| 光谱学与光谱分析 |
|
|
|
|
|
| Native Defect Luminescence of Zinc Oxide Films and Its Potential Application as White Light Sources |
| LIU Shi1, CHEN Yong-jian1, CUI Hai-ning1*, SUN Sheng-nan1, WANG Zi-han1, WANG Hai-shui2 |
1. Department of Optical Information Science and Technology, College of Physics，College of Zhaoqing (526061), State Key Laboratory of Superhard Materials, Jilin University，Changchun 130021, China
2. School of Chemistry and Chemical Engineering, South China University of Technology，Guangzhou 510641, China |
|
|
|
|
Abstract ZnO light-emitting diodes (LEDs) have an enormous potential in lighting applications. The major issue to be resolved is the generating and control of light emissions. This issue arises from the variation and combination in LED wavelength. We found that defect luminescence of ZnO has a varied wide range of wavelength, which suits to an application of LED for white-light generation. We have shown both experimentally and theoretically that defect emission can be used in ZnO systems. This type of defect has the advantage of not requiring extensive and costly factory systems comparing with traditional doped materials and others. We not only propose potential application of native defect luminescence of Zinc Oxide film for white LEDs-flat light sources, but also have some methods to control defect origins, a certain center position and broad range of the emission band of ZnO film in the initial stage. According to different preparing method and certain experiment conditions, variant white such as whitish and bluish-white etc., primary and important colors- blue bands (455, 458 nm), green bands (517, 548 nm), red bands (613, 569 nm) are obtained respectively. This proved that it is a better road to one white light LED with one kind of material -ZnO.
|
|
Received: 2015-09-01
Accepted: 2015-12-30
|
|
|
|
Corresponding Authors:
CUI Hai-ning
E-mail: cuihaining2009@126.com
|
|
[1] Akcelrud L. Prog. Polym. Sci. 2003，28：875.
[2] Shufen C, Lingling D, Jun X, et al. Adv. Mater., 2010, 22: 5227.
[3] Gather M, K?hnen A, Meerholz K. Adv. Mater.，2011，23：233.
[4] Ma J, Piao X, Liu J, et al. Organic Electronics，2011，12：923.
[5] Panin G N, Kang T W, Lee H. Physica E，2004，21：1074.
[6] Ahn T K, Han S H, Lee H. Mol. Cryst. Liq. Cryst.，2002，377：391.
[7] Ahn T K, Choi B S, Ahn S H, et al. Synthetic Metals，2011，117：219.
[8] Kim D Y, Lee S K, Kim J L, et al. Synthetic Metals，2001，121：1707.
[9] Ahn T K, Lee H, Han S H. Appl. Phys. Lett.，2002，80：392.
[10] Micheletto R, Yoshimatsu N, Yokokawa M, et al. Optics Communications，2001，196：47.
[11] Cui H N, Teixeira V, Zhang J, et al. Thin Solid Films，2006，515：301.
[12] Cui H N, Lee H. Mol. Cryst. Liq. Cryst.，2000，349：475.
[13] Cui H N, Lee H. Synthetic. Metals，2001，117(1-3)：255.
[14] Schubert E Fred. Light-Emitting Diodes. Cambridge University，2006. 422.
[15] Steranka F. Opto & Laser Europe，2003.
[16] Cook M. Review，2006，29(5)：22.
[17] Stath N, et.al. Materials Science and Engineering，2001，B80(1-3)：224.
[18] Akasaki I. J. of Cryst. Growth，2002，237-239(4)：905.
[19] María B, Tortosa M, Mollar M, et al. Optical Materials，2010，32：1423.
[20] Cui H N, Teixeira V, Meng L J, et al. Thin Solid Films，2008，516：1484.
[21] Cui H N. Optical Multilayered Coatings for Application of Smart Windows, Subtitle-Preparation and Characterization. VDM Publishing House Ltd. Germany，2009.
[22] Teixeira V, Cui H N, Meng L J, et al. Thin Solid Films，2002，420-421：70.
[23] Cui H N, Xi S Q. Thin Solid Films，1996，288：325.
[24] Cui H N, Jia S, Meng L J, et al. Mikrochimica Acta，2004，145：19.
