| 光谱学与光谱分析 |
|
|
|
|
|
| Adsorption of Heavy Metal Ions on Two Types of Manganese Oxides Analyzed by AAS and AFS |
| XU Liu, ZHANG Li-chun, HOU Xian-deng, XU Kai-lai* |
| College of Chemistry, Sichuan University, Chengdu 610064, China |
|
|
|
|
Abstract Two types of manganese oxides, the octahedral layer structure(OL) and the octahedral molecular tunnel structure(OMS), were controllably synthesized via a facilely hydrothermal route and used to remove heavy metal ions(Pb2+, Cu2+, Ni2+, Hg2+) in solutions. The heavy metal ion concentrations before and after adsorption were determined by atomic absorption spectroscopy (AAS) and atomic fluorescence spectroscopy (AFS) to evaluate the material adsorption performance. The competitive adsorption of the four ions (Pb2+, Cu2+, Ni2+, Hg2+) on manganese oxides was also investigated. The results showed that OMS exhibited better adsorption ability than OL and had excellent adsorption selectivity to Pb2+, with 98% adsorption efficiency in two minutes. Therefore, this can be proposed as a simple, green and efficient method for treatment of polluted water.
|
|
Received: 2012-03-08
Accepted: 2012-06-20
|
|
|
|
Corresponding Authors:
XU Kai-lai
E-mail: xukailai@scu.edu.cn
|
|
[1] Sharma V B, Sohn M. Environment International, 2009, 35: 332.
[2] Scott M J, Morgan J J. Environ. Sci. Technol., 1995, 29(8): 1898.
[3] Li Y, Jiang Y, Yan X P, et al. Anal. Chem., 2002, 74(5): 1075.
[4] Brock S L, Duan N G, Tian Z R, et al. Chem. Mater., 1998, 10(10): 2619.
[5] Clark A. Ind. Eng. Chem., 2009, 45(7): 1476.
[6] Chen H M, He J H. J. Phys. Chem. C, 2008, 112(45): 17540.
[7] Post J E. Proc. Natl. Acad. Sci. USA, 1999, 96: 3447.
[8] Feng Q, Kanoh H, Ooi K. J. Mater. Chem., 1999, 9: 319.
[9] Rziha T, Gies H, Rius J. Eur. J. Mineral, 1996, 8: 675.
[10] Suib S L. Acc. Chem. Res., 2008, 41(4): 479.
[11] Feng Q, Kanoh H, Miyai Y, et al. Chem. Mater. 1995, 7(9): 1722.
[12] Han R P, Lu Z, Zou W H, et al. Journal of Hazardous Materials B, 2006, 137: 480.
[13] Tani Y, Miyata N, Ohashi M, et al. Environ. Sci. Technol., 2004, 38(24): 6618.
[14] Zhang L C, Zhou Q, Liu Z H, et al. Chem. Mater., 2009, 21(21): 5066.
[15] Zhang L C, Kang L P, Lü H, ert al. J. Mater. Res., 2008, 23(3): 780.
