| 光谱学与光谱分析 |
|
|
|
|
|
| Fe3O4-β-Cyclodextrin Polymer Nano Composites Solid-Phase Extraction-UV-Vis Spectrophotometry for Separation Analysis Malachite Green |
| FENG Gang1, 2, PING Wen-hui1, ZHU Xia-shi1* |
1. College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, China
2. Yangzhou Commerice Higher Vocational School, Yangzhou 225002, China |
|
|
|
|
Abstract In this paper, carboxymethyl-hydroxypropyl-β-cyclodextrin polymer modified magnetic particles Fe3O4 (CM-HP-β-CDCP-MNPs) were prepared and applied to magnetic solid phase extraction of malachite green combined with UV-Visible spectrometry detection. The synthesized magnetic particles were characterized by element analysis, Fourier transform infrared spectra and transmission electron microscopy. Several variables affecting the extraction and desorption of malachite green such as pH, the amount of adsorbent, the type and volume of eluent, extraction and desorption time, and temperature were investigated. Under the optimum conditions, malachite green could be adsorbed by CM-HP-β-CDCP-MNPs(RE%=92), and elution by C2H5OH(EE%=90). the preconcentration factor of the proposed method was approximately 7.5, the CM-HP-β-CDCP-MNPs could be used repeatedly for 5 times and offered better recovery. The linear range and detection limit (DL) were found to be 0.08～8.00 μg·mL-1 and 5.6 ng·mL-1 respectively. This technique had been successfully applied to the determination of malachite green in real samples. The inclusion interaction of CM-HP-β-CDCP-MNPs with malachite green was studied through FTIR.
|
|
Received: 2014-07-23
Accepted: 2014-11-10
|
|
|
|
Corresponding Authors:
ZHU Xia-shi
E-mail: xszhu@yzu.edu.cn; zhuxiashi@sina.com
|
|
[1] Bahram M, Keshvari F, Moghaddam P N. Talanta, 2011, 85(2): 891.
[2] Chen L Y, Lu Y B, Li S Y, et al. Food Chem., 2013, 141(2): 1383.
[3] Afkhami A, Moosavi R, Madrakian T. Talanta, 2010, 82(2): 785.
[4] HUANG Bao-mei, YAO Cheng-wei, CHEN Hong, et al(黄宝美, 姚程炜, 陈 红，等) Chinese Journal of Applied Chemistry(应用化学), 2007, 24(3): 327.
[5] MA Ming-ming, SONG Jun-feng, FAN Zeng-lu, et al(马明明, 宋俊峰, 樊增禄, 等). Chinese Journal of Analytical Chemistry(分析化学) 2008, 36(10): 1431.
[6] Hennion M C. J. Chromatogr. A, 1999, 856(1): 3.
[7] Vukcevic M, Kalijadis A, Radisic M, et al. Chem. Eng. J., 2012, 211: 224.
[8] Panavaite D, Padarauskas A, Vickackaite V. Anal. Chim. Acta, 2006, 571(1): 45.
[9] Kagaya S, Maeba E, Inoue Y, et al. Talanta, 2009, 79(2): 146.
[10] Zhu X, Wu M, Gu Y. Talanta, 2009, 78(2): 565.
[11] Abdolmohammad-Zadeh H, Rezvani Z, Sadeghi G H, et al. Anal. Chim. Acta, 2011, 685(2): 212.
[12] Jiang W, Cai Q, Xu W, et al. Environ. Sci. Technol.，2014, 48(14), 8078.
[13] Jiang W, Pelaez M, Dionysios D. et al. Chem. Eng. J. 2013, 222(15), 527.
[14] Liang M M, Fan K L, Pan Y. Anal. Chem., 2012, 85(1): 308.
[15] LI Yuan, XIAO Le-hui, ZHOU Nai-yuan, et al(李 媛, 肖乐辉, 周乃元，等）. Journal of Analytical Chemistry(分析化学), 2013, 41(1): 63.
[16] MA Zhan-ying, HE Yang-qing, XU Wei-xia, et al(马占营, 何仰清, 徐维霞, 等). Chinese Journal of Molecular Catalysis(分子催化), 2012, 3(24): 228.
[17] Jiang W, Jeffrey A Joens, Dionysios D Dionysiou, et al. J. Photochem. Photobiol. A: Chem., 2013, 262: 7.
[18] Zhang N, Peng H Y, Hu B. Talanta, 2012, 94: 278.
[19] GUI Ying-ai, MA Lin, WANG Dan, et al(桂英爱, 马 琳, 王 丹，等). Chinese Journal of Environment and Health(环境与健康杂志). 2007, 24(8): 633.
[20] CHEN Xiao-lan, FAN Ping, WU You-li, et al(陈效兰, 范 萍, 吴有丽，等). Chinese Journal of Instrumental Analysis(分析测试学报), 2013, 32(7): 840.
[21] ZHAI Han, YU Yong-li, CHENG Li-yan, et al(翟 晗, 于永丽, 成利艳, 等). Chinese Journal of Acta Chimica Sinica(化学学报) 2011, 69(10): 1205.
