光谱学与光谱分析 |
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Study on Microwave Co-Pyrolysis of Low Rank Coal and Circulating Coal Gas |
ZHOU Jun1,2, YANG Zhe1, LIU Xiao-feng3, WU Lei4, TIAN Yu-hong1,2, ZHAO Xi-cheng1,2 |
1. School of Metallurgical Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, China 2. Shaanxi Province Metallurgical Engineering and Technology Research Centre, Xi’an 710055,China 3. Yulin Science &Technology Information Research Institute, Yulin 719000, China 4. Xinjiang Chemical Engineering Design & Research Institute Co., Ltd., Urumqi 830006, China |
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Abstract The pyrolysis of low rank coal to produce bluecoke, coal tar and gas is considered to be the optimal method to realize its clean and efficient utilization. However, the current mainstream pyrolysis production technology generally has a certain particle size requirements for raw coal, resulting in lower yield and poorer quality of coal tar, lower content of effective components in coal gas such as H2, CH4, CO, etc. To further improve the yield of coal tar obtained from the pyrolysis of low rank coal and explore systematically the effect of microwave power, pyrolysis time and particle size of coal samples on the yield and composition of microwave pyrolysis products of low rank coal through the analysis and characterization of products with FTIR and GC-MS, introducing microwave pyrolysis of low rank coal into the microwave pyrolysis reactor circularly was suggested to carry out the co-pyrolysis experiment of the low rank coal and coal gas generated by the pyrolysis of low rank coal. The results indicated that the yield of the bluecoke and liquid products were up to 62.2% and 26.8% respectively when the optimal pyrolysis process conditions with the microwave power of 800W, pyrolysis time of 40min, coal samples particle size of 5~10 mm and circulating coal gas flow rate of 0.4 L·min-1 were selected. The infrared spectrogram of the bluecoke under different microwave power and pyrolysis time overlapped roughly. The content of functional groups with —OH,CO,CC and C—O from the bluecoke through the pyrolysis of particle size coal samples had a larger difference. To improve microwave power, prolonging pyrolysis time and reducing particle size of coal samples were conducive to converting heavy component to light one into coal tar.
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Received: 2015-01-23
Accepted: 2015-04-21
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Corresponding Authors:
ZHOU Jun
E-mail: xazhoujun@126.com
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