| 光谱学与光谱分析 |
|
|
|
|
|
| Study of Reference and Order Parameter of Raman Spectroscopy Research on Alkane Phase Transition |
| JIN Yuan-hao,CHEN Yi-ting,DU Wei-min* |
| School of Physics, Peking University, Beijing 100871, China |
|
|
|
|
Abstract Raman spectroscopy was used to investigate the order-disorder phase transition of n-eicosane for real-time cooling run. At the phase transition temperature, the integrated intensity of the 1 300 cm-1 spectra range changes greatly, which requires further consideration of 1 300 cm-1 as a reference in the research on polymer and biomembrane using Raman spectroscopy. The experiment support was provided for doubt about order parameter based on 1 130 cm-1 that it did not refer to generally accepted interpretation of an order parameter and it proved that the order definition could just be used as a relative measure method for disorder.
|
|
Received: 2008-08-10
Accepted: 2008-11-20
|
|
|
|
Corresponding Authors:
DU Wei-min
E-mail: wd00@pku.edu.cn
|
|
[1] Dirand M, Bouroukba M, Chevallier V, et al. J. Chem. Eng. Data, 2002, 47: 115.
[2] Yang Xiaozhen, Kang Shuhui, Yang Yuning, et al. Polymer, 2004, 45: 4241.
[3] ZU En-dong, CHEN Da-peng, ZHANG Peng-xiang(祖恩东，陈大鹏，张鹏翔). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(1): 64.
[4] YU Duo-wei, ZHU Jing-ning, KE Wei-zhong(余多慰，朱景宁，柯惟中). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(4): 734.
[5] Zheng M, Du W. Vib. Spectrosc., 2006, 40: 219.
[6] Manohar R, Gupta M, Shukla J. J. Phys. Chem. Solids, 2000, 61: 1465.
[7] Tarazona A, Koglin E, Meier R J, et al. Vib. Spectrosc., 1997, 14: 159.
[8] QIAO Er-wei, ZHENG Hai-fei(乔二伟，郑海飞). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(1): 78.
[9] Strobl G R, Hagedorn W. J. Polym. Sci., 1978, 16: 1181.
[10] LIAO Yu-bo, MENG Yao-yong, LEI Hao-dong, et al(廖昱博，孟耀勇，雷浩东, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(5): 940.
[11] LIU Hui-jun, XU Wei-jian, LIU Yao-chi, et al(刘慧君，徐伟箭，刘耀驰, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(8): 1596.
[12] Koglin K, Meier R J. Computational Theoredical Polymer Science, 1999, 9: 327.
[13] Garber B P, Peticolas W L. Biochim. Biophys. Acta, 1977, 465: 260.
[14] Meier R J, Csiszar A, Klumpp E. J. Phys. Chem. B, 2006, 110: 5842.
[15] CHEN Hui, JIANG Guo-chang, YOU Jing-lin, et al(陈 辉，蒋国昌，尤静林, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(12): 2464.
[16] Suranga P, Wickramarachchi R, Spells S, et al. J. Phys. Chem. B, 2007, 111: 1604. |
| [1] |
LI Jie, ZHOU Qu*, JIA Lu-fen, CUI Xiao-sen. Comparative Study on Detection Methods of Furfural in Transformer Oil Based on IR and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 125-133. |
| [2] |
WANG Fang-yuan1, 2, HAN Sen1, 2, YE Song1, 2, YIN Shan1, 2, LI Shu1, 2, WANG Xin-qiang1, 2*. A DFT Method to Study the Structure and Raman Spectra of Lignin
Monomer and Dimer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 76-81. |
| [3] |
XING Hai-bo1, ZHENG Bo-wen1, LI Xin-yue1, HUANG Bo-tao2, XIANG Xiao2, HU Xiao-jun1*. Colorimetric and SERS Dual-Channel Sensing Detection of Pyrene in
Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 95-102. |
| [4] |
WANG Xin-qiang1, 3, CHU Pei-zhu1, 3, XIONG Wei2, 4, YE Song1, 3, GAN Yong-ying1, 3, ZHANG Wen-tao1, 3, LI Shu1, 3, WANG Fang-yuan1, 3*. Study on Monomer Simulation of Cellulose Raman Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 164-168. |
| [5] |
WANG Lan-hua1, 2, CHEN Yi-lin1*, FU Xue-hai1, JIAN Kuo3, YANG Tian-yu1, 2, ZHANG Bo1, 4, HONG Yong1, WANG Wen-feng1. Comparative Study on Maceral Composition and Raman Spectroscopy of Jet From Fushun City, Liaoning Province and Jimsar County, Xinjiang Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 292-300. |
| [6] |
LI Wei1, TAN Feng2*, ZHANG Wei1, GAO Lu-si3, LI Jin-shan4. Application of Improved Random Frog Algorithm in Fast Identification of Soybean Varieties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3763-3769. |
| [7] |
WANG Zhi-qiang1, CHENG Yan-xin1, ZHANG Rui-ting1, MA Lin1, GAO Peng1, LIN Ke1, 2*. Rapid Detection and Analysis of Chinese Liquor Quality by Raman
Spectroscopy Combined With Fluorescence Background[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3770-3774. |
| [8] |
LIU Hao-dong1, 2, JIANG Xi-quan1, 2, NIU Hao1, 2, LIU Yu-bo1, LI Hui2, LIU Yuan2, Wei Zhang2, LI Lu-yan1, CHEN Ting1，ZHAO Yan-jie1*，NI Jia-sheng2*. Quantitative Analysis of Ethanol Based on Laser Raman Spectroscopy Normalization Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3820-3825. |
| [9] |
LU Wen-jing, FANG Ya-ping, LIN Tai-feng, WANG Hui-qin, ZHENG Da-wei, ZHANG Ping*. Rapid Identification of the Raman Phenotypes of Breast Cancer Cell
Derived Exosomes and the Relationship With Maternal Cells[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3840-3846. |
| [10] |
LI Qi-chen1, 2, LI Min-zan1, 2*, YANG Wei2, 3, SUN Hong2, 3, ZHANG Yao1, 3. Quantitative Analysis of Water-Soluble Phosphorous Based on Raman
Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3871-3876. |
| [11] |
GUO He-yuanxi1, LI Li-jun1*, FENG Jun1, 2*, LIN Xin1, LI Rui1. A SERS-Aptsensor for Detection of Chloramphenicol Based on DNA Hybridization Indicator and Silver Nanorod Array Chip[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3445-3451. |
| [12] |
ZHU Hua-dong1, 2, 3, ZHANG Si-qi1, 2, 3, TANG Chun-jie1, 2, 3. Research and Application of On-Line Analysis of CO2 and H2S in Natural Gas Feed Gas by Laser Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3551-3558. |
| [13] |
LIU Jia-ru1, SHEN Gui-yun2, HE Jian-bin2, GUO Hong1*. Research on Materials and Technology of Pingyuan Princess Tomb of Liao Dynasty[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3469-3474. |
| [14] |
LI Wen-wen1, 2, LONG Chang-jiang1, 2, 4*, LI Shan-jun1, 2, 3, 4, CHEN Hong1, 2, 4. Detection of Mixed Pesticide Residues of Prochloraz and Imazalil in
Citrus Epidermis by Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3052-3058. |
| [15] |
ZHAO Ling-yi1, 2, YANG Xi3, WEI Yi4, YANG Rui-qin1, 2*, ZHAO Qian4, ZHANG Hong-wen4, CAI Wei-ping4. SERS Detection and Efficient Identification of Heroin and Its Metabolites Based on Au/SiO2 Composite Nanosphere Array[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3150-3157. |
|
|
|
|
