光谱学与光谱分析 |
|
|
|
|
|
Research on Volatiles of Rakkyo (Allium Chinense G. Don) and Chinese Chive (Allium Tuberosum Rottl. ex Sprengel) Based on Headspace and the Molecular Recognition of SERS |
ZHANG Chuan-yun1, SI Min-zhen2*, LI Lun2, ZHANG De-qing2 |
1. School of Physics and Electronic Information, Yunnan Normal University, Kunming 650500, China 2. Key Laboratory of Molecular Spectroscopy, Colleges and Universities in Yunnan Province, Chuxiong Normal University, Chuxiong 675000, China |
|
|
Abstract The headspace and the molecular recognition of surface enhanced Raman scattering (SERS) were used to research volatiles of rakkyo and Chinese chive. Their volatiles SERS spectra were obtained using nano-silver colloid as the substrate$ Then, volatiles SERS spectra of rakkyo and Chinese Chive were compared respectively with the volatiles SERS spectra of liquid allyl methyl sulfide, 1-propanethiol, diallyl disulfide and all possible pairings of the three compounds. The results showed that the repeatability of volatiles SERS spectra of rakkyo and Chinese Chive were all good. The volatiles SERS spectrum of rakkyo was basically consistent with the volatiles SERS spectrum of the mixture of liquid allyl methyl sulfide and 1-propanethiol. The volatiles SERS spectrum of rakkyo included both characteristic peaks at 626 and 674 cm-1 in volatiles SERS spectrum of allyl methyl sulfide and characteristic peaks at 702, 893, 1 024, 1 085, 1 215 and 1 320 cm-1 in volatiles SERS spectrum of 1-Propanethiol. The volatiles SERS spectrum of Chinese chive was basically consistent with the volatiles SERS spectrum of the mixture of liquid allyl methyl sulfide and diallyl disulfide. The volatiles SERS spectrum of Chinese chive included both characteristic peak at 674 cm-1 in volatiles SERS spectrum of allyl methyl sulfide and characteristic peaks at 407, 577, 716, 1 189, 1 291 and 1 401 cm-1 in volatiles SERS spectrum of diallyl disulfide. These illustrated that volatiles of rakkyo contained allyl methyl sulfide and 1-Propanethiol and volatiles of Chinese chive contained allyl methyl sulfide and diallyl disulfide. The volatiles of rakkyo and Chinese chive were different, but they all contained allyl methyl sulfide. All of the above have revealed that the headspace combined with molecular recognition of SERS can be directly used to study volatiles of rakkyo and Chinese chive. The technology under room temperature, can guarantee the volatiles obtained were the primitive constituents in plant volatiles. By comparison with the standard sample, the constituents in plant volatiles can be determined.
|
Received: 2014-03-09
Accepted: 2014-06-14
|
|
Corresponding Authors:
SI Min-zhen
E-mail: siminzhen@cxtc.edu.cn
|
|
[1] Jiangsu New Medical College(江苏新医学院). Traditional Chinese Medicine Dictionary(中药大辞典). Shanghai: Shanghai People’s Publishing House(上海:上海人民出版社), 1977. 870. [2] Bah A A, Wang F, Huang Z H, et al. International Journal of Agriculture and Biotechnolgy, 2012, 14(4): 650. [3] LOU Wei-dong, DUAN Da-hang, SUN Pi-dong(娄卫东,段大航,孙丕东). Medical Journal of Chinese People’s Health(中国民康医学), 2007, 19(8): 671. [4] ZOU Zhong-mei, YU De-quan, CONG Pu-zhu(邹忠梅, 于德泉, 丛浦珠). Acta Pharmaceutica Sinica(药学学报), 1999, 34(5): 395. [5] Lazarevi J S, Dordevic A S, Zlatkovic B K, et al. Journal of the Science of Food and Agriculture, 2011, 91(2): 322. [6] SUN Yun-jun,BAI Jian-shan,CHEN Yu, et al(孙运军,柏建山,陈 宇,等). Food Science(食品科学), 2004, 25(11): 295. [7] Storsberg J, Schulz H, Keusgen M, et al. J. Agric. Food Chem., 2004, 52(17): 5499. [8] PENG Jun-peng, QIAO Yan-qiu, XIAO Ke-yue, et al(彭军鹏,乔艳秋,肖克岳,等). Chinese Journal of Medicinal Chemistry(中国药物化学杂志), 1994, 4(4): 282. [9] CHEN Xiao-lan, SHI Dong-yan, CHEN Shan-na(陈小兰, 史冬燕, 陈善娜). Fine Chemicals(精细化工), 2005, 22(5): 373. [10] Pino J A, Fuentes V, Teresa C M. J. Agric. Food Chem., 2001, 49: 1328. [11] Kim K, Lee J W, Shin K S. Spectrochimica Acta Part A, 2013, 100: 15. [12] SI Min-zhen, ZHANG De-qing, LIU Ren-ming(司民真,张德清,刘仁明). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2014, 34(9): 2449. [13] Si M Z, Kang Y P, Zhang Z G. Journal of Raman Spectroscopy, 2009, 40(9): 1319. [14] George Socrates. Infrared and Raman Characteristic Group Frequencies Tables and Charts-Third Edition, 2001. 209. [15] Mann R S, Rouseff R L, Smoot J M, et al. Bulletin of Entomological Research, 2011, 101: 89. |
