光谱学与光谱分析 |
|
|
|
|
|
Efficient Polymer Solar Cells Using ZnO Electron Transporting Layer with Layered Magentron Sputtered ZnO Film and/or Modified with Functionalized Carbon Nanopartilces |
ZHOU Jian-ping1*, LI Xin-yu1, ZHU Feng2, CHEN Xiao-hong2*, XU Zheng3 |
1. School of Automation Engineering, Shanghai University of Electric Power, Shanghai 200090, China 2. Engineering Research Center for Nanophotonics and Advanced Instrument, Ministry of Education, School of Physics and Materials Science, East China Normal University, Shanghai 200062, China 3. Key Laboratory of Luminescence and Optical Information of Ministry of Education, Beijing Jiaotong University, Beijing 100044, China |
|
|
Abstract Polymer solar cells (PSCs) with ZnO electron transporting layer has been widely studied because ZnO has superior electron transport capability and high light transmittivity. However, lots of defects existed in ZnO film fabricated with sol-gel method and vacuum sputtering deposition can greatly increase carrier recombination at the ZnO interface. Therefore, it is important to enhance the performance of PSCs to inhibit defects and improve contact quality of ZnO interface. The regioregular poly(3-hexylthiophene) (P3HT) and 6,6-phenyl C61-butyric acid methylester (PCBM) based inverted PSCs with ZnO electron transporting layer have been developed by using layered magnetron sputtered ZnO and/or ionic liquid functionalized carbon nanopartilces (ILCNs) modification. The power conversion efficiencies (PCEs) of PSCs with ZnO layer sputtered with Ar and Ar/O2 gas are 2.2% and 2.8%, respectively. PSCs modified with ILCNs or layered sputtered ZnO can respectively reach 3.4% and 3.1%, and further up to 3.8% using layered sputtered ZnO and ILCNs integrated modification. PSCs using modified ZnO layer show the vanishment of negative capacitive behavior, lowering reverse dark current and better diode characteristics. The results indicated that using layered sputtered ZnO or ILCNs, or both integrated modification can efficiently inhibit the defects of ZnO interface and improve contact quality ZnO/P3HT∶PCBM interface. However, this integrated modification method is a more efficient strategy to enhance ZnO layer electron transporting and extraction capabilities, and further improve PCEs of PSCs.
|
Received: 2016-01-25
Accepted: 2016-05-20
|
|
Corresponding Authors:
ZHOU Jian-ping, CHEN Xiao-hong
E-mail: zhoujianping@shiep.edu.cn;xhchen@phy.ecnu.edu.cn
|
|
[1] Lu Zhe, Chen Xiaohong, Zhou Jianping, et al. Organic Electronics, 2015, 17: 364. [2] Jia Xiangkun, Jiang Ziyao, Chen Xiaohong, et al. ACS Applied Materials & Interfaces, 2016, 8: 3792. [3] Jiang Ziyao, Chen Xiaohong, Lin Xuanhuai, et al. Solar Energy Materials and Solar Cells, 2016, 146: 35. [4] Xu Weilong, Wu Bo, Zheng Fei, et al. Organic Electronics, 2015, 25: 266. [5] Etxebarria Ikerne, Guerrero Antonio, Albero Josep, et al. Organic Electronics, 2014, 15(11): 2756. [6] Kam Zhiming, Yang Qingyi, Wang Xizu, et al. Organic Electronics, 2014, 15(7): 1306. [7] Chen Xiaohong, Yang Jiaxiang, Haley Lim Yi Xuan Candy, et al. Organic Electronics, 2010, 11(12): 1942. [8] Liao Sih-Hao, Jhuo Hong-Jyun, Yeh Po-Nan, et al. Scientific Reports, 2014, 4: 6813. [9] Hu Ting, Li Fan, Yuan Kai, et al. ACS Applied Materials & Interfaces, 2013, 5(12): 5763. [10] Jouane Youssef, Colis Silviu, Schmerber Guy, et al. Thin Solid Films, 2015, 576: 23. [11] Jouane Youssef, Colis Silviu, Schmerber Guy, et al. Organic Electronics, 2013, 14(7): 1861. [12] Sharma Anirudh, Franklin Joseph B, Singh Birendra, et al. Organic Electronics, 2015, 24: 131. [13] Chen Xiaohong, Yang Jiaxiang, Lu Jiong, et al. Applied Physics Letters, 2009, 95(13): 133305. [14] Lee Ka Eun, Wang Mingsong, Kim Eui Jung, et al. Current Applied Physics, 2009, 9(3): 683. |
