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| Quantitative Analysis of Manganese in Low Alloy Steel with Micro-Laser-Induced Breakdown Spectroscopy |
| WANG Xu-zhao, HAO Zhong-qi, GUO Lian-bo, LI Xiang-you*, ZENG Xiao-yan，LU Yong-feng |
| Wuhan National Laboratory for Optoelectronics, Laser and Terahertz Technology Division, Huazhong University of Science and Technology, Wuhan 430074, China |
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Abstract Manganese in the low alloy steel was analyzed quantitatively using micro-laser-induced breakdown spectroscopy. The spatial resolution of 20 μm and the single pulse limit of detection of 0.10% were obtained. The calibration curve of Mn was established with basic calibration method, with determination coefficient (R2) of 0.97. The average relative error of Mn concentration prediction on 7 samples is 12.91%, and the root-mean-square error of cross-validation (RMSECV) is 0.11%. The R2 reaches 0.99 when using internal calibration method, as well as the average relative error of Mn concentration prediction on 7 samples and RMSECV were decreased to 7.25% and 0.07%, respectively. These results show that MicroLIBS technique is an effective approach for material surfaces quantitative microanalysis.
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Received: 2014-07-11
Accepted: 2015-02-10
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Corresponding Authors:
LI Xiang-you
E-mail: xyli@mail.hust.edu.cn
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