|
|
|
|
|
|
Application of Zernike Moment in Terahertz Spectrum Quantitative Analysis of Rubber Additives |
YIN Xian-hua1, 2, GUO Chao1, 2, LI An3, MO Wei1* |
1. School of Electronic Engineering and Automation, Guilin University of Electronic Technology, Guilin 541004, China
2. Guangxi Key Laboratory of Automatic Detection Technology and Instrument, Guilin 541004, China
3. National Rubber and Rubber Products Quality Supervision and Inspection Center (Guangxi), Guilin 541004, China |
|
|
Abstract In recent years, the development of “green tire” has attracted much attention. Many kinds of rubber additives are needed in the manufacturing process of green tires, and the content of rubber additives is closely related to whether green tires can meet the standards. Therefore, it is important to quantitatively detect the rubber additives in tire rubber. THz-TDS technology has been successfully applied in the field of quantitative analysis of substances. However, when the quantitative analysis object is a multi-component mixture, the results of quantitative analysis will not be satisfactory due to the overlap and distortion of the mixture spectrum. In order to solve this problem, Zernike moment is introduced as a spectral pretreatment technology into terahertz spectral quantitative analysis of multi-component mixtures of rubber additives. A quantitative analysis method of terahertz spectrum based on Zernike moment and support vector regression (ZM-SVR) is proposed. Firstly, three rubber additives, zinc oxide, silica and 2-Mercaptobenzothiazole (MBT), which affect the quality of green tires, were used as quantitative detection objects. Three rubber additives and nitrile-butadiene rubber were prepared as multi-mixture experimental samples, and the terahertz spectra of samples were measured by terahertz time-domain spectroscopy system. Then, terahertz spectroscopy was analyzed and processed. After obtaining the three optical parameters of absorption coefficient, extinction coefficient and refractive index, the three optical parameters were constructed into the THz three-dimensional spectrum of the sample, and the characteristic information of the THz three-dimensional spectral gray-scale image was extracted by Zernike moment. Finally, the quantitative model between the characteristic information of the THz three-dimensional spectral gray-scale image of the sample and the content of the target component was established by using support vector regression. The target component content in the mixture sample was analyzed. The correlation coefficients of the forecasting set of the quantitative model obtained by this method were greater than or equal to 0.952 2, and the root mean square error was less than or equal to 2.267 2%. To further verify the validity of this method, the results of quantitative analysis were compared with those of PLS and SVR. Compared with the quantitative analysis results obtained by conventional methods, the accuracy and stability of the results obtained by Zernike moment combined with support vector regression method have been significantly improved. Therefore, Zernike moment combined with support vector regression provides a new method for terahertz spectroscopy quantitative detection of multi-component mixture of rubber additives, and has broad application prospects in the field of quality detection of green tires and rubber.
|
Received: 2019-04-15
Accepted: 2019-06-30
|
|
Corresponding Authors:
MO Wei
E-mail: cpxu_ck@163.com
|
|
[1] ZHAO Fei,HUANG Qi-wei, GAO Hong-na, et al(赵 菲, 黄琪伟, 高洪娜, 等), Chinese Science Bulletin(科学通报), 2016, 61(31): 3348.
[2] CHEN Hui(陈 慧). China Rubber(中国橡胶), 2016, 32(10): 45.
[3] CHEN Zhi-hong(陈志宏). Rubber Science and Technology(橡胶科技), 2013, 11(8): 5.
[4] Rolere S, Liengprayoon S, Vaysse L, et al. Polymer Testing, 2015, 43: 83.
[5] Zhang Huo, Li Zhi, Hu Fangrong, et al. Spectroscopy Letters,2018,51(4):174.
[6] Komatsu M, Izutsu T, Ohki Y, et al. Conference Proceedings of ISEIM, 2014, 2014: 338.
[7] Lu Shaohua, Li Baoqiong, Zhai Honglin, et al. Food Chemistry, 2018, (246): 220.
[8] Umut Konur. Biomedical Signal Processing and Control, 2018, (43): 18.
[9] ZHANG Wen-tao, WANG Si-yuan, ZHAN Ping-ping, et al(张文涛, 王思远, 占平平, 等). Acta Optica Sinica(光学学报), 2018,(11): 3385.
[10] Qin Binyi, Li Zhi, Luo Zhihui, et al. Optical Guantum Electronics, 2017, 49(7): 244.
[11] Babkina L A, Garmai Y P, Lebedev D V, et al. Numerical Analysis & Applications, 2013, 6(2): 131.
[12] Wang Xue, Li Baoqiong, Zhai Honglin, et al. Food Chemistry, 2016, 190: 1033.
