光谱学与光谱分析 |
|
|
|
|
|
A Rapid Method for the Determination of Hydrogen Peroxide Concentration |
ZHANG Qian, FU Shi-yu, LI Hai-long*, ZHAN Huai-yu |
State Key Lab of Pulp & Paper Engineering, South China University of Technology, Guangzhou 510640, China |
|
|
Abstract The present paper reported a spectrophotometry for the determination of hydrogen peroxide concentration. It is based on the reaction between ceric sulfate and hydrogen peroxide in an acidic medium, in which orange tetravalent cerium is converted to colorless trivalent cerium that causeds the change in absorbance. According to the quantitative relationship between ceric sulfate and hydrogen peroxide, the hydrogen peroxide concentration can be calculated. The selected conditions were as follows: detection wavelength of 480 nm, H2SO4 concentration of 0.5 mol·L-1, and reaction time of 3.0 min. The results showed that the method has an excellent measurement precision (RSD=0.31%) and accuracy (RSD≤0.91%) for the quantification of hydrogen peroxide. The present method is simple and rapid, with high detection sensitivity and low cost. It is suitable for use in rapid industrial analyses.
|
Received: 2013-05-10
Accepted: 2013-08-26
|
|
Corresponding Authors:
LI Hai-long
E-mail: lihailong1979@gmail.com
|
|
[1] LUAN Guo-yan, GAO Wei-ping, YAO Ping-jing(栾国颜, 高维平, 姚平经). Chemical Technology Market(化工科技市场), 2005, 28(1): 15. [2] Greenspan F P, MacKellar D G. Anal. Chem., 1948, 20(11): 1061. [3] Chai X S, Hou Q X, Luo Q, et al. Anal. Chim. Acta, 2004, 507(2): 281. [4] Odo J, Matsumoto K, Shinmoto E, et al. Anal. Sci.,2004, 20(4): 707. [5] Arnous A, Petrakis C, Makris D P, et al. Journal of Pharmacological and Toxicological Methods, 2002, 48(3): 171. [6] XIE Guang-hua, HUANG Gang(谢光华, 黄 岗). Analytical Chemistry(分析化学), 1991, 19(7): 823. [7] Hanson A K, Tindale N W, Abdel-Moati M A R. Marine Chemistry, 2001, 75(1): 69. [8] Chen Q Y, Li D H, Zhu Q Z, et al. Analytica Chimica Acta, 1999, 381(2): 175. [9] Effkemann S, Pinkernell U, Karst U. Analytica Chimica Acta, 1998, 363(1): 97. [10] Kobayashi K, Kawai S. Journal of Chromatography A, 1982, 245(3): 339. [11] Gustavsson T, Damlin S A. Paper Technology, 1999, 40(7): 101. [12] Yamamoto K, Ohgaru T, Torimura M. Analytica Chimica Acta, 2000, 406(2): 201. [13] De Wael K D, Bashir Q, Van Vlierberghe S, et al. Bioelectrochemistry, 2012, 83: 15. [14] GB-T/601—2002 Chemical reagent-Preparations of Standard Volumetric Solutions(化学试剂标准滴定溶液的制备). National Standards of the People’s Republic of China(中华人民共和国国家标准). |
[1] |
LIANG Ya-quan1, PENG Wu-di1, LIU Qi1, LIU Qiang2, CHEN Li1, CHEN Zhi-li1*. Analysis of Acetonitrile Pool Fire Combustion Field and Quantitative
Inversion Study of Its Characteristic Product Concentrations[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3690-3699. |
[2] |
BAI Bing1, 2, 3, CHEN Guo-zhu2, 3, YANG Wen-bin2, 3, CHE Qing-feng2, 3, WANG Lin-sen2, 3, SUN Wei-min1*, CHEN Shuang1, 2, 3*. The Study on Precise and Quantitative Measurement of Flame OHConcentration by CRDS-CARS-PLIF Techniques[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3955-3962. |
[3] |
DUAN Ming-xuan1, LI Shi-chun1, 2*, LIU Jia-hui1, WANG Yi1, XIN Wen-hui1, 2, HUA Deng-xin1, 2*, GAO Fei1, 2. Detection of Benzene Concentration by Mid-Infrared Differential
