光谱学与光谱分析 |
|
|
|
|
|
Application of ICP-MS in Evaluating Element Contamination in Soils |
WU Ying-juan, CHEN Yong-heng, YANG Chun-xia, CHANG Xiang-yang |
School of Environmental Science and Engineering, Guangzhou University, Guangzhou 510006, China |
|
|
Abstract The Yunfu pyrite was the second biggest pyrite bed in the world. Plants using industrial ore of the Yunfu pyrite are distributed in many sections across the country. In the present paper, elements V, Cr, Co, Cu, Zn, Mo, Cd, Sb, Rb and Cs in soil profiles in slag disposing area of a sulfuric acid plant using industrial ore of theYunfu pyrite were studied. A method for simultaneously determination of metals and some reference elements in soils by ICP-MS was developed. The correlations between the metals and their reference elements were fast found. Enrichment factors were applied for evaluating the degree of soil contamination, and the problem about choosing contamination elements background values was pointed out. The results indicated that element V showed apparent and serious pollution, The Co showed middle degree pollution, and there has been a trend of apparent pollution. The Cr, Mo and Cd showed pollution between light degree and middle degree. The Zn and Sb showed light degree pollution, and there was a latent trend of middle degree pollution. The Cu showed light degree pollution. The high enrichment points of the V and the Cr were observed in the upper part (4.0-10.5 cm) and deep part of soil profiles (44.0-75.5 cm). Those of Co and Mo were found in the surface of soil profiles (0-5.0 cm), middle-upper part (9.5-10.5 cm) and middle part (29.5-46.0 cm), while those of Cd and Cu occurred just in the middle of soil profiles (29.5-46.0 cm). The formation of highly enrichment points of contamination elements in the soil profiles was the result of leaching and accumulating effect of the metals released from slag and the residual metals of highly weathered red soils. Most of pollution of V in the soil was contributed by the V in soil bed. Part of the V pollution in the soil was supplied by leaching and accumulating effect of the V which came from catalyst with lost activity in sulfuric acid production volatilizing into slag.
|
Received: 2007-08-02
Accepted: 2007-11-06
|
|
Corresponding Authors:
WU Ying-juan
E-mail: fwfyd@163.com
|
|
[1] Banat K M, Howari F M, Al-Hama A A. Environmental Research, 2005, 97(2): 258. [2] WANG Xue-song, QIN Yong(王学松,秦 勇). Geochimica(地球化学), 2006,35(1): 90. [3] TENG Yan-guo, JIAO Xu-dong, ZUO Rui, et al(滕彦国,矫旭东,左 锐,等). Journal of Jilin University(Earth Science Edition)(吉林大学学报·地球科学版), 2007, 37(2): 278. [4] RUI Yu-kui, KONG Xiang-bin, QIN Jing(芮玉奎,孔祥斌,秦 静). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2007, 27(6): 1201. [5] YANG Rong-yong, CAO Jian-jin, KANG Xian-gui, et al(杨荣勇,曹建劲,康显桂,等). Acta Sci. Nat. Univ. Sunyatseni(中山大学学报·自然科学版), 1997, 36(4): 79. [6] CHEN Yong-heng, XIE Wen-biao, WU Ying-juan, et al(陈永亨, 谢文彪, 吴颖娟, 等). J. of Shenzhen Univ.·Science and Engineering(深圳大学学报·理工版), 2001, 18(1): 57. [7] YANG Chun-xia, CHEN Yong-heng, PENG Ping-an, et al(杨春霞, 陈永亨, 彭平安, 等). Research of Environmental Sciences(环境科学研究), 2005, 18(2): 99. [8] Sutherland R A. Environment Geology, 2000, 39: 611. [9] ZENG Ying, NI Shi-jun, ZHANG Cheng-jiang(曾 英, 倪师军, 张成江). Advance in Earth Science(地球科学进展), 2004, 19(增刊): 472. [10] Muller G. Chemiker-Zeitung, 1981, 105(6): 157. [11] CHAI Shi-wei, WEN Yan-mao, ZHANG Ya-lei, et al(柴世伟, 温琰茂, 张亚雷, 等). Journal of Tongji University(Natural Science)(同济大学学报·自然科学版), 2006, 34(12): 1657. [12] LI Yong-hua, WANG Wu-yi, YANG Lin-sheng, et al(李永华, 王五一, 杨林生, 等). Environmental Science(环境科学), 2005, 26(5): 187. [13] Hernandez L, Probst A, Probst J L. The Science of the Total Environment, 2003, 312: 195. [14] Tania L, Micaela P, Malcolm C. Environmental International, 2003, 29: 935. |