[13] WU Xi-jun, CUI Yao-yao, PAN Zhao, et al(吴希军, 崔耀耀, 潘 钊, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2018, 38(8): 138. |
[1] |
WAN Mei, ZHANG Jia-le, FANG Ji-yuan, LIU Jian-jun, HONG Zhi, DU Yong*. Terahertz Spectroscopy and DFT Calculations of Isonicotinamide-Glutaric Acid-Pyrazinamide Ternary Cocrystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3781-3787. |
[2] |
LIU Hao-dong1, 2, JIANG Xi-quan1, 2, NIU Hao1, 2, LIU Yu-bo1, LI Hui2, LIU Yuan2, Wei Zhang2, LI Lu-yan1, CHEN Ting1,ZHAO Yan-jie1*,NI Jia-sheng2*. Quantitative Analysis of Ethanol Based on Laser Raman Spectroscopy Normalization Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3820-3825. |
[3] |
LIN Hong-jian1, ZHAI Juan1*, LAI Wan-chang1, ZENG Chen-hao1, 2, ZHAO Zi-qi1, SHI Jie1, ZHOU Jin-ge1. Determination of Mn, Co, Ni in Ternary Cathode Materials With
Homologous Correction EDXRF Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3436-3444. |
[4] |
HUANG Li, MA Rui-jun*, CHEN Yu*, CAI Xiang, YAN Zhen-feng, TANG Hao, LI Yan-fen. Experimental Study on Rapid Detection of Various Organophosphorus Pesticides in Water by UV-Vis Spectroscopy and Parallel Factor Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3452-3460. |
[5] |
LI Zhong-bing1, 2, JIANG Chuan-dong2, LIANG Hai-bo3, DUAN Hong-ming2, PANG Wei2. Rough and Fine Selection Strategy Binary Gray Wolf Optimization
Algorithm for Infrared Spectral Feature Selection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3067-3074. |
[6] |
LIU Shu1, JIN Yue1, 2, SU Piao1, 2, MIN Hong1, AN Ya-rui2, WU Xiao-hong1*. Determination of Calcium, Magnesium, Aluminium and Silicon Content in Iron Ore Using Laser-Induced Breakdown Spectroscopy Assisted by Variable Importance-Back Propagation Artificial Neural Networks[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3132-3142. |
[7] |
LI Yang1, LI Xiao-qi1, YANG Jia-ying1, SUN Li-juan2, CHEN Yuan-yuan1, YU Le1, WU Jing-zhu1*. Visualisation of Starch Distribution in Corn Seeds Based on Terahertz Time-Domain Spectral Reflection Imaging Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2722-2728. |
[8] |
KONG De-ming1, LIU Ya-ru1, DU Ya-xin2, CUI Yao-yao2. Oil Film Thickness Detection Based on IRF-IVSO Wavelength Optimization Combined With LIF Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2811-2817. |
[9] |
ZHAO Yu-wen1, ZHANG Ze-shuai1, ZHU Xiao-ying1, WANG Hai-xia1, 2*, LI Zheng1, 2, LU Hong-wei3, XI Meng3. Application Strategies of Surface-Enhanced Raman Spectroscopy in Simultaneous Detection of Multiple Pathogens[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2012-2018. |
[10] |
CHENG Xiao-xiang1, WU Na2, LIU Wei2*, WANG Ke-qing2, LI Chen-yuan1, CHEN Kun-long1, LI Yan-xiang1*. Research on Quantitative Model of Corrosion Products of Iron Artefacts Based on Raman Spectroscopic Imaging[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2166-2173. |
[11] |
ZHENG Zhi-jie1, LIN Zhen-heng1, 2*, XIE Hai-he2, NIE Yong-zhong3. The Method of Terahertz Spectral Classification and Identification for Engineering Plastics Based on Convolutional Neural Network[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1387-1393. |
[12] |
CHEN Rui1, WANG Xue1, 2*, WANG Zi-wen1, QU Hao1, MA Tie-min1, CHEN Zheng-guang1, GAO Rui3. Wavelength Selection Method of Near-Infrared Spectrum Based on
Random Forest Feature Importance and Interval Partial
Least Square Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1043-1050. |
[13] |
DENG Xiao-jun1, 2, MA Jin-ge1, YANG Qiao-ling3, SHI Yi-yin1, HUO Yi-hui1, GU Shu-qing1, GUO De-hua1, DING Tao4, YU Yong-ai5, ZHANG Feng6. Visualized Fast Identification Method of Imported Olive Oil Quality Grade Based on Raman-UV-Visible Fusion Spectroscopy Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1117-1125. |
[14] |
WANG Yu-ye1, 2, LI Hai-bin1, 2, JIANG Bo-zhou1, 2, GE Mei-lan1, 2, CHEN Tu-nan3, FENG Hua3, WU Bin4ZHU Jun-feng4, XU De-gang1, 2, YAO Jian-quan1, 2. Terahertz Spectroscopic Early Diagnosis of Cerebral Ischemia in Rats[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 788-794. |
[15] |
WANG Hai-ping1, 2, ZHANG Peng-fei1, XU Zhuo-pin1, CHENG Wei-min1, 3, LI Xiao-hong1, 3, ZHAN Yue1, WU Yue-jin1, WANG Qi1*. Quantitative Determination of Na and Fe in Sorghum by LIBS Combined With VDPSO-CMW Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 823-829. |
|
|
|
|