| 光谱学与光谱分析 |
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| Study of the Detection of Histidine Based on “On-Off” Fluorescence Probe of Carbon Dots |
| TAO Hui-lin, LIAO Xiu-fen, SUN Chao, ZHOU Su-lian, ZHONG Fu-xin, YI Zhong-sheng, LU Yan-qun |
| College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China |
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Abstract An new type of switch “On-Off” fluorescence probe was constructed based on fluorescence carbon dots as a novel strategy to analyze trace histidine(His) which was proposed for the first time. In water solution with pH 7.6, the fluorescence of CDs was quenched with Ru3+ due to the formation of ground state compound through electrostatic attraction, and the system was thus “turned-off”. The fluorescence intensity of CDs was “turned-on” due to the competition between His and Ru towards the surface of CDs. The effect of critical parameters including pH, buffer solutions, reaction temperature and time needed to grow the fluorescence intensity of CDs was studied. Results show thatin water solution with pH 7.6, and when the temperature was between 20~25 ℃, the fluorescence intensity of the released CDs displayed a linear relationship in the range of (6.5~219.3)×10-6 mol·L-1 of captopril. Lower limit of detection for His, at the signal-to-noise ratio of 3/(3δ), was 2.15×10-6 mol·L-1. The methodology was successfully applied for the determination of His in Compound Amino Acid Injections, with the RSD≤2.07%, and the recovery rate was between 95.7%～102.4%. The result of the experiment was satisfactory. On the one hand, the excellent optical character CDs was acted as “On-Off” fluorescence probe, which could be extent the application of CDs, on the other hand, the excellent performance of the proposed fluorescence probe shows that this method possesses the potential for practical application.
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Received: 2014-08-12
Accepted: 2015-01-05
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Corresponding Authors:
TAO Hui-lin
E-mail: thl@glut.edu.cn
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[1] LIN Yu-yan(林宇燕). Occupation and Health(职业与健康), 2008, 24(8): 734.
[2] LIU Hai-kun, ZHOU Duan-ci, ZHOU Jing-sen(刘海坤, 周端赐, 周静森). Chinese Journal of Analytical Chemistry(分析化学), 1986, 14(1): 53.
[3] WAN Dan-jing, TONG Da-nian, ZHONG Gao-ren(万丹晶, 佟大年, 钟高仁). Chinese Journal of Clinical Pharmacy(中国临床药学杂志), 2005, 14(6): 372.
[4] WANG Li-zeng, ZHANG Xiao-li, CHEN Ting(王丽增, 张晓丽, 陈 挺). Chinese Journal of Analytical Chemistry(分析化学), 1993, 21(5): 569.
[5] Gutierrez M C，Gomez-Hens A. Anal Chim Acta, 1986, 185: 83.
[6] HAN Ling-jun, LI Sheng-yun, YAO Yi-rong(韩玲军, 李省云, 姚毅荣). Journal of Shanxi Medical University(山西医科大学学报), 2012, 43(4): 276.
[7] Shui Shui Wee, Yan Huey Ng, Sing Muk Ng. Talanta, 2013, 116: 71.
[8] GUO Yong-ming, WANG Zhuo, SHAO Hua-wu. Carbon, 2013, 52: 583.
[9] LIU Li-qin, LI Yuan-fang, ZHAN Lei(刘利芹，李原芳，詹 蕾). Scientia Sinica Chimica(中国科学: 化学), 2011, 54(8): 1342.
[10] ZHANG Li-hong, GUO Zhi-hui(张丽红, 郭志慧). Acta Chim. Sinica(化学学报)，2013, 71: 644.
[11] WANG Yuhui, BAO Lei, LIU Zhihong. Analytical Chemistry，2011, 83: 8130.
[12] Cayuela A, Soriano M L, Valcárcel M. Analytica Chimica Acta, 2013, 804: 246.
[13] ZHENG Hu-zhi, BAI Wen-jun, LONG Yi-juan(郑鹄志，白文君，隆异娟). Scientia Sinica Chimica(中国科学: 化学), 2011, 41(6): 1031.
[14] Adegoke O, Nyokong T. Journal of Luminescence, 2013, 134: 448.
[15] Cheng Zhengjun, Liu Rong, Jiang Xiaohui. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy，2013, 115: 92.
[16] HU Tao-ying, CHEN Lin, LIU Ying(胡涛英，陈 琳, 刘 颖). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2014, 34(5): 1343.
[17] LI Jian-ping(李建平). Advanced Analytical Chemistry(高等分析化学). Beijing：Metallurgical Industry Press(北京: 冶金工业出版社), 2007. 39.
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