光谱学与光谱分析 |
|
|
|
|
|
Determination of Trace Elements in Electrical Absorption Prospecting Polyform Sample by Inductively Coupled Plasma Mass Spectrometry |
SHI Yi-hua, YANG Zhong-ping, HUANG Jian-hui, ZHOU Qi-ming, XIONG Chuan-xin |
Guilin Research Institute of Geology for Mineral Resources, Guilin 541004, China |
|
|
Abstract An ICP-MS method was established for the determination of sixteen trace elements, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Nb, Mo, Ag, Cd, Au, Tl, Pb and Bi in electrical absorption prospecting polyform. Three methods for polyform samples (ashing method, extraction by HNO3+H2O2 and digestion with aqua regia) were compared and the results showed that the second method is the best one. The best operational paramenters of X series ICP-MS were confirmed, the inner standard 103Rh and 185Re were selected for the determination of elements, and analysis of isotopes interference correction equations was established. Satisfactory linearity of working curves of the sixteen trace elements was obtained, giving all their correlation coefficients over 0.999 8. The determination limit of the analytes was in the range of 0.001-2.2 μg·g-1. The precision was 1.39%-4.84%, and the recoveries were between 94.86% and 105.2%. The method is sensitive, quick and simple and has been applied to the analysis of a great number of polyform samples.
|
Received: 2008-08-10
Accepted: 2008-11-20
|
|
Corresponding Authors:
SHI Yi-hua
E-mail: syhua2000@163.com
|
|
[1] ZHOU Qi-ming,ZHOU Li-hong, DONG Shu-zheng(周奇明, 周立宏, 董树政). Geophysical & Geochemical Exploration(物探与化探), 2004, 28(3): 199. [2] ZHOU Qi-ming, HUANG Shu-jun, YANG Fang-fang, et al(周奇明,黄书俊, 杨芳芳, 等). Mineral Resources and Geology(矿产与地质), 2005, 19(6): 660. [3] WANG Ying, XIN Shi-gang(王 莹, 辛士刚). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(2): 226. [4] SONG Xiao-nian, FENG Tian-pei(宋小年, 冯天培). Rock and Mineral Analysis(岩矿测试), 2006, 25(3): 282. [5] HOU Jing, GAO De-yu, LI Hong, et al(侯 静, 高德玉, 李 红, 等). Journal of Isotopes(同位素), 2004, 17(3): 135. [6] CHEN Lin, HE Yu-ping(陈 林, 贺与平). Metallurgical Analysis(冶金分析), 2007, 27(5): 59. [7] LI Chun-sheng, CHAI Zhi-fang, MAO Xue-ying, et al(李春生, 柴之芳, 毛雪瑛, 等). Chinese Journal of Analytical Chemistry(分析化学), 2001, 29(5):534. [8] ZHANG Lei, DING Xi-xiang, FANG Chao-meng(张 蕾, 丁锡祥, 方朝萌). Journal of Instrumental Analysis(分析测试学报), 2003, 22(2): 97. [9] LI Bing, YANG Hong-xia(李 冰, 杨红霞). The Principle and Application of Inductively Coupled Plasma Mass Spectrometry(电感耦合等离子体质谱原理与应用). Beijing: Geological Publishing House(北京: 地质出版社), 2005: 142. [10] HE Xiao-qing, LIU Xiang-sheng, CHEN Weng-xiang, et al(何小青, 刘湘生, 陈翁翔, 等). Metallurgical Analysis(冶金分析), 2004, 24(6): 26. [11] SONG Juan-e, LIANG Yue-qin, YU Shui(宋娟娥,梁月琴,于 水). Chinese Journal of Analytical Chemistry(分析化学), 2007, 35(3):423. [12] WANG Song-jun, CAO Lin, CHANG Ping, et al(王松君, 曹 林, 常 平, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2006, 26(7): 1330. [13] WANG Song-jun, CHANG Ping, WANG Pu-jun, et al(王松君, 常 平, 王璞珺, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(1): 151. [14] SUN De-zhong, HE Hong-liao(孙德忠, 何红蓼). Rock and Mineral Analysis(岩矿测试), 2007, 26(1): 21. [15] LI Man, LI Dong-lei, LIU Xi-xiang, et al(李 曼, 李东雷, 刘玺祥, 等). Journal of Chinese Mass Spectrometry(质谱学报), 2006, 27(2): 100. [16] ZHOU Qi-ming, ZHAO You-fang, HUANG Hua-luan, et al(周奇明, 赵友方, 黄华鸾, 等). Geophysical & Geochemical Exploration(物探与化探), 2001, 25(13): 169.
