光谱学与光谱分析 |
|
|
|
|
|
Properties of Energy Transfer in Two Host Materials Doped with Ir(ppy)3 and Rubrene |
LI Yan-rui1,ZHAO Su-ling1*,YANG Shao-peng2,XU Zheng1,ZHANG Fu-jun1,SONG Dan-dan1,XU Xu-rong1 |
1. Key Laboratory of Luminescence and Optical Information (Beijing Jiaotong University), Ministry of Education, Beijing 100044, China 2. Institute of Physical Science and Technology, Hebei University, Baoding 071002, China |
|
|
Abstract The devices with phosphorescent material tris(2-phenylpyridine)iridium [Ir(ppy)3] and fluorescent material 5,6,11,12-tetraphenylnaphthacene [Rubrene] as dopants in two kinds of host were constructed in the present study. Respectively, the two kinds of host are polyvinylcarbazole [PVK] and 4,4’-N,N-dicarbazole-biphenyl . We studied the properties of energy transfer between host materials and dopants. Firstly, the absorption and photoluminescence spectra of PVK, CBP, Ir(ppy)3 and Rubrene were measured. The spectral overlap between the photoluminescence of PVK and the absorption spectrum of Ir(ppy)3 is larger than that of Rubrene. The result of the spectral overlap for CBP is the same as PVK. It was shown that the energy transfer from the two host materials to Ir(ppy)3 is stronger than that to Rubrene. In addition, the energy transfer from Ir(ppy)3 to Rubrene is possible according to their absorption and photoluminescence spectra. We compared the electroluminescence properties of different devices. In device1 of ITO/PVK∶Rubrene∶Ir(ppy)3(100∶5∶x)/BCP(10 nm)/Alq3(20 nm)/Al and device 2 ITO/CBP∶Rubrene∶Ir(ppy)3(100∶5∶x)/BCP(10 nm)/Alq3(20 nm)/Al(x=0, 3), under the same DC bias, the electroluminescence results show that energy transfer from host to Rubrene through Ir(ppy)3 is the main mechanism. And energy transfer is much more efficient in CBP as host than in PVK. In addition, at the same voltage, the light power of the device doped with Ir(ppy)3 and Rubrene is obviously stronger than that of the device doped with Rubrene only. When the concentration of Ir(ppy)3 increases, the light power decreases at the same voltage, and the effect of concentration quenching is enhanced.
|
Received: 2007-09-30
Accepted: 2007-12-28
|
|
Corresponding Authors:
ZHAO Su-ling
E-mail: slzhao@center.njtu.edu.cn
|
|
[1] Liao L S, Kluhek K P, Tang C W. Appl. Phys. Lett., 2004, 84(2): 167. [2] ZHANG Fu-jun, XU Zheng, HUANG Jin-zhao, et al(张福俊,徐 征,黄金昭, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006,26(8):1403. [3] LIU Ling, XU Zheng, ZHANG Fu-jun, et al(刘 玲,徐 征,张福俊, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006,26(7):1199. [4] Forrest S R, Thomspon M E, Baldo M A. Nature, 2000, 403: 750. [5] Hamada Y, Kanno H, Tsujioka T, et al. Appl. Phys. Lett., 1999, 75: 1682. [6] D'Andrade B W, Baldo M A, Adachi C, et al. Appl. Phys. Lett., 2001, 79: 1045. [7] Gustufsson G, Cao Y, Treacy G M, et al. Nature, 1992, 357: 477. [8] Ohmori Y, Kajii H, Sawatani T, et al. Thin Solid Films., 2001, 393: 407. [9] YANG Sheng-yi,WANG Zhen-jia,XU Xu-rong,et al(杨盛谊,王振家,徐叙瑢,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2000,20(6):872. [10] TAO Dong-liang,HUANG Bao-gui,XU Yi-zhuang,et al(陶栋梁,黄保贵,徐怡庄,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2001,21(6):740. [11] XU Deng-hui, DENG Zhen-bo, XU Ying, et al(徐登辉,邓振波,徐 颖, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006,26(8):1406. [12] WANG Jun, WEI Xiao-qiang, RAO Hai-bo(王 军, 魏孝强, 饶海波). Acta Phys. Sin.(物理学报), 2007, 56(2): 1156. [13] LU Jing, HOU Yan-bing, SHI Quan-min, et al(鲁 晶, 侯延冰, 师全民,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(3): 420. [14] Jabber G E, Kippelen B, Armstrong N B. Appl. Phys. Lett., 1998, 73(9): 1185. [15] Mori T, Kim H G, Mizutani T, et al. Jpn. J. Appl. Phys., 2001, 40: 5346. |
[1] |
XU Lei, ZHU Lin, ZHANG Chun, YE Chang-qing*, CHEN Shuo-ran, LI Lin, LIANG Zuo-qin, WANG Xiao-mei*. Study on Properties of Azaanthracene Derivatives With Triplet-Triplet Annihilation Upconversion and One-Photon Hot Band Absorption
