光谱学与光谱分析 |
|
|
|
|
|
Vibration Spectra and Genetic Type of Cassiterites |
LIU Yan1,SHEN Zhang-wu2,DENG Jun1,JIANG Shao-qing1 |
1. State Key Laboratory of Geo-processes and Mineral Resources, China University of Geosciences, Beijing 100083, China 2. Chengdu Institute of Geology and Mineral Resources, Chengdu 610082, China |
|
|
Abstract Trace elements determination of cassiterites from Furong ore field indicates that there is a certain amount of Fe, Mn and Ti elements in cassiterite. The mean of unit-cell parameters for cassiterite is 7.165(nm3) by the method of XRD analysis and the unit-cell parameter which also indicates that the genetic type of the ore field belongs to cassiterite-sulfide type, is bigger than that of other genetic type. Four IR active vibration frequencies in cassiterite samples also suggest that the IR spectra of cassiterites from Furong ore field belongs to deformed spectra suggesting that the genetic type of cassiterite from Furong ore field is mainly of cassiteriate-sulfur type. The Raman frequency of A1g peak has typomorphic significance to study its genetic type. A1g is a characteristic peak of cassiterite and AO2 oxide of the same structure style. Impure elements of cassiterite remarkably affect its Raman frequency which will move to low frequency if the contents of Nb and Ta reach a certain amount. In Furong ore field, A1g frequency of casstiterite is about 632 cm-1 which is bigger than other cassiterites of various genetic types and the implication and character of Raman spectra are consistent with the cell parameters and IR analysis of these samples. Combined with the study of chemical composition and crystal structure, the IR spectra and Raman spectra can mean a lot for the analysis of genetic type of the cassiterite.
|
Received: 2007-06-09
Accepted: 2007-10-26
|
|
Corresponding Authors:
LIU Yan
E-mail: ly_0620@126.com
|
|
[1] LIU Yan, DENG Jun, WANG Li-hua(刘 琰, 邓 军, 王丽华). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2006,26(3):577. [2] WANG Li-hua, LIU Yan, ZHOU Pei-ling, et al(王丽华, 刘 琰, 周佩玲, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005,25(6):866. [3] SHI Jia-xin(施加辛). Geological Science and Technology Information of Yunnan Province(云南地质科技情报),1990,(1):1. [4] PENG Ming-sheng, HE Shuang-mei(彭明生,何双梅). Chinese Science Bulletin(科学通报),1985, 30(8):600. [5] Katiyar R S, Dawson P, Hargreave M M, et al. Journal of Physics C:Solid State Phys., 1971,4(5):2421. [6] Luxon J T, Summitt. Journal of Chem. Phys., 1969, 50(3):1366. [7] PENG Ming-sheng(彭明生). Spectroscopy and Spectral Analysis(光谱学与光谱分析),1986,6(3):10. [8] Scott J F. J. Chem. Phys., 1970, 53(2):852. [9] ZHANG Hui-fen, ZHU Li-jun(张惠芬,朱立军). Acta Mineralogica Sinica(矿物学报),1988,8(1):58. [10] Hofmeister A M, Horigan J, Campbell J M. America Minerologist, 1990, 75:1238. [11] DENG Jun, Huang Dinghua, WANG Qingfei, et al. Acta Geologica Sinica, 2004, 78(1):267. |
[1] |
LI Jie, ZHOU Qu*, JIA Lu-fen, CUI Xiao-sen. Comparative Study on Detection Methods of Furfural in Transformer Oil Based on IR and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 125-133. |
[2] |
CHENG Jia-wei1, 2,LIU Xin-xing1, 2*,ZHANG Juan1, 2. Application of Infrared Spectroscopy in Exploration of Mineral Deposits: A Review[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 15-21. |
