光谱学与光谱分析 |
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Mass Spectrometric Methods for Colorative Mechanism Analysis of Yaozhou Porcelain Glaze |
XIAO Yuan-fang, HE Miao-hong, ZHANG Shu-di, HANG Wei* |
Department of Chemistry and Ministry of Education Key Lab of Spectrochemical Analysis & Instrumentation, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China |
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Abstract An in-house-built femtosecond laser ionization time-of-flight mass spectrometry (fs-LI-TOFMS) has been applied to the multi-elemental analysis of porcelain glaze from Yaozhou kiln. The samples are selected representing products of different dynasties, including Tang, Five, Song, Jin, and Ming Dynasty. For exploring the colorative mechanism of Yaozhou porcelain through the elemental analysis of the glaze, the effects of all potential coloring elements, especially transition elements, were considered. There was a speculation that the typical Co-Cr-Fe-Mn recipe was used in the fabrication of Yaozhou black glaze; the low content of Fe and high content of Ni resulted in the porcelain of white glaze; an increase content of P could lead the porcelain to be yellow-glazed. Undoubtedly, this research is an important supplement to the study of the colorative mechanism of the Yaozhou porcelain system.
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Received: 2015-04-06
Accepted: 2015-06-25
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Corresponding Authors:
HANG Wei
E-mail: weihang@xmu.edu.cn
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