|
[1] |
HE Yan1, TAO Ran1, YANG Ming-xing1, 2*. The Spectral and Technology Studies of Faience Beads Unearthed in Hubei Province During Warring States Period[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3700-3709. |
[2] |
WANG Wei-en. Analysis of Trace Elements in Ophiocordyceps Sinensis From
Different Habitats[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3247-3251. |
[3] |
WANG Yan1, HUANG Yi1, 2*, YANG Fan1, 2*, WU Zhong-wei2, 3, GUAN Yao4, XUE Fei1. The Origin and Geochemical Characteristics of the Hydrothermal Sediments From the 49.2°E—50.5°E Hydrothermal Fields of the Southwest Indian Ocean Ultra-Slow Spreading Ridge[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2868-2875. |
[4] |
CHEN Chao-yang1, 2, LIU Cui-hong1, 2, LI Zhi-bin3, Andy Hsitien Shen1, 2*. Alexandrite Effect Origin of Gem Grade Diaspore[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2557-2562. |
[5] |
CHEN Di, SONG Chen, SONG Shan-shan, ZHANG Zhi-jie*, ZHANG Hai-yan. The Dating of 9 Batches of Authentic Os Draconis and the Correlation
Between the Age Range and the Ingredients[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1900-1904. |
[6] |
HE Yan1, SU Yue1, YANG Ming-xing1, 2*. Study on Spectroscopy and Locality Characteristics of the Nephrites in Yutian, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3851-3857. |
[7] |
CHEN Chao-yang1,HUANG Wei-zhi1,SHAO Tian1,LI Zhi-bin2,Andy Hsitien Shen1*. Characteristics of Visible Spectrum of Apatite With Alexandrite Effect[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1483-1486. |
[8] |
LIU Yan-de, GAO Xue, JIANG Xiao-gang, GAO Hai-gen, LIN Xiao-dong, ZHANG Yu, ZHENG Yi-lei. Detection of Anthracnose in Camellia Oleifera Based on Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2815-2820. |
[9] |
LU Xiao-ke1, LI Wei-dong1, LI Xin-wei2. Spectroscopic Analysis of Relics Unearthed from Xipo Site[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1186-1194. |
[10] |
LIANG Piao-piao1, ZHOU Shan-shan1, XING Yun-xin1, LIU Ying1, 2*. Quantification of Trace Elements in Hair Samples from 156 Women Living in the Low-Selenium Region of Inner Mongolia by ICP-AES and AFS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(07): 2217-2222. |
[11] |
HAO Xiao-jian*, TANG Hui-juan, HU Xiao-tao. Detection Sensitivity Improvement Study of LIBS by Combining Au-Nanoparticles and Magnetic Field[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1599-1603. |
[12] |
LIU Hong-wei, NIE Xi-du*. Analysis of Trace Elements in Wild Artemisia Selengensis Using Inductively Coupled Plasma Tandem Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(12): 3923-3928. |
[13] |
CAI Shi-shi1,ZHANG En1, 2*. Trace Elements and U-Pb Ages of Zircons from Myanmar Jadeite-Jade by LA-ICP-MS: Constraints for Its Genesis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1896-1903. |
[14] |
JIANG Bo1, 3, HUANG Jian-hua2*, LIU Wei2. Multi-Element Analysis of Wild Chinese Honeylocust Fruit by Inductively Coupled Plasma Tandem Mass Spectrometry (ICP-MS/MS)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3859-3864. |
[15] |
PENG Chuan-yi, ZHU Xiao-hui, XI Jun-jun, HOU Ru-yan, CAI Hui-mei*. Macro- and Micro-Elements in Tea (Camellia sinensis) Leaves from Anhui Province in China with ICP-MS Technique: Levels and Bioconcentration[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1980-1986. |
|
|
|
|