Upconversion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1761-1768. |
[2] |
LIANG Zuo-qin, YAN Xu, SONG Dong-dong, ZHANG Xiao-bo, ZHANG Jia-xuan, YE Chang-qing, CHEN Shuo-ran, WANG Xiao-mei. The Influence of Substituents in Anthracene Derivatives on the Performance of Triplet-Triplet Annihilation Upconversion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 802-807. |
[3] |
YE Chang-qing, YU Xue, CHEN Shuo-ran, LIANG Zuo-qin, ZHOU Yu-yang, WANG Xiao-mei*. Study on the Structure/Energy-Level of Palladuim-Porphyrin Sensitizers on the Triplet-Triplet-Annihilation Upconversion Performance[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 71-79. |
[4] |
ZHAN Ying-fei, LIU Chun-guang*, WANG Ming-wei, YANG Jian, ZHU Han-cheng, YAN Duan-ting, XU Chang-shan, LIU Yu-xue. Preparation, Microstructure and Optical Properties of Cr3+ Single-Doped and Eu3+/Cr3+ Co-Doped GdAlO3 Near Infrared Long Persistent Luminescent Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(01): 80-87. |
[5] |
ZHAO Yuan, LÜ Zhao-yue*, DENG Jian, ZENG Guo-qing. The Emissive Mechanism of C545T Thin Layer at the Exciplex and Non-Exciplex Interfaces[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3711-3715. |
[6] |
CHEN Shuo-ran1, ZHENG Dao-yuan1, LIU Teng1, YE Chang-qing1*, SONG Yan-lin2. Ratiometric Fluorescent Temperature Probe Based on Up/Down-Conversion Luminescence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(10): 3088-3095. |
[7] |
LI Zhao, CAO Jing, WANG Yong-feng. Synthesis and Spectral Properties of Phosphors Based on Schiff Base Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(09): 2879-2882. |
[8] |
WU Qi-xiao1, 2, ZHAO Su-ling1, 2*, XU Zheng1, 2, SONG Dan-dan1, 2, QIAO Bo1, 2, ZHANG Jun-jie1, 2, ZUO Peng-fei1, 2. Synthesis and Upconversion Mechanism of NaYF4∶Yb3+,Er3+ Nanocrystal Doped with Different Concentration of Sensitizer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1406-1411. |
[9] |
ZHANG Yong1,2, ZHU Jin-ming1, YANG Li-li1*, Lü Shi-quan1, WU Yan-qun1,CHU Xue-juan1. Effect of Dy3+ on Luminescence Properties of Tb3+ Activated Silicate Oxyfluoride Scintillating Glass[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1412-1419. |
[10] |
ZHENG Jia-jin1, 2, LU Qiang1, ZHENG Rui-lin1, ZOU Hui1, YU Ke-han1, WEI Wei1. Preparation and Photoluminescence Properties of Fluorophosphate Glasses with High Efficient White Light Emission[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(01): 39-44. |
[11] |
CHEN Xiao-bo1, LI Song1, YU Chun-lei2, WANG Shui-feng1, ZHAO Guo-ying3, MA Hui1,ZHENG Dong1, YANG Guo-jian1, LIU Yuan1, DENG Zhi-wei1, HE Qing1, HU Li-li2. Intense Spectral Modulation by Quantum Cutting Luminescence of Er3+Yb3+ Ion-Pair in Nanophase Oxyfluoride Vitroceramics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1949-1957. |
[12] |
ZHANG Chun-yan1,2, LUO Jian-xin2*, OU Li-juan2, LIU Yong2, HU Bo-nian2, YU Gui-peng1*, PAN Chun-yue1*. Luminescence Properties of Carbazole-Substituted Alq3 Derivative: a Potential Multifunctional Fluorescent Sensing Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1290-1297. |
[13] |
CHEN Jia1, YE Chang-qing1, ZHU Sai-jiang1, WANG Xiao-mei1,2*, TAO Xu-tang2. Synthesis of 9,10-Diheterocyclicanthracenes and Performance Correlations in Triplet-Triplet Annihilation Upconversion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 715-721. |
[14] |
WAN Ying,HE Jiu-yang, MA Yuan-yuan, ZHOU Zhi-xuan, Taximaiti·Yusufu, Aierken·Sidike*. Synthesis and Luminescence Properties of a New Type of Green Fluorescent Powder BaAl2Si2O8∶Tb3+, Ce3+[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(05): 1595-1600. |
[15] |
WANG Guang-hua1,2, ZHAO Hui-qiong1,2, DENG Rong-bin1, DUAN Yu1,2, SUN Hao1, ZHANG Xiao-dan1,2, ZHOU Qin1, QIAN Jin-mei1, WAN Rui-min1,2, JI Hua-xia1, JI Rong-bin2. Research on the Preparation and Chromaticity Coordinates Shift Mechanism of Organic White Light Top-Emitting Devices[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(11): 3758-3763. |
|
|
|
|