光谱学与光谱分析 |
|
|
|
|
|
Quantitative Analysis of Vanadium and Titanium in Steel Samples Using LIBS |
GUO Lian-bo1, ZHANG Yong1, HAO Zhong-qi1, SHEN Meng1, LI Chang-mao1, REN Zhao2, LI Xiang-you1*, ZENG Xiao-yan1 |
1. Wuhan National Laboratory for Optoelectronics, Laser and Terahertz Technology Division, Huazhong University of Science and Technology, Wuhan 430074, China 2. Wuhan New Research and Development Laser Engineering Co., Ltd., Wuhan 430074, China |
|
|
Abstract The concentrations of vanadium and titanium elements in the steel samples were quantitatively analyzed by Laser-induced breakdown spectroscopy technique in the present paper. The lines of V (V Ⅰ: 440.85 nm) and Ti (Ti Ⅰ: 334.19 nm) were chosen as the quantitative analysis spectral lines, while spectral line of Fe (Fe Ⅰ: 438.35 nm) was chosen as the internal calibration line due to it being the matrix element. Then the calibration curves of V and Ti elements were established with basic calibration method and internal calibration method respectively to quantitatively analyze the concentrations of vanadium and titanium elements in steel. The experimental results showed that the fitting correlation coefficient (R2) of vanadium and titanium elements are 0.987 5 and 0.990 9 when using basic calibration method, and their maximum relative errors of measurement are 11.09% and 4% respectively; while the fitting correlation coefficient (R2) of vanadium and titanium elements reachs 0.995 2 and 0.992 1 respectively when using internal calibration method, at the same time, the relative errors of measurement for vanadium and titanium elements were decreased to be lower than 4%. The results of this study demonstrated that the concentration measurement of vanadium and titanium elements in the steel was more suitable with internal calibration method in laser-induced breakdown spectroscopy.
|
Received: 2013-04-08
Accepted: 2013-06-25
|
|
Corresponding Authors:
LI Xiang-you
E-mail: xyli@mail.hust.edu.cn
|
|
[1] Volker S, Jens V, Reinhard N, et al. Anal. At. Spectrom., 2004, 19, 451. [2] Winefordner J D, Gomushkin I B, Correll T, et al. J. Anal. At. Spectrom.,2004, 19: 1065. [3] Singh J P, Thakur S N. Laser-Induced breakdown Spectroscopy. Oxford: Elsevier Science, 2007. 1. [4] Miziolect A W, Palleschi V, Schechter eds. I. Laser-Induced Breakdown Spectroscopy (LIBS) - Fundamentals and Applications, Cambridge University Press, Cambridge, 2006. [5] Cremers D A, Radzeimki L J. Handbook of Laser Induced Breakdown Spectroscopy, Wiley, New York, 2006. [6] Haider A, Wahadoszamen M, Sadat M E, et al. Optics & Laser Technology, 2010, 42: 969. [7] WANG Qi,CHEN Xing-long, YU Rong-hua, et al(王 琦,陈兴龙,余嵘华, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2011, 31(9):2546. [8] Lucena P, Cabal′in L M, Pardo E, et al. Talanta, 1998, 47: 143. [9] Giacomo A D. Spectrochimica Acta Part B, 2003, 58: 71. [10] YU Shi-juan, CHEN Jin-zhong, SU Hong-xin, et al(玉世娟, 陈金忠, 苏红新, 等). Metallurgical Analysis(冶金分析), 2010, 30(10): 11. [11] LIU Yan, LU Ji-dong, LI Ping, et al(刘 彦, 陆继东, 李 娉, 等). Proceedings of the CSEE(中国电机工程学报), 2009, 29(5): 1. [12] CUI Zhi-feng, ZHANG Xian-yi, YAO Guan-xin, et al(崔执凤, 张先燚, 姚关心, 等). Acta Physica Sinica(物理学报), 2006, 55(9): 4506. [13] XIN Ren-xuan(辛仁轩). Plasma Emission Spectrometry Analysis(等离子体发射光谱分析). 2nd ed.(第2版). Beijing: Chemical Industry Press(北京:化学工业出版社),2010. 123. [14] XIE Cheng-li, LU Ji-dong, YAO Shun-chun, et al(谢承利, 陆继东, 姚顺春, 等). Laser & Optoelectronics Progress(激光与光电子进展), 2009, 46(11): 65. |
[1] |
LIU Jia1, 2, GUO Fei-fei2, YU Lei2, CUI Fei-peng2, ZHAO Ying2, HAN Bing2, SHEN Xue-jing1, 2, WANG Hai-zhou1, 2*. Quantitative Characterization of Components in Neodymium Iron Boron Permanent Magnets by Laser Induced Breakdown Spectroscopy (LIBS)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 141-147. |
