| 光谱学与光谱分析 |
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| Spectroscopic Properties of Salicylaldehyde Anil Zinc and Its Thin Film |
| HAO Yu-ying1,GAO Zhi-xiang1,WANG Hua2,ZHOU He-feng2,MA Guo-zhang3,LIU Xu-guang2,XU Bing-she2 |
1. College of Science of Taiyuan University of Technology, Taiyuan 030024, China
2. College of Materials Science and Engineering of Taiyuan University of Technology，Taiyuan 030024, China
3. Institute of Applied Chemistry of Shanxi, Tayuan 030024, China |
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Abstract A new light emitting material, salicylaldehyde anil zinc (SAZ), was synthesized. It can form high quality nano-scale amorphous thin films on clean glass substrates by vacuum evaporation. Its structure, crystallization, thermal stability, and optical property were investigated by IR spectra, DTA-TG analysis, XRD spectra, UV-Vis spectra, and fluorescence spectra. Its energy band structure was confirmed by cyclic voltammogram and optical absorption band edge. Results show that the SAZ film is a thermally stable material, and can emit intense green fluorescence with a peak wavelength at 508 nm and a full width at halfmaximum of 90.2 nm under UV irradiation. Its HOMO energy level is about -5.659 eV，LUMO energy level is about -3.054 eV，optical gap band is about 2.604 eV. The fluorescence decay of stored films under ambient atmosphere is more rapid than that of 8-hydroxyquinoline aluminum films. However, the fluorescence decay of the films under UV irradiation is slower than that of 8-hydroxyquinoline aluminum films.
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Received: 2004-12-20
Accepted: 2005-04-18
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Corresponding Authors:
HAO Yu-ying
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| Cite this article: |
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HAO Yu-ying,GAO Zhi-xiang,WANG Hua, et al. Spectroscopic Properties of Salicylaldehyde Anil Zinc and Its Thin Film[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(03): 491-495.
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| URL: |
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https://www.gpxygpfx.com/EN/Y2006/V26/I03/491 |
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