|
|
|
|
|
|
A Fluorescent Probe Based Host-Guest Complexation Between Cucurbit[7]uril and Neutral Red for the Detection of Paraquat Herbicide in Water Sample |
TANG Qing1, ZHANG Jing2, SONG Gui-xian2, XI Yun-yun2, HUANG Ying2*, TAO Zhu2, ZHOU Qing-di3, WEI Gang4* |
1. College of Tobacco Science, Guizhou University, Guiyang 550025, China
2. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China
3. School of Chemistry, the University of Sydney, NSW 2006, Australia
4. Commonwealth Scientific and Industrial Research Organization (CSIRO), Manufacturing, P. O. Box 218, Lindfield, NSW 2070, Australia |
|
|
Abstract We have now shown that a host-guest complex between cucurbit[7]uril (Q[7]) and neutral red (NR) can be used as a fluorescent probe for detecting the herbicide paraquat. The Q[7]/NR complex can be used to detect paraquat with high selectivity using fluorescence spectrometry. A linear correlation (ΔF=4.98+0.32c, r=0.999 1) was observed between the fluorescence intensity and the concentration of PQ over the concentration range (1~8)×10-6 mol·L-1. The detection limit for PQ was 1.40×10-8 mol·L-1. Recoveries obtained with the proposed method in river water examples were 104%~108%. Such method provides a rapid, selective and sensitive strategy for herbicide detection in real samples.
|
Received: 2016-09-20
Accepted: 2017-01-30
|
|
Corresponding Authors:
HUANG Ying, WEI Gang
E-mail: yinghung128@163.com;Gang.wei@csiro.au
|
|
[1] US Environmental Protection Agency, Drinking Water Health Advisory: Pesticides, Lewis Publishors, Chelsea, MI, 1989.
[2] Code of Federal Regulations, US Government Printing Office, Rev., 2001.
[3] Chen Y, Luo J, Yuan B, et al. Environ. Chem., 2012, 31: 748.
[4] Qiu K, Wu H, Zhang Z, et al. Chin. Pharm. J., 2009, 44: 1259.
[5] Zhang T, Tan J Y, Qi B K, et al. Chin. J. Nat. Med., 2009, 24: 161.
[6] Mallat E, Barzen C, Abuknesha R, et al. Anal. Chim. Acta, 2001, 427: 165.
[7] Raul G F, Pablo S J, Francisco S B, et al. Food Control, 2014, 41: 193.
[8] LIU Qi, JI Wen-bo, WANG Ai-jun(刘 奇,姬文博,王爱军). PTCA (Part B: Chem. Anal.)(理化检验:化学分册), 2014, 50: 594.
[9] Zhang N, Chen Y, Yu M, et al. Chem. Asian J., 2009, 4: 1697.
[10] GAO Jian-hua, ZHAI Hai-yun, CHEN Bin(高建华,翟海云,陈 彬). Chinese J. Anal. Chem.(分析化学), 2002, 30(3): 295.
[11] Freeman W A, Mock W L, Shih N Y, J. Am. Chem. Soc., 1981, 103:7367.
[12] Kim J, Jung I S, Kim S Y, et al. J. Am. Chem. Soc., 2000, 122:540.
[13] Kim K, Selvapalam N, Ko Y H, et al. Chem. Soc. Rev., 2007, 36, 267.
[14] Koner A L, Nau W M. Supramol. Chem., 2007, 19(1-2), 55.
[15] YANG Ji-yuan, SHEN Ai-zhuo, DU Li-ming, et al(杨吉元,申爱卓,杜黎明,等). Chinese J. Anal. Chem.(分析化学), 2010, 38(12): 1813.
[16] Wu W Y, Yang J Y, Du L M, et al. Spectrochimica Acta Part A, 2011, 79: 418.
[17] Li C F, Du L M, Wu H, et al. Chin. Chem. Lett., 2011, 22: 851.
[18] Zhang H M, Yang J Y, Du L M, et al. Anal. Methods., 2011, 3: 1156.
[19] Xing X Q, Zhou Y Y, Sun J Y, et al. Anal. Lett., 2013, 46: 694.
[20] Yao F, Liu H L, Wang G Q, et al. J. Environ. Sci., 2013, 25(6): 1245.
[21] Mohanty J, Bhasikuttan A C, Nau W M, et al. J. Phys. Chem. B., 2006, 110:5132.
[22] Kim J, Jung I S, Kim S Y, et al. J. Am. Chem. Soc., 2000, 122:540.
