光谱学与光谱分析 |
|
|
|
|
|
FTIR and XPS Analysis of Characteristics of Synthesized Zeolite and Removal Mechanisms for Cr(Ⅲ) |
FAN Chun-hui, MA Hong-rui, HUA Li, WANG Jia-hong, WANG Hai-jun |
School of Resource & Environment, Shaanxi University of Science & Technology, Xi’an 710021, China |
|
|
Abstract Zeolite products were synthesized from fly ash using one-stage method, and the characteristics of zeolite were analyzed with approaches of XRD, SEM and ζ potential, the removal mechanism for Cr(Ⅲ) was further investigated by FTIR and XPS. From the pH value of 8 to 12, the negative ζ potential of NaP1 zeolite products decreased from -8.72 to -24.46 mV. The pseudo-second-order kinetics equation and Langmuir isotherm fit better the reaction, the maximum adsorption capacity was 33.557 0 mg·g-1. Functional groups of —OH and Si—O were important for Cr(Ⅲ) removal shown from FTIR spectra. The Cr(2p3/2) peak was found at the binding energy of 576.45 eV, indicating the effectiveness of reaction. The binding energy of Si—Si and Si—O increased by 0.25 eV and 0.60 eV, respectively, coordination effect might work between functional groups and Cr(Ⅲ), and O(1s) binding energy decreased after the adsorption process. The removal for Cr(Ⅲ) on zeolite was the comprehensive results of physical and chemical adsorption effects.
|
Received: 2011-06-12
Accepted: 2011-09-15
|
|
Corresponding Authors:
FAN Chun-hui
E-mail: fanchunhui@sust.edu.cn
|
|
[1] Ahmaruzzaman M. Prog. Energy Combust. Sci., 2010, 36: 327. [2] Panias D, Giannopoulou I, Perraki T. Colloids Surf., A, 2007, 301: 246. [3] Wang S, Wu H. J. Hazard. Mater., 2006, 136: 482. [4] State Environmental Protection Administration of China(国家环境保护总局). Monitoring and Analyzing Methods for the Examination of Water and Wastewater, 4th ed(水和废水监测分析方法, 第4版). Beijing: China Environmental Sciences Press(北京: 中国环境科学出版社), 2002. 346. [5] Berkgau T V, Singer A. Appl. Clay Sci., 1996, 10: 369. [6] Murayama N, Yamamoto H, Shibata J. Int. J. Miner. Process, 2002, 64(1): 1. [7] Moulin P, Roques H. J. Colloid Interface Sci., 2003, 261: 115. [8] Chang M Y, Juang R S. J. Colloid Interface Sci., 2004, 278: 18. [9] Freundlich H M F. J. Phys. Chem., 1906, 57: 385. [10] Akhtar M, Bhanger M I, Iqba I S, et al. J. Hazard. Mater., 2006, B128(1-3): 44. [11] Dale O J, Barroeta Y, Cartledge F K, et al. Environ. Sci. Technol., 1991, 25: 1171. [12] Yim S D, Nam I S. J. Catal., 2004, 221: 601. [13] Lin Z Y, Zhou C H, Wu J M, et al. Spectrochim. Acta, Part A, 2005, 61: 1195. [14] Black L, Garbev K, Stemmermann P, et al. Phys. Chem. Minerals, 2004, 31: 337.