[3] |
WANG Fang-yuan1, 2, HAN Sen1, 2, YE Song1, 2, YIN Shan1, 2, LI Shu1, 2, WANG Xin-qiang1, 2*. A DFT Method to Study the Structure and Raman Spectra of Lignin
Monomer and Dimer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 76-81. |
[4] |
GAO Feng1, 2, XING Ya-ge3, 4, LUO Hua-ping1, 2, ZHANG Yuan-hua3, 4, GUO Ling3, 4*. Nondestructive Identification of Apricot Varieties Based on Visible/Near Infrared Spectroscopy and Chemometrics Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 44-51. |
[5] |
XING Hai-bo1, ZHENG Bo-wen1, LI Xin-yue1, HUANG Bo-tao2, XIANG Xiao2, HU Xiao-jun1*. Colorimetric and SERS Dual-Channel Sensing Detection of Pyrene in
Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 95-102. |
[6] |
WANG Xin-qiang1, 3, CHU Pei-zhu1, 3, XIONG Wei2, 4, YE Song1, 3, GAN Yong-ying1, 3, ZHANG Wen-tao1, 3, LI Shu1, 3, WANG Fang-yuan1, 3*. Study on Monomer Simulation of Cellulose Raman Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 164-168. |
[7] |
LIU Jia, ZHENG Ya-long, WANG Cheng-bo, YIN Zuo-wei*, PAN Shao-kui. Spectra Characterization of Diaspore-Sapphire From Hotan, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 176-180. |
[8] |
BAO Hao1, 2,ZHANG Yan1, 2*. Research on Spectral Feature Band Selection Model Based on Improved Harris Hawk Optimization Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 148-157. |
[9] |
GUO Ya-fei1, CAO Qiang1, YE Lei-lei1, ZHANG Cheng-yuan1, KOU Ren-bo1, WANG Jun-mei1, GUO Mei1, 2*. Double Index Sequence Analysis of FTIR and Anti-Inflammatory Spectrum Effect Relationship of Rheum Tanguticum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 188-196. |
[10] |
WANG Lan-hua1, 2, CHEN Yi-lin1*, FU Xue-hai1, JIAN Kuo3, YANG Tian-yu1, 2, ZHANG Bo1, 4, HONG Yong1, WANG Wen-feng1. Comparative Study on Maceral Composition and Raman Spectroscopy of Jet From Fushun City, Liaoning Province and Jimsar County, Xinjiang Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 292-300. |
[11] |
YANG Cheng-en1, 2, LI Meng3, LU Qiu-yu2, WANG Jin-ling4, LI Yu-ting2*, SU Ling1*. Fast Prediction of Flavone and Polysaccharide Contents in
Aronia Melanocarpa by FTIR and ELM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 62-68. |
[12] |
LI Qi-chen1, 2, LI Min-zan1, 2*, YANG Wei2, 3, SUN Hong2, 3, ZHANG Yao1, 3. Quantitative Analysis of Water-Soluble Phosphorous Based on Raman
Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3871-3876. |
[13] |
SUN Wei-ji1, LIU Lang1, 2*, HOU Dong-zhuang3, QIU Hua-fu1, 2, TU Bing-bing4, XIN Jie1. Experimental Study on Physicochemical Properties and Hydration Activity of Modified Magnesium Slag[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3877-3884. |
[14] |
BAI Xue-bing1, 2, SONG Chang-ze1, ZHANG Qian-wei1, DAI Bin-xiu1, JIN Guo-jie1, 2, LIU Wen-zheng1, TAO Yong-sheng1, 2*. Rapid and Nndestructive Dagnosis Mthod for Posphate Dficiency in “Cabernet Sauvignon” Gape Laves by Vis/NIR Sectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3719-3725. |
[15] |
WANG Qi-biao1, HE Yu-kai1, LUO Yu-shi1, WANG Shu-jun1, XIE Bo2, DENG Chao2*, LIU Yong3, TUO Xian-guo3. Study on Analysis Method of Distiller's Grains Acidity Based on
Convolutional Neural Network and Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3726-3731. |
|
|
|
|