[16] Zhang L C, Liu Z H, Lü H, et al. J. Phys. Chem. C, 2007, 111(24): 8418. |
| [1] |
WANG Peng1, GAO Yong-bao1*, KOU Shao-lei1, MEN Qian-ni1, ZHANG Min1, HE Tao1, YAO Wei2, GAO Rui1, GUO Wen-di1, LIU Chang-rui1. Multi-Objective Optimization of AAS Conditions for Determination of Gold Element Based on Gray Correlation Degree-RSM Model[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3117-3124. |
| [2] |
CHAI Lin-lin, Areyi Mulati, Shawket Abliz*. Analysis the Adsorption Behaviors of Acetic Acid Modified Sand Grains for Lead Ions by Atomic Absorption Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2775-2778. |
| [3] |
ZHENG Li-zhen1, 2, CHENG Cong2, MA Wen-hua2, WANG Zhuo-rui2, HU Dao-dao2*. Online Detection of Water Forms and Moisture Volatilization Behavior in Earthen Relics Based on FE Fluorescence Probe[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 383-388. |
| [4] |
LIU Pan1, 2, DU Mi-fang1, LI Zhi-ya1, GAO Ling-qing1, 3, HAN Hua-yun4, ZHANG Xin-yao1, 3. Determination of Trace Tellurium Content in Steel by Hydride Generation Atomic Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3103-3108. |
| [5] |
YU Xin, ZHOU Wei*, XIE Dong-cai, XIAO Feng, LI Xin-yu. The Study of Digital Baseline Estimation in CVAFS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2392-2396. |
| [6] |
WANG Peng, MEN Qian-ni*, GAN Li-ming, YANG Ke. Research on Optimization of Determination Conditions for Trace
Gold Analysis by Graphite Furnace Atomic Absorption
Spectrometry Based on RSM Model[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2334-2339. |
| [7] |
HOU Ya-ru, LU Ji-long*, FAN Yu-chao, Abudusalamu·KADIER, TANG Xiao-dan, WEI Qiao-qiao, GUO Jin-ke, ZHAO Wei. Uncertainty Evaluation and Method Improvement of Determination of Copper, Lead, and Zinc in Rocks by Atomic Absorption Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2101-2106. |
| [8] |
SONG Hong-yan, ZHAO Hang, YAN Xia, SHI Xiao-feng, MA Jun*. Adsorption Characteristics of Marine Contaminant Polychlorinated Biphenyls Based on Surface-Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 704-712. |
| [9] |
FAN Chun-hui1,2, ZHENG Jin-huan3, WANG Yu-fei3, SU Zhe3, LIN Long-jian3, YANG Chen3. Adsorption of Cadmium on Fe-Mn Nodules Derived From Soil by Spectral Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 616-621. |
| [10] |
WEI Yi-hua1, HUANG Qing-qing2, ZHANG Jin-yan1*, QIU Su-yan1, 3, TU Tian-hua1, YUAN Lin-feng1, DAI Ting-can1, ZHANG Biao-jin1, LI Wei-hong1, YAN Han1. Determination of 5 Kinds of Selenium Species in Livestock and Poultry Meat With Ion Pair Reversed Phase Liquid Chromatography-Atomic Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3822-3827. |
| [11] |
LIU Qin-rong1, DU Zi-wei1, LI Jia-zhen1, WANG Yi-shuo1, 3*, GU Xuan2, CUI Xiu-mei2. Analysis and Evaluation of Inorganic Elements in Salvia miltiorrhiza and Rhizosphere Soils From Different Areas[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3618-3624. |
| [12] |
TANG Gu-hua, ZHANG Hui, SUN Xin-yuan, XU Meng, OUYANG Jian-ming*. Differences in Adsorption of Anionic Surfactant AOT by Calcium Oxalate Dihydrate With Different Morphologies[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(04): 1079-1085. |
| [13] |
CHEN Hai-jie1, 2, MA Na1, 2, BO Wei1, 2, ZHANG Ling-huo1, 2, BAI Jin-feng1,2, SUN Bin-bin1, 2, ZHANG Qin1, 2, YU Zhao-shui1, 2*. Research on the Valence State Analysis Method of Selenium in Soil and Stream Sediment[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 871-874. |
| [14] |
MIAO Chuang-he1,2, LÜ Yi-zhong1, 2*, YU Yue1, ZHAO Kang1. Study on Adsorption Behavior of Dissolved Organic Matter Onto Soil With Spectroscopic Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3832-3838. |
| [15] |
CHEN Hai-jie1, 2, MA Na1, 2, BAI Jin-feng1, 2, CHEN Da-lei3, GU Xue1, 2, YU Zhao-shui1, 2, SUN Bin-bin1, 2, ZHANG Qin1, 2*. Study on Determination of Se in Geochemical Samples by External Supply H2-Hydride Generation Atomic Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2896-2900. |
|
|
|
|