[22] Yang Z J, Chai K G, Ji H B. Separation and Purification Technology, 2011, 80: 209. |
| [1] |
HAN Xue1, 2, LIU Hai1, 2, LIU Jia-wei3, WU Ming-kai1, 2*. Rapid Identification of Inorganic Elements in Understory Soils in
Different Regions of Guizhou Province by X-Ray
Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 225-229. |
| [2] |
XU Rong1, AO Dong-mei2*, LI Man-tian1, 2, LIU Sai1, GUO Kun1, HU Ying2, YANG Chun-mei2, XU Chang-qing1. Study on Traditional Chinese Medicine of Lonicera L. Based on Infrared Spectroscopy and Cluster Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3518-3523. |
| [3] |
ZHANG Xiao-dan1, 2, LIU Li-li1*, YU Ying1, CHENG Wei-wei1, XU Bao-cheng1, HE Jia-liang1, CHEN Shu-xing1, 2. Activation of Epigallocatechin Gallate on Alcohol Dehydrogenase:
Multispectroscopy and Molecular Docking Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3622-3628. |
| [4] |
WANG Peng1, GAO Yong-bao1*, KOU Shao-lei1, MEN Qian-ni1, ZHANG Min1, HE Tao1, YAO Wei2, GAO Rui1, GUO Wen-di1, LIU Chang-rui1. Multi-Objective Optimization of AAS Conditions for Determination of Gold Element Based on Gray Correlation Degree-RSM Model[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3117-3124. |
| [5] |
LIU Pan1, 2, 3, DU Mi-fang1*, LI Bin1, LI Jing-bin1, ZENG Lei1, LIU Guo-yuan1, ZHANG Xin-yao1, 4, ZHA Xiao-qin1, 4. Determination of Trace Tellurium Content in Aluminium Alloy by
Inductively Coupled Plasma-Atomic Emission Spectrometry Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3125-3131. |
| [6] |
LIU Wen-bo, LIU Jin, HAN Tong-shuai*, GE Qing, LIU Rong. Simulation of the Effect of Dermal Thickness on Non-Invasive Blood Glucose Measurement by Near-Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2699-2704. |
| [7] |
LI Chen-xi1, SUN Ze-yu1, 2, ZHAO Yu2*, YIN Li-hui2, CHEN Wen-liang1, 3, LIU Rong1, 3, XU Ke-xin1, 3. The Research Progress of Two-Dimensional Correlation Spectroscopy and Its Application in Protein Substances Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 1993-2001. |
| [8] |
WANG Bin1, 2, ZHENG Shao-feng2, GAN Jiu-lin1, LIU Shu3, LI Wei-cai2, YANG Zhong-min1, SONG Wu-yuan4*. Plastic Reference Material (PRM) Combined With Partial Least Square (PLS) in Laser-Induced Breakdown Spectroscopy (LIBS) in the Field of Quantitative Elemental Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2124-2131. |
| [9] |
HOU Qian-yi1, 2, DONG Zhuang-zhuang1, 2, YUAN Hong-xia1, 2*, LI Qing-shan1, 2*. A Study of the Mechanism of Binding Between Quercetin and CAV-1 Based on Molecular Simulation, Bio-Layer Interferometry and
Multi-Spectroscopy Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 890-896. |
| [10] |
WU Lei1, LI Ling-yun2, PENG Yong-zhen1*. Rapid Determination of Trace Elements in Water by Total Reflection
X-Ray Fluorescence Spectrometry Using Direct Sampling[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 990-996. |
| [11] |
LI Wen, CHEN Yin-yin*, LUO Xue-ke, HE Na. Research on Testing NH3-N and COD in Water Quality Based on
Continuous Spectroscopy Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 254-259. |
| [12] |
YANG Kun, CHEN Lei*, CHENG Fan-chong, PEI Huan, LIU Gui-ming, WANG Bao-huai, ZENG Wen. Emission Spectroscopy Diagnosis of Air Gliding Arc Plasma Under
Atmospheric Pressure Condition[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3006-3011. |
| [13] |
HU Xuan1, CHENG Zi-hui1*, ZHANG Shu-chao2, SHI Lei2. Matrix Separation-Determination of Rare Earth Oxides in Bauxite by
Inductively Coupled Plasma-Atomic Emission Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3130-3134. |
| [14] |
LIU Pan1, 2, LI Jing-bin1, ZHANG Jian-hao1, ZHANG Yi1, CHANG Guo-liang1, HE Peng-fei1, ZHANG Bin-bin1, ZHANG Xin-yao1, 3. Determination of Phosphorus in Welding Flux by Inductively Coupled Plasma Atomic Emission Spectrometry With Ultrasonic Assisted
Hydrochloric Acid Extraction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2824-2829. |
| [15] |
DONG Jun-hang1, 2, ZHU Zhen-li1, 2*, DING Han-qing1, 2, XING Peng-ju1, ZHOU Fei-yang1, 2, ZHENG Hong-tao2, LIU Xing1. Research Progress of Isotope Analysis Method Based on Optical
Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2325-2333. |
|
|
|
|
