|
|
|
|
|
|
| Preparation of Four Phenoxy Phthalocyanine Zinc/ZnO Composites with in-situ Method by DBU Liquid Phase Catalyst and Its Photocatalytic Selectivity |
| LIU Jun-shao1, HUANG Lei2, XIE Wen-ju1, LIN Hao1, CHEN Yi-ping2, PAN Hai-bo2* |
1. College of Ecological and Resources Engineering, Fujian Provincial Key Laboratory of Eco-Industrial Green Technology, Wuyi University, Wuyishan 354300, China
2. College of Chemistry, Fujian Key Lab of Medical Instrument and Pharmaceutical Technology, Fuzhou University, Fuzhou 350116, China |
|
|
|
|
Abstract Hydrophobic four phenoxyphthalocyanine zinc (ZnTPPc) was prepared on the surface of hydrophilic ZnO nanomaterialson the indium tin oxide (ITO) conductive glasswith in-situ synthesis by using DBU as liquid phase Catalyst. ZnTPPc was cyclized with phenoxy phthalonitrile as a molecular fragment and unsaturated zinc ions with dumbbellshaped ZnO(ZnO ZDs) surface as a template. The structure of ZnTPPc molecule and the characteristics of photogenerated charge in ZnTPPc/ZnO interface were confirmed by a variety of characterization methods. The photocatalytic selectivity of ZnTPPc/ZnO for the degradation of hydrophobic phenol (PL) was quantitatively analyzed by using hydrophilic methylene blue (MB), hydrophobic (PL) and their mixtures. The results show that hydrophobic ZnTPPc is synthesized by in-situ method on ZnO surface, presenting a monomolecular layer. The hydrophobic PL was preferentially adsorbed by ZnTPPc, and the relative degradation efficiency of PL is 1.3 times as high as that of MB under visible light irradiation.
|
|
Received: 2017-04-28
Accepted: 2017-09-15
|
|
|
|
Corresponding Authors:
PAN Hai-bo
E-mail: hbpan@fzu.edu.cn
|
|
[1] Doudrick K，Yang T，Hristovski K，et al. Applied Catalysis B: Environmental，2013, 136： 40.
[2] Shen Xiantao，Zhu Lihua，Wang Nan，et al. Catalysis Today, 2014，225： 164.
[3] Ahn W Y，Sheeley S A，Tijana Rajh，et al. Applied Catalysis B: Environmental, 2007，74： 103.
[4] Hiroyuki Sakai，Yuji Kubota，Kosuke Yamaguchi，et al. Journal of Porous Materials，2013，20： 693.
[5] Tang Heqing，Zhu Lihua，Yu Chen，et al. Separation and Purification Technology，2012，95： 165.
[6] Araya Tirusew，Chen Chuncheng，Jia Manke，et al. Optical Materials，2017，64： 512.
[7] Bai Hongzhen，Zhou Jun，Zhang Hongjian，et al. Colloidsand Surfaces B: Biointerfaces，2017，150： 68.
[8] John Mack，Nagao Kobayashi. Chemical Review，2011，111： 281.
[9] Liu Lingyun，Zhang Wenhua，Guo Panpan，et al. Physical Chemistry Chemical Physics，2015，17(5)： 3463.
[10] Uihlein J，Peisert H，Adler H，et al. The Journal of Physical Chemistry C，2014，118(19)： 10106.
[11] Toader M，Shukrynau P，Knupfer M，et al. Langmuir，2012，28(37)： 13325.
[12] Shaymurat T，Qingxin T，Yanhong T，et al. Advanced Materials，2013，25(16)： 2269.
[13] Kian Mun Lee，Chin Wei Lai，Koh Sing Ngai，et al. Water Research，2016，88： 428.
[14] Zhan Hongbing，Wang Minquan，Chen Wenzhe. Materials Letters, 2002，55： 97.
[15] Sedat Yurdakal，Giovanni Palmisano，Vittorio Loddo，et al. Green Chemistry，2009，11： 510.