|
[1] |
ZHANG Hao-yu1, FU Biao1*, WANG Jiao1, MA Xiao-ling2, LUO Guang-qian1, YAO Hong1. Determination of Trace Rare Earth Elements in Coal Ash by Inductively Coupled Plasma Tandem Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2074-2081. |
[2] |
XU Qi-lei, GUO Lu-yu, DU Kang, SHAN Bao-ming, ZHANG Fang-kun*. A Hybrid Shrinkage Strategy Based on Variable Stable Weighted for Solution Concentration Measurement in Crystallization Via ATR-FTIR Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1413-1418. |
[3] |
KAN Yu-na1, LÜ Si-qi1, SHEN Zhe1, ZHANG Yi-meng1, WU Qin-xian1, PAN Ming-zhu1, 2*, ZHAI Sheng-cheng1, 2*. Study on Polyols Liquefaction Process of Chinese Sweet Gum (Liquidambar formosana) Fruit by FTIR Spectra With Principal Component Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1212-1217. |
[4] |
YAN Li-dong1, ZHU Ya-ming1*, CHENG Jun-xia1, GAO Li-juan1, BAI Yong-hui2, ZHAO Xue-fei1*. Study on the Correlation Between Pyrolysis Characteristics and Molecular Structure of Lignite Thermal Extract[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 962-968. |
[5] |
LI Zong-xiang1, 2, ZHANG Ming-qian1*, YANG Zhi-bin1, DING Cong1, LIU Yu1, HUANG Ge1. Application of FTIR and XRD in Coal Structural Analysis of Fault
Tectonic[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 657-664. |
[6] |
CHENG Xiao-xiao1, 2, LIU Jian-guo1, XU Liang1*, XU Han-yang1, JIN Ling1, SHEN Xian-chun1, SUN Yong-feng1. Quantitative Analysis and Source of Trans-Boundary Gas Pollution in Industrial Park[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3762-3769. |
[7] |
ZHANG Hao1, 2, HAN Wei-sheng1, CHENG Zheng-ming3, FAN Wei-wei1, LONG Hong-ming2, LIU Zi-min4, ZHANG Gui-wen5. Thermal Oxidative Aging Mechanism of Modified Steel Slag/Rubber Composites Based on SEM and FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3906-3912. |
[8] |
CHEN Jing-yi1, ZHU Nan2, ZAN Jia-nan3, XIAO Zi-kang1, ZHENG Jing1, LIU Chang1, SHEN Rui1, WANG Fang1, 3*, LIU Yun-fei3, JIANG Ling3. IR Characterizations of Ribavirin, Chloroquine Diphosphate and
Abidol Hydrochloride[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(07): 2047-2055. |
[9] |
MA Fang1, HUANG An-min2, ZHANG Qiu-hui1*. Discrimination of Four Black Heartwoods Using FTIR Spectroscopy and
Clustering Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1915-1921. |
[10] |
FAN Chun-hui1, 2, ZHENG Jin-huan3, LIU Hong-xin1. FTIR, 2D-IR and XPS Analyses on the Mechanism of Protoplast Derived From Calendula Officinalis in Response to Lead and Cadmium in Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1420-1425. |
[11] |
ZHANG Dian-kai1, LI Yan-hong1*, ZI Chang-yu1, ZHANG Yuan-qin1, YANG Rong1, TIAN Guo-cai2, ZHAO Wen-bo1. Molecular Structure and Molecular Simulation of Eshan Lignite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1293-1298. |
[12] |
WANG Fang-fang1, ZHANG Xiao-dong1, 2*, PING Xiao-duo1, ZHANG Shuo1, LIU Xiao1, 2. Effect of Acidification Pretreatment on the Composition and Structure of Soluble Organic Matter in Coking Coal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 896-903. |
[13] |
HU Chao-shuai1, XU Yun-liang1, CHU Hong-yu1, CHENG Jun-xia1, GAO Li-juan1, ZHU Ya-ming1, 2*, ZHAO Xue-fei1, 2*. FTIR Analysis of the Correlation Between the Pyrolysis Characteristics and Molecular Structure of Ultrasonic Extraction Derived From Mid-Temperature Pitch[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 889-895. |
[14] |
YANG Jiong1, 2, QIU Zhi-li1, 4*, SUN Bo3, GU Xian-zi5, ZHANG Yue-feng1, GAO Ming-kui3, BAI Dong-zhou1, CHEN Ming-jia1. Nondestructive Testing and Origin Traceability of Serpentine Jade From Dawenkou Culture Based on p-FTIR and p-XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 446-453. |
[15] |
HE Xiong-fei1, 2, HUANG Wei3, TANG Gang3, ZHANG Hao3*. Mechanism Investigation of Cement-Based Permeable Crystalline Waterproof Material Based on Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3909-3914. |
|
|
|
|