[25] María B, Tortosa M, Mollar M, et al. Optical Materials，2010，32：1423.
[26] Teixeira V, Cui H N, Meng L J, et al. Thin Solid Films，2002，420-421：70.
[27] Cembrero J, Elmanouni A, Hartiti B, et al. Thin Solid Films，2004，451-452：198.
[28] Lee H S, Lee N, Lee H W, et al. Mol. Cryst. Liq. Cryst., 2002，377：25.
[29] Manjón F J, Hernández-Fenollosa M A, Marí B, et al. The European Physical Journal B，2004，40：453.
[30] Whitaker T. Innovations Push White LEDs Towards New Applications. Compound Semiconductor，2003.
[31] Detchprohm T, Hiramatsu K, Amano H, et al. Appl. Phys. Lett.，1992，61：2688.
[32] Xiao R F, Sun X W, Liao H B, et al. J. Appl. Phys.，1996，80：4226.
[33] Ryu Y R, Lee T S, Lubguban J A, et al. Appl. Phys. Lett.，2006，88：241108.
[34] Yan Y F, Li J B, Wei S H, et al. Phys. Rev. Lett.，2007，98：135506.
[35] Hernández M A, Damonte L C, Marí B. Superlattices and Microstructures，2005，38：336.
[36] Damonte L C, Hernández M A, Marí B. Journal of Alloys and Compounds, 2007，434-435：813.
[37] Bradley D C. Chem. Brit.，1991，27：719.
[38] Ryu Y R, Lee T S, White H W. Appl. Phys. Lett.，2003，83：87.
[39] Wang X, Summers C J, Wang Z L. Adv. Mater.，2004，16：1215.
[40] Dai J, Su H, Wang L, et al. J. Cryst. Growth，2006，290：426.
[41] He H P, Ye Z Z, Zhuge F, et al. Solid State Commun.，2006，138：542.
[42] Liu X, Wu X, Cao H, et al. J. Appl. Phys.，2004，95：3141.
[43] Choi C H, Kim S H. J. Cryst. Growth，2005，283：170.
[44] Kang H S, Kang J S, Kim J W, et al. J. Appl. Phys.，2003，95：1246.
[45] Look D C, Falow G C, Reunchan P, et al. Phys. Rev. Lett.，2005，95：225502.
[46] Janotti A, Van de Walle C G. Appl. Phys. Lett.，2005，87：122102.
[47] Bylander F G. J. Appl. Phys.，1978，49：1188.
[48] Lin B, Fu Z, Jia Y. Appl. Phys. Lett.，2001，79943.
[49] Vlasenko L S, Watkins G D. Phys. Rev. B，2005，71：125210.
[50] Look D C, Farlow G C, Reunchan P, et al. Phys. Rev. Lett.，2005，95：225502.
[51] van Dijken A, Meulenkamp E A, Vanmaekelbergh D, et al. J. Lumin.，2000，90：123.
[52] Chen J, Feng Z, Ying P, et al. J. Phys. Chem. B, 2004, 108: 12669.
[53] Vanheusden K, Warren W L, Seager C H, et al. J. Appl. Phys.，1996，79：7983.
[54] Liu M, Kitai A H, Mascher P. J. Lumin.，1992，54：35.
[55] zgür ü, Alivov Y, Liu C, et al. J. Appl. Phys.，2005，98：041301.
[56] Auret F D, Goodman S A, Hayes M, et al. Appl. Phys. Lett.，2001，79：3074.
[57] Hernández M A, Damonte L C, Marí B. Superlattices and Microstructures，2005，38：336.
[58] Damonte L C, Hernández M A, Marí B. Journal of Alloys and Compounds, 2007, 434-435: 813.
[59] Vlasenko L S, Watkins G D. Phys. Rev. B，2005，71：125210.
