|
|
|
|
|
|
Development of a Spectral Measurement System for the Determination of the Fluorescence Efficiency of Dissolved Oxygen Membrane |
NIE Ling-mei1, ZHA Tao1, XIA Bin-biao1, ZHANG Kai1, GUAN Zhi-qiang1, ZHAO You-quan1*, YUAN Da2, CAO Xuan2, LIU Yan2 |
1. School of Precision Instruments and Optoelectronics Engineering, Tianjin University, Tianjin 300072, China
2. Institute of Oceanographic Instrumentation, Qilu University of Technology (Shandong Academy of Sciences), Qingdao 266061, China |
|
|
Abstract Fluorescence quenching technology is one of the advanced technologies for rapid measurement of oxygen content in sewage, surface water and aquaculture water. Oxygen sensitive membrane is the core of fluorescence quenching detection technology. Oxygen sensitive membrane with high fluorescence emission efficiency owns high sensitivity, strong specificity and high signal-to-noise ratio,which makes the detection results more accurate. High efficiency is not the basis of selecting oxygen sensitive film and the key to the optimization design of dissolved oxygen detection components, detection circuit and detection optical path. There is no standard method for evaluating the quality of oxygen-sensitive membranes in existing dissolved oxygen fluorescence detection devices. Based on the research on the optical path and circuit of existing sensor probes, this paper proposes a method to evaluate the quality of oxygen-sensitive membranes using the fluorescence emission efficiency of the whole wavelength range. In this method, the high-power xenon lamp was selected as the excitation light source, and the monochromatic spectroscopy was performed based on the continuous single-wavelength scanning method. Then of oxygen-sensitive membranes were determined by scanning the excitation light spectrum and fluorescence spectrum, and the fluorescence emission efficiency calculation method was put forward and established. The method could objectively evaluate the fluorescence emission ability and find the optimum excitation wavelength accurately. In order to verify the feasibility of this method, this article conducted experimental measurement on a number of oxygen-sensitive film samples from home and abroad. The test results showed that: the fluorescence emission efficiency of a single oxygen-sensitive film varied with wavelength and exhibits a multimodal distribution. The fluorescence efficiency curves of the samples of the same type were similar, but there were significant differences in the fluorescence emission efficiency. The fluorescence emission efficiency of the samples with the largest excitation wavelength was 14.5% higher than that of the ones with the smallest excitation wavelength. The wavelength of the highest peak of the given three films were located differently, respectively lying at 401, 543 and 435 nm, meanwhile, all emission peaks were at 650 nm. it is great different of magnitude from 10 to 100 times of the maximum fluorescence emission efficiency for every oxygen sensor membrane. In practice, the observed fluorescence efficiency is only half of the highest, because the exit light wavelength used is not the best one with highest fluorescence, which indicates that it is necessary to optimize the wavelength selection of exit light in order to obtain the highest efficiency. In conclusion, this paper established a dissolved oxygen-sensitive membrane fluorescence emission efficiency detection system, proposed a method to effectively evaluate the quality of oxygen-sensitive membranes based on fluorescence emission efficiency, and carried out the experimental determination of oxygen-sensitive membrane samples. The work in this paper is expected to be used in the research of new oxygen-sensitive membrane materials and processes and the optimal design and manufacture of sensors.
|
Received: 2020-10-09
Accepted: 2021-02-18
|
|
Corresponding Authors:
ZHAO You-quan
E-mail: zhaoyouquan@tju.edu.cn
|
|
[1] Shriwastav A, Sudarsan G, Bose P, et al. Measurement, 2017, 106: 190.
[2] Stine J M, Beardslee L A, Sathyam R M, et al. Sensors and Actuators B: Chemical, 2020, 320: 128381.
[3] Li F, Wei Y, Chen Y, et al. Sensors, 2015, 15(12): 30913.
[4] Liao H, Qiu Z, Feng G, et al. The Research of Dissolved Oxygen Detection System Based on Fluorescence Quenching Principle: IEEE, 2011. 3575.
[5] Jia C, Chang J, Wang F, et al. Photonic Sensors, 2016, 6(2): 169.
[6] Zhang H, Liu T, Xu M, et al. Materials Letters, 2019, 251: 165.
[7] HU Xiao-ying, LI Jian-xiong, LIU An-hua(胡小英,李健雄,刘安华). Imaging Science and Photochemistry(影像科学与光化学), 2015, 33(6): 513.
[8] WANG Ting-ting, CHANG Jian-hua, ZHU Cheng-gang, et al(王婷婷,常建华,朱成刚,等). Transducer and Microsystem Technologies(传感器与微系统), 2016, 35(5): 39.
[9] de Acha N, Elosúa C, Martínez D, et al. Sensors and Actuators B: Chemical, 2017, 239: 1124.
[10] Wang Q, Zhang J, Li S. Instrumentation Science & Technology, 2019, 47(1): 19.
[11] Akram M, Mei Z, Shi J, et al. Talanta, 2018, 188: 124.
[12] Shehata N, Kandas I, Samir E. Nanomaterials, 2020, 10(2): 314.
[13] Lam H, Rao G, Loureiro J, et al. Talanta, 2011, 84(1): 65.
[14] Banerjee S, Kuznetsova R T, Papkovsky D B. Sensors & Actuators B: Chemical, 2015, 212: 229.