[23] Day A I, Blanch R J, Arnold A P, et al. Angew. Chem. 2002, 114:285. |
[1] |
YI Min-na1, 2, 3, CAO Hui-min1, 2, 3*, LI Shuang-na-si1, 2, 3, ZHANG Zhu-shan-ying1, 2, 3, ZHU Chun-nan1, 2, 3. A Novel Dual Emission Carbon Point Ratio Fluorescent Probe for Rapid Detection of Lead Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3788-3793. |
[2] |
HE Yan-ping, WANG Xin, LI Hao-yang, LI Dong, CHEN Jin-quan, XU Jian-hua*. Room Temperature Synthesis of Polychromatic Tunable Luminescent Carbon Dots and Its Application in Sensitive Detection of Hemoglobin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3365-3371. |
[3] |
LENG Jun-qiang, LAN Xin-yu, JIANG Wen-shuo, XIAO Jia-yue, LIU Tian-xin, LIU Zhen-bo*. Molecular Fluorescent Probe for Detection of Metal Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2002-2011. |
[4] |
QIAN Duo, SU Wen-en, LIU Zhi-yuan, GAO Xiao-yu, YI Yu-xin, HU Cong-cong, LIU Bin, YANG Sheng-yuan*. Soy Protein Gold Nanocluster as an “Off-On” Fluorescent Probe for the Detection of Bacillus Anthracis Biomarkers DPA[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1815-1820. |
[5] |
ZHENG Li-zhen1, 2, CHENG Cong2, MA Wen-hua2, WANG Zhuo-rui2, HU Dao-dao2*. Online Detection of Water Forms and Moisture Volatilization Behavior in Earthen Relics Based on FE Fluorescence Probe[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 383-388. |
[6] |
LÜ Chun-qiu1, SI Lu-lu1, PAN Zhao-jin2, LIANG Yang-lin1, LIAO Xiu-fen2, CHEN Cong-jin2*. Fast and Ratiometric Detection of Dimethoate Via the Dual- Emission Center Nitrogen-Doped Carbon Quantum Dots[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 468-474. |
[7] |
ZHAI Yan-ke1, PAN Yi-xing1, XIANG Hao1, XU Li1*, ZHU Ze-ce2, LEI Mi1. Coordination Interaction of DSAZn With Quercetin and High Sensitivity Detection of Quercetin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 122-128. |
[8] |
SONG Jiang-tao, YUAN Yue-hua, ZHU Yong-jun, WANG Yu-zhen, TIAN Mao-zhong*, FENG Feng*. Research Progress of Near-Infrared Fluorescent Probes for Hydrogen Sulfide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3321-3329. |
[9] |
XU Yi-fei, LIU Lu, SHI Shi-kao*, WANG Yue, PAN Yu-jing, MA Xing-wei. Spectroscopic Properties of Carbon Quantum Dots Prepared From Persimmon Leaves and Fluorescent Probe to Fe3+ Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2418-2422. |
[10] |
WAN Xiao-ming1, 2, ZENG Wei-bin1, 2, LEI Mei1, 2, CHEN Tong-bin1, 2. Micro-Distribution of Elements and Speciation of Arsenic in the Sporangium of Pteris Vittata[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 478-482. |
[11] |
LI Meng-yao1, 2, WANG Shu-ya1, XIE Yun-feng1, LIU Yun-guo3*, ZHAI Chen1*. Detection of Protease Deterioration Factor in Tomato by Fluorescence Sensor Array[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3477-3482. |
[12] |
JIA Hui-jie, ZHU Ning, GAO Yuan-yuan, WANG Ya-qi, SUO Quan-ling*. Effect of Substituent Structure of Benzothiazole Probe on Recognition to Metal Ion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3594-3598. |
[13] |
ZHU Dan-dan1, 2, QU Peng2*, SUN Chuang2, YANG Yuan2, LIU Dao-sheng1*, SHEN Qi3, HAO Yuan-qiang2*. A Benzothiazole-Based Long-Wavelength Fluorescent Probe for Dual-Response to Viscosity and H2O2[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1775-1779. |
[14] |
MA Hong-yan,WANG Jing-yuan, ZHANG Yue-cheng*, YANG Xiao-jun, CHEN Xiao-li. Determination of Dopamine by Fluorescence Quenching-Recovery Method with Peanut Carbon Quantum Dots as Probe[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1093-1098. |
[15] |
LIAN Jie1, REN Yi-fei2, YANG Rui-qin1*, HAO Hong-xia3. Rapid Detection System of 2,4,6-Trinitrophenol (TNP) Based on Fluorescent Probe[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(03): 804-808. |
|
|
|
|