光谱学与光谱分析 |
|
|
|
|
|
Determination of Bi in Soils and Sediments by Atomic Fluorescence Spectrometry |
LIN Hai-lan1, LI Zhi-huang2, ZHU Ri-long1, 3, SONG Bing-bing1, LIU Pei1*, BI Jun-ping1,LUO Yue-ping1 |
1. Hunan Province Environmental Monitoring Cerner, State Environmental Protection Key Laboratory of Monitoring for Heavy Metal Pollutants, Changsha 410019, China2. GRG Metrology & Test Hunan Co., Ltd., Changsha 410003, China3. Beijing Normal University, Beijing 100875, China |
|
|
Abstract A method for determination of the contents of Bi in soils and sediments by atomic fluorescence spectrophotometry (AFS) was established by using aqua regia as the dissolved medium. In this paper, the instrument parameters, load flow and reducing agent concentration were optimized. Compared with microwave digestion and electric heating plate digestion, water bath digestion demonstrated the better digestion efficiency and was most commonly used. Under the optimal experimental conditions, the detection limit (LOD) was 0.01 mg·kg-1 (sample quantity 0.500 0 g, sample volume 50 mL), and the limit of quantitation (LOQ) was 0.04 mg·kg-1. The results were in good agreement with the centified value, and the relative error was -4.7%~-2.0%. For determination of soil and sediment actual samples, the relative standard deviation (RSD) were 2.5%~3.4% and 3.1%~3.4%, respectively, and the recoveries of the method respectively ranged from 97.6%~102% and 99.5%~104%.
|
Received: 2015-03-03
Accepted: 2015-07-20
|
|
Corresponding Authors:
LIU Pei
E-mail: lewpeii@163.com
|
|
[1] SUN Jun(孙 骏). Agro-Environment and Development (农业环境与发展),2012,29(1):86. [2] Gücer S, Demir M. Analytica Chimica Acta, 1987, 196: 277. [3] ZHANG Qi-lei(张奇磊). Environmental Science Survey (环境科学导刊),2014,1:94. [4] Ryszard Dobrowolski, Joanna Dobrzyńska, Barbara Gawrońska. Environ Monit Assess, 2015, 187: 4125. [5] Ni Zheming, Le Xiaochun, Han Hengbin. Analytica Chimica Acta, 1986, 186: 147. [6] Velitchkova N, Pentcheva E N, Daskalova N. Spectrochimica Acta Part B: Atomic Spectroscopy, 2004, 59(6): 871. [7] XU Peng, SUN Ya-li(徐 鹏,孙亚莉). Chinese Joumal of Analytical Chemistry(分析化学),2010,38(4):581. [8] ZHOU Li-ping, LI Zhong-xi(周丽萍,李中玺). Chinese Journal of Analysis Laboratory(分析试验室),2005,24(9):20. [9] XUE Guang-pu, CHEN Su-lan, XU Jian-hua, et al(薛光璞,陈素兰,许建华,等). Sichuan Environment(四川环境),2009,28(1):39. [10] Zhang Yanlin, Samuel B. Adeloju. Talanta, 2008, 76(4): 724. [11] Carmen Moscoso-Pérez, Jorge Moreda-Pieiro, Purificación López-Mahia, et al. Talanta, 2003, 621(5): 633. [12] HE Pan-hong, WU Ling-jun, YANG Zhen, et al(贺攀红,吴领军,杨 珍,等). Rock and Mineral Analysis(岩矿测试),2013,32(2):240. [13] LIU Xian-guo, FANG Jin-dong, HU Sheng-hong, et al(刘先国,方金东,胡圣虹,等). Chinese Journal of Analysis Laboratory(分析试验室),2002,21(6):14. [14] Schramel P, Xu Liqiang. Fresenius’ Journal of Analytical Chemistry, 340(1): 41. [15] Xing Zhi, Wang Juan, Zhang Sichun, et al. Talanta, 2009, 80(1): 139. [16] WANG Ke-chu, XIAO Zhi-de(王克初,肖志德). Physical Testing and Chemical Analysis Part B: Chemical Analysis(理化检验-化学分册),2000,36(2):89.