[15] Song D H, Kim H D, Kim K C. Journal of Visualization, 2011, 14(3): 295.
[16] Alexandrovskaya A Y, Melnikov P V, Safonov A V, et al. Materials Today Communications, 2020, 23: 100916.
[17] ZHOU Kun-peng, LIU Shuang-shuo, CUI Jian, et al(周昆鹏,刘双硕,崔 健,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2020, 40(4): 1143.
[18] Chen G, Li B. Dissolved Oxygen Detection Based on Light-to-Frequency Conversion: IEEE, 2018. 1302.
[19] Sun L, Dai W, Bao J, et al. Design and Research on the Optical Sensor of Dissolved Oxygen in Water Based on Fluorescence Quenching: SPIE, 2007. 67233N. |
[1] |
YU Hao-zhang, WANG Fei-fan, ZHAO Jian-xun, WANG Sui-kai, HE Shou-jie*, LI Qing. Optical Characteristics of Trichel Pulse Discharge With Needle Plate
Electrode[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3041-3046. |
[2] |
LIU Hong-wei1, FU Liang2*, CHEN Lin3. Analysis of Heavy Metal Elements in Palm Oil Using MP-AES Based on Extraction Induced by Emulsion Breaking[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3111-3116. |
[3] |
LIU Pan1, 2, 3, DU Mi-fang1*, LI Bin1, LI Jing-bin1, ZENG Lei1, LIU Guo-yuan1, ZHANG Xin-yao1, 4, ZHA Xiao-qin1, 4. Determination of Trace Tellurium Content in Aluminium Alloy by
Inductively Coupled Plasma-Atomic Emission Spectrometry Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3125-3131. |
[4] |
TIAN Fu-chao1, CHEN Lei2*, PEI Huan2, BAI Jie-qi1, ZENG Wen2. Diagnosis of Emission Spectroscopy of Helium, Methane and Air Plasma Jets at Atmospheric Pressure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2694-2698. |
[5] |
ZHANG Zhi-fen1, LIU Zi-min1, QIN Rui1, LI Geng1, WEN Guang-rui1, HE Wei-feng2. Real-Time Detection of Protective Coating Damage During Laser Shock Peening Based on ReliefF Feature Weight Fusion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2437-2445. |
[6] |
LI Zhi-xiong1, 2, LU Qian-shu1, ZHANG Lian-kai1, 2*, ZHANG Song1, YANG Wan-tao1, LI Can-feng1, FENG Jun1, LIU Zhen-chao1. Study on the Determination of Silver, Boron, Molybdenum, Tin in Geochemical Samples by the Method of Solid Sampling Carrier Distillation Atomic Emission Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2132-2138. |
[7] |
SI Yu1, LIU Ji1*, WU Jin-hui2, ZHAO Lei1, YAN Xiao-yan2. Optical Observation Window Analysis of Penetration Process Based on Flash Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 718-723. |
[8] |
YU Cheng-hao, YE Ji-fei*, ZHOU Wei-jing, CHANG Hao*, GUO Wei. Characteristics of the Plasma Plume and Micro-Impulse Generated by
Irradiating the Aluminum Target With a Nanosecond Laser Pulse at
Oblique Incidence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 933-939. |
[9] |
WANG Wei, WANG Yong-gang*, WU Zhong-hang, RAO Jun-feng, JIANG Song, LI Zi. Study on Spectral Characteristics of Pulsed Argon Vacuum Dielectric
Barrier Discharge[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 455-459. |
[10] |
LI Ru, YANG Xin, XING Qian-yun, ZHANG Yu. Emission Spectroscopy Study of Remote Ar Plasma[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 394-400. |
[11] |
HAO Jun1, WANG Yu2, LIU Cong2, WU Zan2, SHAO Peng2, ZU Wen-chuan2*. Application of Solution Cathode Glow Discharge-Atomic Emission Spectrometry for the Rapid Determination of Calcium in Milk[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3797-3801. |
[12] |
YANG Kun, CHEN Lei*, CHENG Fan-chong, PEI Huan, LIU Gui-ming, WANG Bao-huai, ZENG Wen. Emission Spectroscopy Diagnosis of Air Gliding Arc Plasma Under
Atmospheric Pressure Condition[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3006-3011. |
[13] |
HU Xuan1, CHENG Zi-hui1*, ZHANG Shu-chao2, SHI Lei2. Matrix Separation-Determination of Rare Earth Oxides in Bauxite by
Inductively Coupled Plasma-Atomic Emission Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3130-3134. |
[14] |
LIU Pan1, 2, LI Jing-bin1, ZHANG Jian-hao1, ZHANG Yi1, CHANG Guo-liang1, HE Peng-fei1, ZHANG Bin-bin1, ZHANG Xin-yao1, 3. Determination of Phosphorus in Welding Flux by Inductively Coupled Plasma Atomic Emission Spectrometry With Ultrasonic Assisted
Hydrochloric Acid Extraction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2824-2829. |
[15] |
LI Yan-fei1, 2,HAN Dong1, 2*,QIU Zong-jia1,LI Kang1,ZHAO Yi-kun1, 2,WAN Liu-jie1, 2,ZHANG Guo-qiang1, 2. Characteristic Emission Spectrum Analysis and Discharge Identification on the Development Process of Air Corona Discharge[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2956-2962. |
|
|
|
|