[60] Choopan S, Vispute R D, Noch W, et al. Appl. Phys. Lett.，1995，75：3947. |
| [1] |
LI Zhao, WANG Ya-nan, XU Yi-pu, CAO Jing, WANG Yong-feng, WU Kun-yao, DENG Lu. Synthesis and Photoluminescence of Blue-Emitting Phosphor
YVO4∶Tm3+ for White Light Emitting Diodes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 623-628. |
| [2] |
LI Zhao, WU Kun-yao, WANG Ya-nan, CAO Jing, WANG Yong-feng, LU Yuan-yuan. Synthesis and Luminescence Properties of Yellow-Emitting Phosphor Y2.93Al5O12∶0.07Ce3+ Under Blue Light Excitation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 381-385. |
| [3] |
CAO Li, ZHENG Zi-shan, ZHANG Hong*, LIANG Pei, ZHU Qiang-qiang, WANG Le*. Phosphor-Converted White Light-Emitting Diodes for Plant Lighting[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(04): 1060-1065. |
| [4] |
LI Zhao, WANG Yong-feng, CAO Jing, WU Kun-yao, WANG Ya-nan. Preparation and Performance of Red Phosphor ScVO4∶Eu3+ for White LEDs[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(10): 3077-3080. |
| [5] |
ZHANG Hong1, WANG Le1*, LUO Dong1, ZHENG Zi-shan1, LI Yang-hui1, 2, PAN Gui-ming1. Structural and Luminescence Properties of Eu2+ Doped CaAlSiN3 Silicon Nitride Red Emitting Phosphor[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 59-64. |
| [6] |
ZHUO Ning-ze1, 2, 3, ZHANG Na1, 2, CHEN Yong-hao4, JIANG Peng4, CHENG Shao-wen5, ZHU Yue-hua1, 2, WANG Hai-bo2*. Preparation and Spectral Properties of White Light Emitting LED Based on Layered Remote Phosphor Film[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2337-2343. |
| [7] |
LI Bo-chao1, 2, ZHUO Ning-ze2*, LI Wen-quan2,3, HE Qing-yang1, 2, HUANG Ru-xi2, LIU Guang-xi2, YE En-gan1, 2, WANG Hai-bo2*. The Preparation and Properties Study of High CRI White LED Based on Remote Phosphor Technology [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(03): 728-732. |
| [8] |
FENG Ying, TONG Yi-ping*, LI Wen-wei . A Study on Synthesis of CaAl12O19∶xMn4+ Red Phosphor with Combustion Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(10): 3211-3214. |
| [9] |
CAO Jin2, ZHOU Jie1, XIE Jing-wei1, CHEN An-ping1, ZHANG Xue1, YIN Lu-qiao2, ZHANG Jian-hua2 . Research on the Highly Stable White LED with CdSe/ZnS Quantum Dot as Light Conversion Layer [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(02): 349-354. |
| [10] |
FU Yue, CONG Yan*, YANG Yang, XIAO Yu, HE Yang-yang, WANG Li-mei, DONG Bin* . Spectroscopic Properties of CeO2∶Eu3+ for White LEDs [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(11): 3032-3035. |
| [11] |
YU Chun-yu1, JIN Peng2, ZHOU Qi-feng3 . Optimizing Color Rendering for Mixed-Color White Light LED [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(05): 1316-1319. |
| [12] |
KUANG Qing-liang, LI Yong-jin*, QIU Jian-bei, YIN Zhao-yi, YANG Zheng-wen, SONG Zhi-guo*, WAN Rong-hua, LIU Qun, ZHOU Yu-ting. Synthesis and Luminescence Properties of BiOCl∶Dy3+ Phosphors for NUV Excited White Light-Emitting Diodes [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(04): 889-893. |
| [13] |
XIAO Yao1, FAN Guang-han1, 2, PI Hui1, XU Yi-qin2, CHEN Zhi-wu1, HE Long-fei2, YU Xiao-peng1, ZHANG Li1, ZHENG Shu-wen1*, ZHANG Tao1*. Preparation and Luminescent Properties of Light Scattering Fluorescent Resin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(12): 3178-3182. |
| [14] |
LI Zhao1, ZHAO Xi-cheng2, JIANG Yuan-ru3 . Preparation and Photoluminescent Property of Sphere Y2.96Al5O12∶ 0.04Ce3+ Phosphor for White Light-Emitting Diodes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(11): 2918-2922. |
| [15] |
XU Guo-tang, LIANG Pei*, WANG Le*, DONG Qian-min, LIU Yang, LI Xiao-yan . Progress in the Research on Silicon-Nitrogen Based Phosphor for White LED [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(11): 2907-2912. |
|
|
|
|
