光谱学与光谱分析 |
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Preparation and Up-Conversion Luminescence Properties of Yb3+/Tm3+ Co-Doped Sb2O4 Powder |
LI Rui-qin, QIU Jian-bei, YANG Zheng-wen*, LIAO Jia-yan, WU Hang-jun, LAI Shen-feng, SONG Zhi-guo, YANG Yong, ZHOU Da-cheng, WANG Rong-fei |
College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China |
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Abstract The Sb2O4∶Yb3+, Tm3+ up-conversion luminescence powder with excellent physical, chemical stability and relative low phonon energy was synthesized by the high temperature solid-state reaction and its up-conversion luminescence property was investigated. Under the 980 nm excitation, infrared and blue up-conversion emissions centered at 800 and 480 nm were observed, which were assigned to the 1G4→3H6 and 3H4→3H6 transitions of Tm3+, respectively. The influence of Yb3+ and Tm3+ concentration on the up-conversion emission property was also obtained. The up-conversion luminescence increases with increasing of Yb3+ and Tm3+ concentration. Additionally, the up-conversion luminescence mechanism was discussed based on the dependence of Tm3+ up-conversion luminescence on pump power. It is interesting that two photon excitation processes for blue and infrared emission were observed in the Sb2O4∶Yb3+, Tm3+ powder under a 980 nm excitation. Based on the energy level diagram of Tm3+ and Yb3+ ions, we think that two photons blue emission is contributed to the cooperation energy transfer between Tm3+ and Yb3+ ions. We believe that the Sb2O4∶Yb3+, Tm3+ up-conversion luminescence powder will have potential application for new optical devices in up-conversion color displays, sensors, detection of infrared radiation, and lasers.
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Received: 2013-05-03
Accepted: 2013-09-16
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Corresponding Authors:
YANG Zheng-wen
E-mail: yangzw@kmust.edu.cn
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[1] Jiang Shan, Zhang Yong, Lim Kian Meng, et al. Nanotechnology, 2009, 20(15): 155101. [2] Wang Meng, Hou Wei, Mi Congcong, et al. Anal. Chem., 2009, 81: 8783. [3] Qin Weiping, Zhang Daisheng, Zhao Dan, et al. Chem. Commun., 2010, 46: 2304. [4] XU Xing-cheng, ZHOU Ya-xun, WANG Sen, et al(徐星辰,周亚训,王 森,等). Acta Photonica Sinica(光子学报), 2012, 41(9): 1028. [5] GAN Zong-song, YU Hua, LI Yan-ming,et al(甘棕宋,余 华,李妍明, 等). Acta Physica Sinica(物理学报), 2008, 9(57): 5699. [6] FENG Yan, CHEN Xiao-bo, LI Kun, et al(冯 衍,陈晓波,李 昆,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),1998,18(4):390. [7] Chen Lei, Wei Xianhua, FU Xu. Science Direct, 2012, 22(5): 1156. [8] Ming Chengguo, Song Feng, Wang Qingru, et al. Journal of Luminescence, 2011, 31: 271. [9] Pandozzi F, Vetrone F, Boyer J C, et al. J. Phys. Chem. B, 2005, 109(37): 17400. [10] LI Hui, YANG Kui-sheng, QI Ning, et al(李 慧, 杨魁胜, 祁 宁, 等). Chinese Journal of Inorganic Chemistry(无机化学报), 2012, 28(2): 221. [11] Kushida T. J. Phys. Soc., 1993, 34(5): 1318. |
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