Absorption Lidar[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3351-3359. |
[4] |
SHEN Ying, WU Pan, HUANG Feng*, GUO Cui-xia. Identification of Species and Concentration Measurement of Microalgae Based on Hyperspectral Imaging[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3629-3636. |
[5] |
KANG Ying1, ZHUO Kun1, LIAO Yu-kun1, MU Bing1, QIN Ping2, LI Qian1, LUAN Xiao-ning1*. Quantitative Determination of Alcohol Concentration in Liquor Based on Polarized Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2768-2774. |
[6] |
CHANG Zhen1, ZHONG Ming-yu2*, SU Jing-ming1, 2, SI Fu-qi1, WANG Yu3, ZHOU Hai-jin1, DOU Ke1, ZHANG Quan1. Study on the Reconstructing the NO2 Gas Distribution in a Vertical Plane Using MAX-DOAS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2413-2418. |
[7] |
PU Gui-juan1, 2, CHENG Si-yang3*, LI Song-kui4, LÜ Jin-guang2, CHEN Hua5, MA Jian-zhong3. Spectral Inversion and Variation Characteristics of Tropospheric NO2
Column Density in Lhasa, Tibet[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1725-1730. |
[8] |
ZHANG Rong1, 2, DUAN Ning1, 3, JIANG Lin-hua1, 3*, XU Fu-yuan3, JIN Wei3, LI Jian-hui1. Study on Optical Path Optimization for Direct Determination of
Spectrophotometry of High Concentration Hexavalent Chromium
Solution by Ultraviolet Visible Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1829-1837. |
[9] |
ZHANG Li-fang1, YANG Yan-xia1, ZHAO Guan-jia1, MA Su-xia1, GUO Xue-mao2. Comparison of Numerical Iterative Algorithms for Two-Dimensional Absorption Spectral Reconstruction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1367-1375. |
[10] |
XU Qi-lei, GUO Lu-yu, DU Kang, SHAN Bao-ming, ZHANG Fang-kun*. A Hybrid Shrinkage Strategy Based on Variable Stable Weighted for Solution Concentration Measurement in Crystallization Via ATR-FTIR Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1413-1418. |
[11] |
PENG Wei, YANG Sheng-wei, HE Tian-bo, YU Ben-li, LI Jin-song, CHENG Zhen-biao, ZHOU Sheng*, JIANG Tong-tong*. Detection of Water Vapor Concentration in Sealed Medicine Bottles Based on Digital Quadrature Phase-Locked Demodulation Algorithm and TDLAS
Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 698-704. |
[12] |
ZHANG Qi-jin1, 2, GUO Ying-ying1, 2, LI Su-wen1, 2*, MOU Fu-sheng1, 2*. Study on the Methods of Collecting Atmospheric Pollution Gases in
Huaibei Region by Mobile Mini-DOAS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 984-989. |
[13] |
OU Li-juan1*, LI Jing1, ZHANG Chao-qun1, LUO Jian-xin1, WEI Ji1, WANG Hai-bo2*, ZHANG Chun-yan1. Redox-Controlled Turn-on Fluorescence Sensor for H2O2 and Glucose Using DNA-Template Gold Nanoclusters[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3757-3761. |
[14] |
LOU Deng-cheng, RAO Wei*, SONG Jun-ling, WANG Kai, JIANG Ya-jing, GUO Jian-yu. Research of Carbon Monoxide Concentration Measurement in Combustion Field by Off-Axis Integrated Cavity Output Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3678-3684. |
[15] |
SUN You-rui1, GUO Mei1, LIU Gui-shan1*, FAN Nai-yun1*, ZHANG Hao-nan2, LI Yue1, PU Fang-ning2, YANG Shi-hu1, WANG Hao2. Fusion of Visible Near-Infrared (VNIR) Hyperspectral Imaging and Texture Feature for Prediction of Total Phenolics Content in
Tan Mutton[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3631-3636. |
|
|
|
|