[2] |
TIAN Fu-chao1, CHEN Lei2*, PEI Huan2, BAI Jie-qi1, ZENG Wen2. Study of Factors Influencing the Length of Argon Plasma Jets at
Atmospheric Pressure With Needle Ring Electrodes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3682-3689. |
[3] |
YANG Wen-feng1, LIN De-hui1, CAO Yu2, QIAN Zi-ran1, LI Shao-long1, ZHU De-hua2, LI Guo1, ZHANG Sai1. Study on LIBS Online Monitoring of Aircraft Skin Laser Layered Paint Removal Based on PCA-SVM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3891-3898. |
[4] |
SUN Cheng-yu1, JIAO Long1*, YAN Na-ying1, YAN Chun-hua1, QU Le2, ZHANG Sheng-rui3, MA Ling1. Identification of Salvia Miltiorrhiza From Different Origins by Laser
Induced Breakdown Spectroscopy Combined with Artificial Neural
Network[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3098-3104. |
[5] |
LIU Hong-wei1, FU Liang2*, CHEN Lin3. Analysis of Heavy Metal Elements in Palm Oil Using MP-AES Based on Extraction Induced by Emulsion Breaking[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3111-3116. |
[6] |
LIU Shu1, JIN Yue1, 2, SU Piao1, 2, MIN Hong1, AN Ya-rui2, WU Xiao-hong1*. Determination of Calcium, Magnesium, Aluminium and Silicon Content in Iron Ore Using Laser-Induced Breakdown Spectroscopy Assisted by Variable Importance-Back Propagation Artificial Neural Networks[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3132-3142. |
[7] |
LIU Pan1, 2, 3, DU Mi-fang1*, LI Bin1, LI Jing-bin1, ZENG Lei1, LIU Guo-yuan1, ZHANG Xin-yao1, 4, ZHA Xiao-qin1, 4. Determination of Trace Tellurium Content in Aluminium Alloy by
Inductively Coupled Plasma-Atomic Emission Spectrometry Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3125-3131. |
[8] |
ZHU Yu-qi1, 2, ZHANG Xin2, DU Pan-pan2, LIU Shu1, ZHANG Gui-xin1, 2, GUAN Song-lei2*, ZHENG Zhong1*. Infrared Spectroscopy and X-Ray Spectroscopy Combined With
Inductively Coupled Plasma Mass Spectrometry for Quality
Control of Mongolian Medicine Yu Grain Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3163-3169. |
[9] |
YANG Fan1, HAO Liu-cheng1, KE Wei2, LIU Qing1, WANG Jun1, CHEN Min-yuan2, YUAN Huan2*, YANG Ai-jun2, WANG Xiao-hua2, RONG Ming-zhe2. Research on Effect of Laser Incident Angle on Laser-Induced Plasma at Low Pressure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2740-2746. |
[10] |
KANG Ying1, ZHUO Kun1, LIAO Yu-kun1, MU Bing1, QIN Ping2, LI Qian1, LUAN Xiao-ning1*. Quantitative Determination of Alcohol Concentration in Liquor Based on Polarized Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2768-2774. |
[11] |
ZHANG Zhi-fen1, LIU Zi-min1, QIN Rui1, LI Geng1, WEN Guang-rui1, HE Wei-feng2. Real-Time Detection of Protective Coating Damage During Laser Shock Peening Based on ReliefF Feature Weight Fusion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2437-2445. |
[12] |
LI Chang-ming1, CHEN An-min2*, GAO Xun3*, JIN Ming-xing2. Spatially Resolved Laser-Induced Plasma Spectroscopy Under Different Sample Temperatures[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2032-2036. |
[13] |
LI Shi-lun1, LIU Tao2, SONG Wen-min3, WANG Tian-le2, LIU Wei1, CHEN Liang1, LI Zhi-gang2*, FENG Shang-shen1*. Study of Two-Dimensional Ordered Magnetic Co Nanosphere Array Film Construction and Its Optical Properties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2037-2042. |
[14] |
ZHAO Yang1, ZHANG Lei2, 3*, CHENG Nian-kai4, YIN Wang-bao2, 3*, HOU Jia-jia5, BAI Cheng-hua1. Research on Space-Time Evolutionary Mechanisms of Species Distribution in Laser Induced Binary Plasma[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2067-2073. |
[15] |
YAN Ming-liang1, ZHANG Chen-long2, ZHAO Lian-xiang3, ZHAO Hua-he4, GAO Xun2*. Spectral Characteristics of Ge Plasma Induced by Femtosecond Pulsed Laser Ablation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2095-2098. |
|
|
|
|