|
|
|
|
|
|
Fabrication of Semiconductor Polymer Membranes Combined with a Colored Charge Transfer Complexes Used in the Manufacture of Solar Cells as a Source of Alternative Energy |
Ahmed. I. El-Shenawy*, Ishaq. F. E. Ahmed, Moamen. S. Refat |
Department of Chemistry, Colloge of Education, Imam Abdulrahman Bin Faisal University, Dammam 1982, Saudi Arabia |
|
|
Abstract The main task of this article was to prepared of new pigment model in situ solar cells accordance to charge-transfer complexes of rhodamine C (RhC) donor as dye laser gain media with iodine (σ-acceptor) and chloranilic acid, CLA (π-acceptor). The synthesis stoichiometry of these complexes were of 1∶2 (donor∶acceptor) with general formulas [(RhC)]I·I3 and [(RhC)(CLA)2]. The discussed data of elemental analysis, conductivity measurements, FT-IR, UV-Vis spectroscopy and photometric titration data visualized the stoichiometry, formula and complexity of the complexes. The physicochemical and spectroscopic analyses obtained suggested that the electron transfer occurred through nitrogen atom in a tertiary amine —N(C2H5)2 of RhC donor with acceptor. The synthesized solid complexes were under go to thermogravimetric analyses to investigate their thermal stability and decomposition steps. The molar conductance measurements revealed that RhC complexes have an electrolytic statement. The thermal stability of rhodamine C complexes was enhanced in comparable with RhC itself. The polymer membranes of poly-methyl methacrylate) (PMMA) combined with the RhC charge(transfer complexes in chloroform solvent have been prepared and characterized by (infrared & electronic) spectroscopy and scanning electron microscopy (SEM) morphological examination. The photo-stability properties of the RhC complexes have been investigated.
|
Received: 2018-10-08
Accepted: 2019-02-15
|
|
Corresponding Authors:
Ahmed. I. El-Shenawy
E-mail: aelshenawy@uod.edu.sa
|
|
[1] Hashem H A, Refat M S. Surf. Rev. Lett., 2006, 13(4): 439.
[2] Seridi S, Dinar K, Seridi A, et al. New J. Chem., 2016, 40: 4781.
[3] Mohamed M E, Frag E Y Z, Hathoot A A, et al. Spectrochim Acta A, 2018, 189: 357.
[4] Wu Y, Luo S, Cao L, et al. Anal. Chim. Acta,2017,976: 74.
[5] Refat M S, Adam A M A, El-Sayed M Y. Arabian J. Chem., 2017, 10: S3482.
[6] Mutneja R, Singh R, Kaur V, et al. Dyes. Pigm., 2107, 139: 635.
[7] Duarte F J. High Power Dye Lasers. Springer-Verlag: Berlin,1991.
[8] Beija M, Afonso C A M, Martinho J M G. Chem. Soc. Rev., 2009, 38: 2410.
[9] Park H, Choi J, Choi J, et al. J. Photochem. Photobiol. A, 2018, 351: 139.
[10] El-Maghrabi H H, Barhoum A, Nada A A, et al. J. Photochem. Photobiol. A, 2018, 351: 261.
[11] Eiamprasert U, Sudchanham J, Surawatanawong P, et al. J. Photochem. Photobiol. A,2018,352: 86.
[12] Grabchev I, Bojinov V. J. Photochem. Photobiol. A: Chem., 2001, 139: 157.
[13] Trotter P J, White P A. Appl. Spectrosc., 1978, 32: 323.
[14] Skoog D A. Principle of Instrumental Analysis. 3rd ed. Ch. 7. Saunders College Publishing, New York, 1985.
[15] Kiefer W, Bernstein H J. Chem. Phys. Lett., 1972, 16: 5.
[16] Andrews L, Prochaska E S, Loewenschuss A. Inorg. Chem., 1980, 19: 463.
[17] Kaya K, Mikami N, Udagawa Y, et al. Chem. Phys. Lett., 1972, 16: 151.
[18] Abu-Eittah R, El-Kourashy A. J. Phys. Chem., 1972, 76(17): 2405.
[19] Briegleb G, Angew Z. Chem., 1964, 76: 326.
[20] Martin A N, Swarbrick J, Cammarata A. Physical Pharmacy, 3<sup>rd</sup> ed. Lee and Febiger, Philadelphia, PA, 1969. 344.
[21] Rathore R, Lindeman S V, Kochi J K. J. Am. Chem. Soc., 1997, 119: 9393.
[22] Tsubomura H, Lang R P. J. Am. Chem. Soc., 1961, 83: 2085.
[23] Aloisi G G, Pignataro S. J. Chem. Soc. Faraday Trans., 1973, 69: 534.
[24] Briegleb G, Czekalla J, Physikchem Z, et al. Chem. (Frankfurt), 1960, 24: 237.
