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| Experimental Investigations on the Hydrogen Isotope Fractionation between Benzene and Heavy Water with in-situ Raman Spectrograph |
| WANG Shi-xia1, ZHAO Hao-chen1, WU Jia2, ZHENG Hai-fei3 |
1. School of Science，University of Shanghai for Science and Technology, Shanghai 200093, China
2. State Key Laboratory of Petroleum Resources and Prospecting-College of Geoscience, China University of Petroleum, Beijing 102249, China
3. Key Laboratory of Orogenic Belts and Crustal Evolution under Ministry of Education, Peking University, Beijing 100871, China
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Abstract Hydrothermal diamond-anvil cell and Raman spectrograph were used to measure the hydrogen isotope fractionation factor between benzene and heavy water at high P-T condition. The isotope fractionation factor is determined when the isotope fractionation between phases reached equilibrium. This research shows that hydrogen isotope fractionated easily between benezene and water, different from hydrogen isotope fractionation betweenwater and n-alkanes or cycloalkanes. In this study, benzene was dispersed to many small particles, indicating the increasing contacting area to heavy water when temperature reached 300 ℃. Sufficient heating time enabled that stable isotope phases to reach the fractionation equilibrium. The ratio of Raman peak intensities and ratio of corresponding amount of substances is linearly correlated. The calculated hydrogen isotope fractionation factors between benzene and heavy water is 0.909 9 at 300 ℃. Taken together, it is feasible to determine the stable isotope fractionation factor between liquid phases with Hydrothermal Diamond-Anvil Cell combining with Raman spectroscopy.
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Received: 2016-10-16
Accepted: 2017-03-26
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[1] LIU Jin-ping, GENG An-song, XIONG Yong-qiang, et al(刘金萍，耿安松，熊永强，等). Xinjiang Petroleum Geology(新疆石油地质)，2007，28：104.
[2] WANG Bao-zhong, ZHOU Shi-xin, OU Wen-jia, et al(王保忠，周世新，欧文佳，等). Journal of Lanzhou University·Natural Science(兰州大学学报·自然科学版)，2014，50：809.
[3] SUN Jing(孙 晶). Petroleum Geology and Oilfield Development in Daqing(大庆石油地质与开发)，2014，33：39.
[4] HU Jian-fang, PENG Ping-an(胡建芳，彭平安). Acta Sedimentologica Sinica(沉积学报)，2017，35：968.
[5] Luo P, Peng P A, Gleixner G, et al. Earth and Planetary Science Letters, 2011, 201: 285.
[6] Garcin Y, Schwab V F, Gleixner G, et al. Geochimica et Cosmochimica Acta, 2012, 79: 106.
[7] Rampen S W, Willmott V, Kim J H, et al. Organic Geochemistry, 2014, 76: 39.
[8] Rao Z G, Jia G D, Qiang M R, et al. Organic Geochemistry, 2014, 76: 104.
[9] Ho S L, Laepple T. Nature Geoscience, 2016, 9: 606.
[10] Bar M W D, Dorhout D J C, Hopmans E C, et al. Organic Geochemistry, 2016, 101: 184.
[11] Rao Z G, Jia G D, Liu Y X, et al. Earth and Planetary Science Letters, 2016, 446: 68.
[12] Mao H K, Bell P M. Carnegie Institute Washington Yearbook, 1978, 77: 904.
[13] XU Pei-cang, LI Ru-bi(徐培仓，李如壁). Raman Spectroscopy in Geosciences(地学中的拉曼光谱). Xi’an: Shanxi Science and Techology Press(西安：陕西科学技术出版社), 1996.
[14] WANG Shi-xia, ZHENG Hai-fei(王世霞，郑海飞). Acta Mineralogica Sinca(矿物学报), 2011, 31: 230.
[15] LI Li-wu, DU Li(李立武, 杜 丽). Journal of Chinese Mass Spectrometry Society(质谱学报), 2004, 25: 249. |
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