of Physics D: Applied Physics, 1999, 32(18): 2462. [7] Benedicte L, Clement S. Current Opinion in Solid State & Materials Science, 1999, 4(1): 11. [8] Sanchez C, Ribot F, Lebeau B. Journal of Materials Chemistry, 1999, 9(1): 35. [9] Fan X P, Wang Z Y, Wang M Q. Chemical Physics Letters, 2002, 358(1-2): 115. [10] Qian G D, Yang Y, Wang Z Y, et al. Chemical Physics Letters, 2002, 368(5-6): 555. [11] QIN Jing, LIN Zhi-peng, ZHAN Hong-bing(秦 静, 林志鹏, 詹红兵). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(9): 1681. [12] Litran R, Blanco E, Ramirez M, et al. Journal of Sol-Gel Science and Technology, 1997, 8: 985. [13] Xia H P, Nogami M. Journal of Materials Science, 1999, 34(13): 3053. [14] Gu Y Z, Liang Z J, Gan F X. Optical Materials, 2001, 17(4): 471. [15] Xiong G H, Wang Z Y, Qian G D, et al. Journal of Sol-Gel Science and Technology, 2000, 18: 21. [16] Zhan H B, Wang M Q, Chen W Z. Materials Letters, 2002, 55(1-2): 97. [17] Yao X, Zhang L, Wang S. Sensors and Actuators B, 1995, 24-25: 347. [18] Santos A M M, Vasconcelos W L. Journal of Non-Crystalline Solids, 2000, 273(1-3): 145. [19] Rubio F, Rubio J, Oteo J L. Journal of Sol-Gel Science and Technology, 1997, 8: 159. [20] Japanese Chemical Society(日本化学学会). Inorganic Solid State Reactions(无机固态反应). Translated by DONG Wan-tang, DONG Shao-jun(董万堂,董绍俊,译). Beijing: Science Press(北京: 科学出版社), 1985. 36. |
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