| 光谱学与光谱分析 |
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| Content Determination of Different Species of Pb, As, and Cd in the Municipal Sewage Sludge of Beijing with ICP-MS |
| CHEN Si-yang, WANG Juan, LI Li-na, HAN We-xuan*, JIANG Rong-feng |
| Department of Environmental Science and Engineering, China Agricultural University, Beijing 100193, China |
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Abstract Heavy metals in municipal sewage sludge can limit the utilization of sludge resources, due to their recalcitrant characteristics and harmful effects. Here, ICP-MS was used to determine the total and special content of Pb, As and Cd in the sewage sludge from G and Q Wastewater Treatment Plants, Beijing. The air-dried samples were dissolved in HNO3-HClO4 before the total content determination, or, sequentially extracted with BCR three-step method before special content determination for the heavy metals. The total contents are 19.60, 37.96 and 1.34 mg·kg-1 dry weight (DW) for Pb, As and Cd in the sewage sludge from G Plant, respectively; or, 19.58, 23.46 and 2.30 mg·kg-1 DW in that from Q Plant, respectively. Pb and Cd decreased dramatically in the total contents, compared to the corresponding data in the late 20th century. Both G and Q sludge samples show similar patterns in the species distribution for the three heavy metals: most of Pb and As are HAc soluble, and least are H2O2 oxidative; while Cd mainly exists in NH2OH-HCl reductive state, seldom in HAc soluble state. Species with high ecotoxicity account for a major part (over 70%) of the three species for all the metals on the whole. The authors’ results provide basic data for the ecological risk assessment and utilization of municipal sewage sludge from Beijing.
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Received: 2008-06-10
Accepted: 2008-09-15
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Corresponding Authors:
HAN We-xuan
E-mail: hanwenxuan@cau.edu.cn
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[1] State Environmental Protection Administration of P.R. China(国家环保总局). Environmental Protection(环境保护), 2000, (9): 8.
[2] Alvarez E A, Mochon M C, Sanchez J C J, et al. Chemosphere, 2002, 47: 765.
[3] TIAN Dong-mei, DENG Gui-chun, ZANG Shu-liang, et al(田冬梅，邓桂春，臧树良，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(12): 2330.
[4] RUI Yu-kui, GUO Jing, HUANG Kun-lun, et al(芮玉奎，郭晶，黄昆仑，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(4): 796.
[5] Rauret G. Talanta, 1998, 46(3): 449.
[6] LIU En-feng, SHEN Ji, ZHU Yu-xin(刘恩峰，沈吉，朱育新). Research of Environmental Sciences(环境科学研究), 2005, 18: 57.
[7] BAO Shi-dan, JIANG Rong-feng, YANG Chao-guang, et al(鲍士旦，江荣风，杨超光，等). Soil and Agricultural Chemistry Analysis(土壤农化分析). Beijing: China Agriculture Press(北京: 中国农业出版社)，2000.
[8] CHEN Tong-bin, HUANG Qi-fei, GAO Ding, et al(陈同斌, 黄启飞, 高定, 等). Acta Scientiae Circumstantiae(环境科学学报), 2003, 23(5): 561.
[9] HE Pei-song, ZHANG Ji-rong, CHEN Jiu, et al(何培松，张继荣，陈玖，等). Chinese Journal of Ecology(生态学杂志), 2004, 23(3): 131.
[10] CHEN Mao-lin, HU Xin, WANG Chao(陈茂林，胡忻，王超). Journal of Agro-Environment Science(农业环境科学学报), 2004, 23(6): 1102.
[11] HUANG Ya-xi, LI Ji, LI Guo-xue, et al(黄雅曦，李季，李国学，等). Chinese Journal of Eco-Agriculture(中国生态农业学报), 2006, 14(1): 156.
[12] LONG Qian, ZHANG Jing(隆茜，张经). Transaction of Oceanology and Limnology(海洋湖沼通报), 2002, 3(3): 25.
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