| 光谱学与光谱分析 |
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| Preparation and Luminescence of Single-Host White-Light-Emitting BaSrMg(PO4)2∶ Eu2+ Phosphor for Ultraviolet LEDs |
| PAN Zai-fa, LIU Shuang, ZHU Cheng-jing, XU Juan, LIU Wen-han, WANG Li-li* |
| College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, China |
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Abstract A single-host white-light-emitting phosphor BaSrMg(PO4)2∶Eu2+ was prepared by high temperature solid-state reaction method, and the luminescence characteristics and XRD pattern were investigated. The results show that BaSrMg(PO4)2 phase was obtained by sintering at 1 200 ℃ for 3 hours. BaSrMg(PO4)2∶Eu2+ phosphor exhibits two main emission bands peaking at 424 and 585 nm, respectively. The emission band peaking at 424 nm is attributed to the 4f 65d1→4f7 transition of Eu2+ substituting Sr2+, while the emission band peaking at 585 nm originates from the 4f 65d1→4f7 transition of Eu2+ replacing Ba2+ in host lattice. The excitation spectra of the two emission peaks are range from 250 to 400 nm and both peaking at 360 nm. The effect of the proportion of Ba and Sr, and the Eu2+ doping concentration on the emission intensity were discussed in detail. Different chromaticity coordinates were obtained for each phosphor, that is, the chromaticity coordinates of the designed phosphor is tunable for the white-emitting LED or for special purpose. Quantum efficiency was also examined for the phosphors with different Eu2+ doping concentration, and concentration quenching took place obviously when Eu2+ doping concentration was lager than 6% in mole ratio. The obtained phosphor BaSrMg(PO4)2∶Eu2+ can be excited by near ultraviolet radiation effectively and emit full color lighting, which is a promising single-host white-light-emitting phosphor for white LED.
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Received: 2010-12-08
Accepted: 2011-06-30
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Corresponding Authors:
WANG Li-li
E-mail: lili_wang@zjut.edu.cn
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