[1] |
LAI Niu, HUANG Qi-qiang, ZHANG Qin-yang, ZHANG Bo-wen, WANG Juan, YANG Jie, WANG Chong, YANG Yu, WANG Rong-fei*. Introduction to Perovskite Quantum Dots and Metal-Organic Frameworks and the Development of Composites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3321-3329. |
[2] |
ZHANG Yu-hui1, 2, DING Yong-kang3, PEI Jing-cheng1, 2*, GU Yi-lu1, 2, YU Min-da1, 2. Chemical Constituents and Spectra Characterization of Monocrystal
Rhodonite From Brazil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3504-3508. |
[3] |
LI Xiao-li1, WANG Yi-min2*, DENG Sai-wen2, WANG Yi-ya2, LI Song2, BAI Jin-feng1. Application of X-Ray Fluorescence Spectrometry in Geological and
Mineral Analysis for 60 Years[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 2989-2998. |
[4] |
SUN Da-wei1, 2, 3, DENG Jun1, 2*, JI Bing-bing4. Study on the Preparation Mechanism of Steel Slag-Based Biomass Activated Carbon by Special Steel Slag-Discard Walnut Shells Based on ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2308-2312. |
[5] |
BI Yan-qi1, 2 , YANG Ying-dong3, DU Jing4, TANG Xiang5, LUO Wu-gan1, 2*. A Study on Mineral Material Sources of Multi-Style Bronzes Collected by Cultural Relic Administration Center of Huili County, Sichuan Province With MC-ICP-MS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1140-1146. |
[6] |
WANG Zi-min1, MAO Xiao-tian1, YIN Zuo-wei1*, CHEN Chang2, CHENG Tian-jia1. Study on the Spectral Characteristics and the Color-Change Effect of Spinel[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3541-3545. |
[7] |
JUMAHONG Yilizhati1, 2, TAN Xi-juan1, 2*, LIANG Ting1, 2, ZHOU Yi1, 2. Determination of Heavy Metals and Rare Earth Elements in Bottom Ash of Waste Incineration by ICP-MS With High-Pressure Closed
Digestion Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3168-3173. |
[8] |
LUO Heng, Andy Hsitien Shen*. Based on Color Calculation and In-Situ Element Analyze to Study the Color Origin of Purple Chalcedony[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1891-1898. |
[9] |
YANG Yan-ling1, Andy Hsitien Shen1, FAN Yu-rong2, HUANG Wei-zhi1, PEI Jing-cheng1*. UV-Vis-NIR Spectroscopic Characteristics of Vanadium-Rich
Hydrothermal Synthetic Emeralds From Russia[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1199-1203. |
[10] |
ZHONG Yuan, QU Meng-wen, Andy Hsitien Shen*. Comparison of Chemical Composition and Spectroscopy of Purple- Brownish Red Garnet From Zambia, Tanzania and Australia[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 184-190. |
[11] |
DU Jing1,JIN Tao2, HU Feng-dan1, ZHANG Chi1, ZHU Tie-quan3, ZHAN Chang-fa3, LI Nai-sheng1, JIA Zheng1, CHEN Yue1*. Desalination Monitoring of Wooden Shipwreck Components of the Qing Dynasty Marine Shipwreck,Xiaobaijiao No.1[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3294-3298. |
[12] |
ZHAO Wen-ya1, 2, MIN Hong2, LIU Shu2*, AN Ya-rui1*, YU Jin3. Application Progress of Artificial Neural Network in Laser-Induced Breakdown Spectral Data Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 1998-2004. |
[13] |
ZHU Jie1, WU Qian1, SHAO Xiao1, YU Xiao-jun2, LIU Lin-bo3, DAI Jia-ning1, MO Jian-hua1*. Conformal Coating Thickness Measurement on Printed Circuit Board With Spectral Domain Optical Coherence Tomography[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(04): 1157-1162. |
[14] |
GE Liang-quan, LI Fei*. Research Advances in In-Situ X-Ray Fluorescence Analysis Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 704-713. |
[15] |
ZHAO Ting1,2,3, CHI Hai-tao1,2,3*, LIU Yi-ren1,2,3, GAO Xia1,2,3, HUANG Zhao1,2,3, ZHANG Mei1,2,3, LI Qin-mei1,2,3. Determination of Elements in Health Food by X-Ray Fluorescence Microanalysis Combined With Inductively Coupled Plasma Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 750-754. |
|
|
|
|