| 光谱学与光谱分析 |
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| Vibrational Spectra of Scheelite and Its Color Genesis |
| LIU Yan1,2,DENG Jun1,2,XING Yan-yan1,2,JIANG Shao-qing1,2 |
1. State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, China
2. Key Laboratory of Lithosphere Tectonics and Lithoprobing Technology of Ministry of Education, China University of Geosciences, Beijing 100083, China |
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Abstract In order to study the spectral characteristics and color-genetic mechanism of the scheelite with orange color found in scheelite-tin-beryl (W-Sn-Be) deposits in Xuebaoding, four groups of scheelite were investigated by means of EMPA, IR, LRM and XRD. The scheelite samples were tested by XRD and IR in order to reveal if there are other minerals intermingled with scheelite. Meanwhile, the structure, the structure water and the crystal water were studied through infrared spectra. The absorption bands and peaks of infrared and Raman spectra were assigned. Finally, it seems that there is no distinct color difference between scheelite from Xue baoding and those from other places. So, it is conceived that the color causing may correlate with the minor crystal structure, trace element or REE in the crystal.
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Received: 2006-05-10
Accepted: 2006-08-20
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Corresponding Authors:
LIU Yan
E-mail: ly_0620@126.com
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[1] Clarence Karr J R. Infrared and Raman Spectroscopy of Lunar and Terrestrial Minerals. Academic Press. Inc.(London)LTD, 1975. 209, 316.
[2] Gadsden J A. Infrared Spectra of Minerals and Related Inorganic Compounds. London: Butterworths, 1975. 152.
[3] PENG Wen-shi, LIU Gao-kui (彭文世, 刘高魁). The Compilation of Infrared Spectroscopy of Minerals(矿物红外光谱图集). Beijing: Science Press(北京：科学出版社), 1982. 192.
[4] WEN Lu, LIANG Wan-xue, ZHANG Zheng-gang, et al(闻 辂, 梁婉雪, 章正刚, 等). Infrared Spectroscopy of Minerals(矿物红外光谱学). Chongqing: Chongqing University Press(重庆: 重庆大学出版社), 1988. 72.
[5] Menéndez C J, Nolasco E J, Tavani E L, et al. Materials Chemistry and Physics, 1995, 40(4): 273.
[6] Hanuza J, Mczka M, Hermanowicz K, et al. Journal of Solid State Chemistry, 1999, 148(2): 468.
[7] Kaminskii A A, McCray C L, Lee H R, et al. Optics Communications,2000, 183(1-4): 277.
[8] Kloprogge T J, Frost R L. Spectrochimica Acta Part A,2000, 56: 501.
[9] Frost R L, Loc Duong, Matt Weier. Spectrochimica Acta Part A,2004, 60: 1853.
[10] LIU Yan, DENG Jun, CAI Ke-qin, et al(刘 琰, 邓 军, 蔡克勤, 等). Acta Petrologica et Mineralogica(岩石矿物学杂志),2005,24(2): 110.
[11] LIU Yan, DENG Jun, WANG Qing-fei, et al(刘 琰，邓 军，王庆飞，等). Geological Journal of China University(高校地质学报),2005，11(3): 439.
[12] LIU Yan, DENG Jun, WANG Li-hua(刘 琰，邓 军，王丽华). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2006，26(3): 577.
[13] WANG Li-hua, ZHOU Pei-ling, LIU Yan, et al(王丽华，周佩铃，刘 琰，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2005，25(6): 866.
[14] LI Yi-qun, LAN Xiao-zhong(李逸群, 颜晓锺). Bureau of Geology & Mineral Resources of Nanling(中国南岭及邻区钨矿床矿物学). Wuhan: China University of Goescirnces Press(武汉: 中国地质大学出版社), 1991. 95.
[15] Mineral Powder Diffraction File. Philadelphia: Joint Committee on Powder Diffraction Standards(Edition, 72-1624),2000.
[16] LUO Hong-yu, WANG Chun-sheng, LIAO Shang-yi(罗红宇，王春生，廖尚宜). Acta Petrologica et Mineralogica(岩石矿物学杂志),2004,23(2): 177.
[17] WU Rui-hua，WANG Chun-sheng，YUAN Xiao-jiang(吴瑞华，王春生，袁晓江). Gemstone Enhancement(天然宝石的改善及鉴定方法). Beijing: Geological Publishing House(北京: 地质出版社), 1994. 63.
[18] Deng Jun, Wang Qingfei, Wei Yanguang, et al. Journal of China University of Geosciences,2004, 15(1): 23.
[19] Deng Jun, Huang Dinghua, WANG Qingfei, et al. Acta Geologica Sinica(English Edition),2004, 78(1): 267. |
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