[16] Emeline A V，Zhang X，Murakami T，et al. Journal of Hazardous Materials，2012，211： 154. |
| [1] |
LIAO Yi-min1, YAN Yin-zhou1, WANG Qiang2*, YANG Li-xue3, PAN Yong-man1, XING Cheng1, JIANG Yi-jian1, 2. Laser-Induced Growth Device and Optical Properties of ZnO
Microcrystals[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3000-3005. |
| [2] |
YANG Chang-hu, YUAN Jian-hui. Effects of Thickness on Spectral Properties of Undoped ZnO Thin Films[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2835-2838. |
| [3] |
WANG Shi-xia, HU Tian-yi, YANG Meng. Study on Preparation of Ag-Doped ZnO Nanomaterials and Phase Transition at High Pressure Using Diamond Anvil Cell and Raman Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 484-488. |
| [4] |
QIAO Jin, XU Chang-shan*, ZHANG Hai-jiao, SHAO Hai-ling, ZHENG Bo-wen, HE Hui-min. Effects of ZnO NPs on the Photosynthetic Processes of Egeria najas[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(05): 1495-1502. |
| [5] |
MU Si-tu1,2, LIU Chun2, WANG Shu3, FAN Hui-ju3, HAN Bing-jun1, XIAO Kang1*. Spectroscopic Characteristics of Hydrophilic/Hydrophobic Fractions of Natural Organic Matters at Various Critical Retention Factors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(07): 2221-2226. |
| [6] |
YIN Wen-yi1, LIU Yu-zhu1,2*, ZHANG Qi-hang1, LI Bing-sheng3*, QIN Chao-chao4. Optical Excitation Characteristics of ZnO under the Radiation Fields[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1348-1352. |
| [7] |
HUANG Jie, HU Chen-li, MAO Jian-min, SHEN Wei-min, WANG Le, YU Jing. Synthesis and Fluorescence Property of CdS/ZnO Composite Structure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2788-2791. |
| [8] |
WU Cheng-ling1, GUO Jun-hong1, 2, YAO Heng-bin1, PAN Ling-nan1, WANG Fei1, WU Wen-qi1, JI Tong1, HU Fang-ren1, 2*. Study on the Photoluminescence Properties of ZnO Single Crystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1700-1702. |
| [9] |
ZHOU Jian-ping1*, LI Xin-yu1, ZHU Feng2, CHEN Xiao-hong2*, XU Zheng3 . Efficient Polymer Solar Cells Using ZnO Electron Transporting Layer with Layered Magentron Sputtered ZnO Film and/or Modified with Functionalized Carbon Nanopartilces[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(02): 517-521. |
| [10] |
CHEN Jing-han, YAO Wen-qing*, ZHU Yong-fa . Photoluminescence of Silicon Nitride-Based ZnO Thin Film Developed with RF Magnetron Sputtering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(02): 391-393. |
| [11] |
ZHU Lin1, CUI Hai-ning1*, B. Marí2, WANG Yi-xin1, WANG Rong1*, LI Xiao-xia1. Growth and Characteristics of ZnO Needles in the Surface of “Platanus Occidentalis” Made of Al2O3, Au and ZnO[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(10): 3394-3398. |
| [12] |
CHEN Xiang1, YANG Wen-yu1, ZHANG Hui-qin1, ZOU Ming-zhong1, ZHUANG Bin1, LIN Ying-bin1,2, HUANG Zhi-gao1,2*. The Optics and Magnetic Properties of Cr Doped ZnO Thin Films[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(05): 1328-1333. |
| [13] |
FENG Shi-hong1, JIA Tai-xuan2, ZHANG Zhen-bin1, GAO Jie1, LIN Yan1, LIU Zi-li3 . Preparation of δ-Valerolactone and Its Spectral Analysis [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(10): 2810-2813. |
| [14] |
CHEN Fang1, FANG Dan1*, WANG Shuang-peng2*, FANG Xuan1, TANG Ji-long1, ZHAO Hai-feng2, FANG Fang1, 3, CHU Xue-ying1, LI Jin-hua1, WANG Fei1, WANG Xiao-hua1, LIU Guo-jun1，MA Xiao-hui1, WEI Zhi-peng1 . Optical Properties Investigation of p-Type ZnO Film Based on Doping by Diffusion [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(07): 1787-1790. |
| [15] |
JIA Hui-min1, TANG Ji-long1*, FANG Xuan1*, WANG Shuang-peng2, ZHAO Hai-feng2, FANG Dan1, WANG Xiao-hua1, FANG Fang1, LI Jin-hua1, CHU Xue-ying1, WEI Zhi-peng1, MA Xiao-hui1, XU Li1 . Preparation of MgxZn1-xO Nanofibers Using PVP Nanofibers as Templates by Atom Layer Deposition and Their Optical Properties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(12): 3197-3200. |
|
|
|
|