[25] Pandeeswaran M, Elango K P. Spectrochim. Acta A, 65: 1148.
[26] El-Habeeb A A, Refat M S. Russ. J. Gen. Chem., 2015, 85(4): 939.
[27] Nour E M, Shahada L A. Spectrochim. Acta A, 1989,45: 1033.
[28] Kiefer W, Bernstein H J. Chem. Phys. Let., 1972, 16: 5.
[29] Coats A W, Redfern J P. Nature,1964,201: 68.
[30] Karipcin F, Dede B, Caglar Y, et al. Opt. Commun., 2007, 272: 131.
[31] Yakuphanoglu F, Cukurovali A, Yilmaz I. Opt. Mater, 2005, 27: 1363.
[32] Hoffman M, Martin S, Choi W, et al.Chemical Review, 1995, 95: 69.
[33] Fu M L, Guo G G, Liu X, et al. Inorg. Chem. Comm., 2005, 8: 18.
[34] Grabchev I, Bojinov V. Polym. Degrad. Stab., 2000, 70: 147.
[35] Esumi K, Hayakawa K, Yoshimura T. J. Colloid and Interface Science, 2003, 268(2): 501. |
[1] |
Moamen S. Refat1*, Mahmoud Salman2, Akram M. El-Didamony3, Hammad Fetooh3, Eman S.E. Abd El-Maksoud3,Mohamed Y. El-Sayed3,4. Spectroscopic and Fluorescence Studies on the Trivalent Ce, Eu, Nd and La Metal Ions Rhodamine C Florescent Dye Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3311-3315. |
[2] |
Lamia A Albedair1*, Samar O Aljazzar1, Mohamed I Kobeasy2,3,Moamen S Refat3,4*. Complexity of Gold(Ⅲ) Ion With Cefotaxime and Cefepime Drugs: Spectroscopic, Antimicrobial and Antitumor Discussions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3315-3320. |
[3] |
Moamen S. Refat1,2*, Abeer A. El-Habeeb3. Synthesis, Spectroscopic and Antimicrobial Investigations of Scandium(Ⅲ) Complexes with Four Kinds of Sulfa Drugs[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(03): 985-990. |
[4] |
Ömer Söğüt1*, Betül Demirezen Kara1, Gökhan Apaydın2, Erhan Cengiz3, Ayşe Kazancı4. Examination of Polymeric Azomethine Compounds and Their Transition Metal Complexes by Using XRF and XRD Technique[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 328-332. |
[5] |
Enas Aljuhani1, Amnah M. A. Alsuhaibani2, A. M. El-Didamony3, N. Hassan4, Sameh Abo Taleb4, Moamen S. Refat4,5*. Preparation and Spectroscopic of Vanadyl(Ⅱ) Vitamin D3 Amino Acid Mixed Complexes as Insulin Mimetic Drug[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(07): 2316-2324. |
[6] |
Omar B. Ibrahim1, El-Sayed A. Manaaa2,3, M.M. AL-Majthoub1, Ahmed M. Fallatah1, Abdel Majid A. Adam1, Mha M. Alatibi1, Jehan Y. Al-Humaidi4, Moamen S. Refat1,5*. Estimation of Metformin Drug for the Diabetes Patients by Simple, Quick and Cheap Techniques within the Formation of Colored Charge Transfer Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3622-3630. |
[7] |
Belal H M Hussein1,2*, Mostafa A Gouda1,3, Omer Sakin1, Abdulla Faluji4, Mohamed Gomaa5, Hassan A Azab2, Walid Fathalla6, Sherin Arabi7, Sawsan Mosa8. DNA Binding and Antitumor Activity of a New Fluorescent Probe Eu(Ⅲ)-Complex Containing 4-Methyl-Coumarin Moiety[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(11): 3611-3621. |
[8] |
Tulin BCM, Mehmet YAMAN. Sensitivity Enhancement in Uranium Determination by UV-Visible Spectroscopy Using Ion Imprinted Polymer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(06): 1992-1997. |
[9] |
Mithat Celebi1,2, Zafer Omer Ozdemir2,3*, Emre Eroglu4, Melda Altikatoglu5, Ibrahim Guney6 . Determination of Minimum Enzymatic Decolorization Time of Reactive Dye Solution by Spectroscopic & Mathematical Approach [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(02): 340-345. |
[10] |
YUAN Dan, CHEN Zhi-jian*, XIAO Li-xin, MU Li-ping, QU Bo,GONG Qi-huang* . The Improvement of Bulk-Heterojunction Order in Polymer Photovoltaic Device[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(12): 3175-3179. |
[11] |
ZHU Meng-hua1, LIU Liang-gang1, ZHENG Mei2, QI Dong-xu1, ZHENG Cai-mu1 . Automatically Smoothing the Spectroscopic Data by Cubic B-Spline Basis Functions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(10): 2721-2724. |
|
|
|
|