|
[1] |
JING Jiang1, GU Xiao-yu1*, ZHANG Sheng1 , LI Hong-fei1, SUN Jun1, CHEN Yu2. Preparation and Study of High Reflective Near Infrared Heat-Insulation Film[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1708-1711. |
[2] |
LU Jian-ping, QIN Meng-lin, BU Jing-long, DENG Yang-hui,TONG Zhang-fa. Determination of Mercury in Rice with Dispersive Liquid-Liquid Microextraction and Atomic Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(11): 3606-3609. |
[3] |
CUI Yu-min, LI Hui-quan, MIAO Hui, TAO Dong-liang, FAN Su-hua . The Latest Research Progress of Coupling between BiOX and Semiconductor Photocatalyst[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(08): 2579-2584. |
[4] |
LIN Hai-lan1,2, GAN Jie1,2, YU Lei1,2, ZHU Ri-long1,2,3, TIAN Yun1,2, LUO Yue-ping1,2* . Determination of Beryllium in Soil and Sediment by Graphite Furnace Atomic Absorption with a Microwave-Acid Digestion Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(11): 3275-3280. |
[5] |
CHEN Hai-jie, YU Zhao-shui, BAI Jin-feng, LI Qing-xia, LIU Ya-xuan, BO Wei, ZHANG Qin* . Determination of Trace Germanium in Plant Samples by Dry Ashing-Atomic Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(04): 1048-1051. |
[6] |
ZHAI Qiu-ge, GUO Peng, ZHOU Lin, LIU Yan-ming* . Sensitive Determination of Bi3+ by Spectrofluorimetry Based on Graphene Oxide-Methylene Blue System [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(08): 2152-2156. |
[7] |
YUAN Chun-gang, JIANG Wan-ping, ZHU Tao, YUAN Bo, SONG Xiao-wei . Analysis of Arsenic Speciation in Food Condiments Based on the Online Trapping/Separation Coupling System [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(08): 2259-2263. |
[8] |
CHENG Jun-wen1,3, CHEN Fei-fei1,3, DAI Shi-xun1,3*, XU Yin-sheng2,3, TAN Rui-qin1,3 . Study on Spectroscopy and Third-Order Optical Nonlinear Characteristics of Ag-Nanoparticles Embedded Bismuthate Glass [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(06): 1642-1646. |
[9] |
PENG Xiao-li1, XU Fang1*, BIAN Jing1, ZHANG Wen-zhong1, WU Yi2 . Fe(Ⅲ) Modified Sodium Alginate Beads Based Micro-Extraction in Combination with Hydride Generation-Atomic Fluorescence Spectrometry (HG-AFS) for Speciation Analysis of Inorganic As(Ⅲ) and As(Ⅴ) in Water Samples[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(06): 1689-1692. |
[10] |
YANG Zhao-ning, LI Jun, QIU Jian-bei, YANG Zheng-wen*, SONG Zhi-guo, WANG Rong-fei, YU Xue, YANG Yong, ZHOU Da-cheng . Synthesis and Photoluminescence Properties of Eu3+, Bi3+ Codoped BaZrO3 Phosphors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(01): 19-22. |
[11] |
LU Jian-ping1, GENG Guo-xing1, LU Zhi-yong1, TANG Yan-kui2 . Indirect Determination of Iodine with Methyl Isobutyl Ketone (MIBK) Extraction by Atomic Fluorescence Spectrometer [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(05): 1394-1396. |
[12] |
WANG Sheng-li1, WANG Xue-jin1*, WANG Wen-zhong2, LIANG Chun-jun3, WANG Zhi2,QI Zheng1 . Comparative Study on Thin Films of Cadmium Sulfide Prepared by Chemical Bath Deposition and Radio Frequency Magnetron Sputtering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(04): 1094-1097. |
[13] |
WANG Bin1,4, ZHENG Cheng-bin2, WANG Jun-wei3, FENG Li1, LI Shao-bo1, DAN De-zhong1, LENG Geng1* . Determination of Trace Amounts of Mercury in Sediments by Sequential Injection Cold Vapor Atomic Fluorescence Spectrometry Coupled with Microwave-Assisted Digestion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(04): 1106-1110. |
[14] |
JI Zi-fang1, YOU Jing-lin1, 2*, SIMON Patrick2, WANG Yuan-yuan1, HOU Min1, WANG Li-hong1, ZHANG Guo-chun3, WAN Song-ming4, FU Pei-zhen3, WU Yi-cheng3, YIN Shao-tang4 . Microstructure Study on Bismuth Triborate Crystal and Its Melt at High Temperature by Raman Spectroscopy [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(01): 127-131. |
[15] |
XIN Hua1, XU Fang2, ZHOU Wei2 . Investigation on Urinary Arsenic Concentration of City Children in China [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(12): 3392-3394. |
|
|
|
|