[1] |
LAI Chun-hong*, ZHANG Zhi-jun, WEN Jing, ZENG Cheng, ZHANG Qi. Research Progress in Long-Range Detection of Surface-Enhanced Raman Scattering Signals[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2325-2332. |
[2] |
LI Jia-jia, XU Da-peng *, WANG Zi-xiong, ZHANG Tong. Research Progress on Enhancement Mechanism of Surface-Enhanced Raman Scattering of Nanomaterials[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1340-1350. |
[3] |
SUN Zhi-ming1, LI Hui1, FENG Yi-bo1, GAO Yu-hang1, PEI Jia-huan1, CHANG Li1, LUO Yun-jing1, ZOU Ming-qiang2*, WANG Cong1*. Surface Charge Regulation of Single Sites Improves the Sensitivity of
Raman Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1075-1082. |
[4] |
YIN Xiong-yi1, SHI Yuan-bo1*, WANG Sheng-jun2, JIAO Xian-he2, KONG Xian-ming2. Quantitative Analysis of Polycyclic Aromatic Hydrocarbons by Raman Spectroscopy Based on ML-PCA-BP Model[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 861-866. |
[5] |
SUN Nan, TAN Hong-lin*, ZHANG Zheng-dong, REN Xiang, ZHOU Yan, LIU Jian-qi, CAI Xiao-ming, CAI Jin-ming. Raman Spectroscopy Analysis and Formation Mechanism of Carbon
Nanotubes Doped Polyacrylonitrile/Copper Cyclized to Graphite
at Room Temperature[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(09): 2983-2988. |
[6] |
WANG Zi-xiong, XU Da-peng*, ZHANG Yi-fan, LI Jia-jia. Research Progress of Surface-Enhanced Raman Scattering Detection Analyte Molecules[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 341-349. |
[7] |
WAN Xiao-ming1, 2, ZENG Wei-bin1, 2, LEI Mei1, 2, CHEN Tong-bin1, 2. Micro-Distribution of Elements and Speciation of Arsenic in the Sporangium of Pteris Vittata[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 470-477. |
[8] |
HUANG Hui1, 2, TIAN Yi2, ZHANG Meng-die1, 2, XU Tao-ran2, MU Da1*, CHEN Pei-pei2, 3*, CHU Wei-guo2, 3*. Design and Batchable Fabrication of High Performance 3D Nanostructure SERS Chips and Their Applications to Trace Mercury Ions Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3782-3790. |
[9] |
WANG Run-yu1, DONG Da-ming1,2, YE Song1*, JIAO Lei-zi1,2. Measurement of Volatile Compounds Released From Plastic Using[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3039-3044. |
[10] |
FU Xing-hu, WANG Zhen-xing, MA Shuang-yu, ZHAO Fei, LU Xin, FU Guang-wei, JIN Wa, BI Wei-hong. Preparation and Properties of Micro-Cavity Silver Modified Fiber SERS Probe[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2800-2806. |
[11] |
GUI Bo1, 2, YANG Yu-dong1, ZHAO Qian1, 2, SHI Meng1, MAO Hai-yang1, 3*, WANG Wei-bing1, CHEN Da-peng1, 3. A SERS Substrate for On-Site Detection of Trace Pesticide Molecules Based on Parahydrophobic Nanostructures[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(08): 2499-2504. |
[12] |
SUN Ning, CHEN Jun-fan, ZHANG Jie*, ZHU Yong. The Forming Mechanism of Surface Morphology of Nanostructures and Its Effect on Graphene Raman Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1821-1827. |
[13] |
ZHANG Can, ZHANG Jie*, DOU Xin-yi, ZHU Yong. Connection of Absorption and Raman Enhancement Characteristics of Different Types of Ag Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1816-1820. |
[14] |
DOU Xin-yi, ZHANG Can, ZHANG Jie*. Effects of Process Parameters on Double Absorption Resonance Peaks of Au Nanoparticles[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1446-1451. |
[15] |
ZHANG Lei, ZHANG Xia*, WENG Yi-jin, LIU Xiao. Preparation and Properties of Ag/PANI Multifunction Nanozymes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3399-3403. |
|
|
|
|