[1] |
LI Shi-lun1, LIU Tao2, SONG Wen-min3, WANG Tian-le2, LIU Wei1, CHEN Liang1, LI Zhi-gang2*, FENG Shang-shen1*. Study of Two-Dimensional Ordered Magnetic Co Nanosphere Array Film Construction and Its Optical Properties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2037-2042. |
[2] |
LIAO Yi-min1, YAN Yin-zhou1, WANG Qiang2*, YANG Li-xue3, PAN Yong-man1, XING Cheng1, JIANG Yi-jian1, 2. Laser-Induced Growth Device and Optical Properties of ZnO
Microcrystals[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3000-3005. |
[3] |
FU Xing-hu, WANG Zhen-xing, MA Shuang-yu, ZHAO Fei, LU Xin, FU Guang-wei, JIN Wa, BI Wei-hong. Preparation and Properties of Micro-Cavity Silver Modified Fiber SERS Probe[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2800-2806. |
[4] |
YANG Chang-hu, YUAN Jian-hui. Effects of Thickness on Spectral Properties of Undoped ZnO Thin Films[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2835-2838. |
[5] |
WANG Shi-xia, HU Tian-yi, YANG Meng. Study on Preparation of Ag-Doped ZnO Nanomaterials and Phase Transition at High Pressure Using Diamond Anvil Cell and Raman Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 484-488. |
[6] |
LIN Shun-hui,ZHANG Li-hui, LIU Yong-quan, WANG Xiao-kun, LIN Chun-lei, YU Yun-peng*. Thermal Annealing Effect on Photoluminescence of Y2O3∶Eu3+ Thin Films Prepared by Magnetron Sputtering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3336-3340. |
[7] |
SUN Ke-wei, JIN Dan, YANG Chun-li. Effects of Temperature on the Infrared Emission Performance of AZO Films[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(06): 1975-1979. |
[8] |
QIAO Jin, XU Chang-shan*, ZHANG Hai-jiao, SHAO Hai-ling, ZHENG Bo-wen, HE Hui-min. Effects of ZnO NPs on the Photosynthetic Processes of Egeria najas[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1495-1502. |
[9] |
YIN Wen-yi1, LIU Yu-zhu1,2*, ZHANG Qi-hang1, LI Bing-sheng3*, QIN Chao-chao4. Optical Excitation Characteristics of ZnO under the Radiation Fields[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1348-1352. |
[10] |
LIU Jun-shao1, HUANG Lei2, XIE Wen-ju1, LIN Hao1, CHEN Yi-ping2, PAN Hai-bo2*. Preparation of Four Phenoxy Phthalocyanine Zinc/ZnO Composites with in-situ Method by DBU Liquid Phase Catalyst and Its Photocatalytic Selectivity[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1486-1491. |
[11] |
HUANG Jie, HU Chen-li, MAO Jian-min, SHEN Wei-min, WANG Le, YU Jing. Synthesis and Fluorescence Property of CdS/ZnO Composite Structure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2788-2791. |
[12] |
WU Cheng-ling1, GUO Jun-hong1, 2, YAO Heng-bin1, PAN Ling-nan1, WANG Fei1, WU Wen-qi1, JI Tong1, HU Fang-ren1, 2*. Study on the Photoluminescence Properties of ZnO Single Crystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1700-1702. |
[13] |
CHEN Jing-han, YAO Wen-qing*, ZHU Yong-fa . Photoluminescence of Silicon Nitride-Based ZnO Thin Film Developed with RF Magnetron Sputtering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(02): 391-393. |
[14] |
YANG Bing-yang1,2, HE Da-wei1,2*, ZHUO Zu-liang1,2, WANG Yong-sheng1,2 . Influence of Dimethyl Sulfoxide as Processing Additive for Improving Efficiency of Polymer Solar Cells[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(01): 287-292. |
[15] |
LU Bao-qi, XU Yao-xian, SHEN Guang-yao, JI Jiang-hua, WANG Lin-jun. Raman Spectra Study on the Structure and Thermal Stability of Vacuum Annealed Cr-DLC Films Prepared with UBMS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(11): 3568-3571. |
|
|
|
|